4-butoxy-9H-carbazole

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 4-butoxy-9H-carbazole
• 化学式: C₁₆H₁₇NO
• 分子量: 239.317
• InChiKey: KIGDCIAMBMDKRI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  18
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  25
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  2-(2-溴乙氧基)四氢吡喃 、 4-butoxy-9H-carbazole 在 sodium hydride 、 sodium iodide 、 对甲苯磺酸 作用下， 以 N,N-二甲基甲酰胺 、 甲醇 为溶剂， 反应 25.0h， 生成 2-(4-butoxy-9H-carbazol-9-yl)ethan-1-ol
  参考文献：
  名称：

  Macroscopic Wires from Fluorophore-Quencher Dyads with Long-Lived Blue Emission

  摘要：

  We report the formation of macroscopic wires up to centimeters in length from a series of structurally flexible, covalently tethered small-molecular fluorophore-quencher dyads (FQDs, average MW = 425 Da), comprised of carbazole, melatonin, and cyanobenzoate moieties. These FQDs are nonemissive in organic solutions but become moderately to highly luminescent (Phi(F) = 0.037-0.39) upon formation of wires with emission maxima in the blue region (446-483 nm). The blue photoluminescence (PL) is ascribed to a combination of singlet charge transfer, localized triplet state, and possibly delayed fluorescence emissions with intrinsic luminescence lifetimes ranging from 0.228 to 21333 mu s, based on luminescence, transient absorption measurements, X-ray diffraction, and calculations.

  DOI：

  10.1021/acs.jpca.7b08268
• 作为产物：
  描述：

  正溴丁烷 、 4-羟基咔唑 在 四丁基溴化铵 、 potassium carbonate 作用下， 以 乙酸乙酯 为溶剂， 反应 25.0h， 生成 4-butoxy-9H-carbazole
  参考文献：
  名称：

  Macroscopic Wires from Fluorophore-Quencher Dyads with Long-Lived Blue Emission

  摘要：

  We report the formation of macroscopic wires up to centimeters in length from a series of structurally flexible, covalently tethered small-molecular fluorophore-quencher dyads (FQDs, average MW = 425 Da), comprised of carbazole, melatonin, and cyanobenzoate moieties. These FQDs are nonemissive in organic solutions but become moderately to highly luminescent (Phi(F) = 0.037-0.39) upon formation of wires with emission maxima in the blue region (446-483 nm). The blue photoluminescence (PL) is ascribed to a combination of singlet charge transfer, localized triplet state, and possibly delayed fluorescence emissions with intrinsic luminescence lifetimes ranging from 0.228 to 21333 mu s, based on luminescence, transient absorption measurements, X-ray diffraction, and calculations.

  DOI：

  10.1021/acs.jpca.7b08268

文献信息

• Macroscopic Wires from Fluorophore-Quencher Dyads with Long-Lived Blue Emission
  作者：Tao Wang、Ziye Wu、Wei Sun、Shengye Jin、Xingyuan Zhang、Chuanyao Zhou、Jun Jiang、Yi Luo、Guoqing Zhang

  DOI：10.1021/acs.jpca.7b08268

  日期：2017.9.28

  We report the formation of macroscopic wires up to centimeters in length from a series of structurally flexible, covalently tethered small-molecular fluorophore-quencher dyads (FQDs, average MW = 425 Da), comprised of carbazole, melatonin, and cyanobenzoate moieties. These FQDs are nonemissive in organic solutions but become moderately to highly luminescent (Phi(F) = 0.037-0.39) upon formation of wires with emission maxima in the blue region (446-483 nm). The blue photoluminescence (PL) is ascribed to a combination of singlet charge transfer, localized triplet state, and possibly delayed fluorescence emissions with intrinsic luminescence lifetimes ranging from 0.228 to 21333 mu s, based on luminescence, transient absorption measurements, X-ray diffraction, and calculations.