9,9-bis(4-hydroxy-3-phenylphenyl)fluorene

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 二芳基庚烷
• 英文名称: 9,9-bis(4-hydroxy-3-phenylphenyl)fluorene
• 英文别名: 9,9-bis(3-phenyl-4-hydroxyphenyl)fluorene；4-[9-(4-Hydroxy-3-phenylphenyl)fluoren-9-yl]-2-phenylphenol
• 化学式: C₃₇H₂₆O₂
• 分子量: 502.612
• InChiKey: FLMZHPQIDVOWEJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.2
• 重原子数：
  39
• 可旋转键数：
  4
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  9,9-bis(4-hydroxy-3-phenylphenyl)fluorene 在 hydrazine hydrate 、 potassium carbonate 、 甲烷 作用下， 以 1,4-二氧六环 、 N,N-二甲基甲酰胺 为溶剂， 反应 27.0h， 生成
  参考文献：
  名称：

  一种主链含噁嗪和Cardo结构的双马来酰亚胺及其制备方法

  摘要：

  本发明提供一种主链含噁嗪和Cardo结构的双马来酰亚胺的制备方法，属于高性能热固性树脂技术领域。双马来酰亚胺单体分子结构式为： 其中，R为 中任意一种；R1为下列结构中任意一种： R2为下列结构中任意一种： 本发明在主链中引入非共平面Cardo结构可以阻止分子链密堆积，降低分子间作用力，从而提高分子的溶解性。引入的噁嗪可以在加热条件下发生开环聚合而无小分子放出，进一步增加固化物的交联密度进而提高耐热性。引入的苯并噁嗪也具有优异的阻燃性、介电型和防腐性能等性能。本方法制备的双马来酰亚胺可以单独使用或与其它树脂混合使用，所得到的固化制品具有更高的耐热性、阻燃性、介电性和防腐性能。

  公开号：

  CN114805333A
• 作为产物：
  描述：

  9-芴酮 、 邻苯基苯酚 在 硫酸 、 3-巯基丙酸 作用下， 以 甲苯 为溶剂， 生成 9,9-bis(4-hydroxy-3-phenylphenyl)fluorene
  参考文献：
  名称：

  心脏双（苯基苯基）芴基半氟化聚（醚酰胺）的合成，表征和气体传输性能

  摘要：

  在这里，我们报告了一系列由新的二胺单体9,9-双-[3-苯基-4- { 2'-三氟甲基-4'-（4''-氨基苯基）苯氧基}苯基]芴。为了比较目的，还由二胺9，9-双-[4- {2'-三氟甲基-4'-（（4''-氨基苯基）苯氧基}苯基]芴制备了具有双（苯基）芴部分的类似PA。 。合成的PA表现出高的热稳定性（在空气和氮气中分别达到517°C和539°C，重量减轻10％），玻璃化转变温度（272-299°C）和高达117 MPa的高拉伸强度。这些PA的光学透明膜（λ截止≥368 nm）在barrer（PCO 2最高可达67.42， P O 2最高可达15）和高选择性（ P CO 2 / P CH 4最高可达88.37， P O 2 / P N 2最高可达10.84）；特别是对于O 2 / N 2气体对，PA超过或达到了Robeson制定的2008年当前上限。关联了PA中的双（苯基苯基）芴部分和

  DOI：

  10.1039/c4ra00920g

文献信息

• MATERIAL FOR FORMING ORGANIC FILM, METHOD FOR FORMING ORGANIC FILM, PATTERNING PROCESS, AND COMPOUND
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US20210286266A1

  公开（公告）日：2021-09-16

  The present invention is a material for forming an organic film, including: a compound shown by the following general formula (1); and an organic solvent, where in the general formula (1), X represents an organic group with a valency of “n” having 2 to 50 carbon atoms or an oxygen atom, “n” represents an integer of 1 to 10 , and R 1 independently represents any of the following general formulae (2), where in the general formulae (2), broken lines represent attachment points to X, and Q 1 represents a monovalent organic group containing a carbonyl group, at least a part of which is a group shown by the following general formulae (3), where in the general formulae (3), broken lines represent attachment points, X 1 represents a single bond or a divalent organic group having 1 to 20 carbon atoms optionally having a substituent when the organic group has an aromatic ring, R 2 represents a hydrogen atom, a methyl group, an ethyl group, or a phenyl group, and ** represents an attachment point. An object of the present invention is to provide a material for forming an organic film for forming an organic film having dry etching resistance, and also having high filling and planarizing properties and adhesion to a substrate.

  本发明是一种用于形成有机薄膜的材料，包括：由以下通用式（1）所示的化合物；和有机溶剂，在通用式（1）中，X代表具有2至50个碳原子或一个氧原子的价为“n”的有机基团，“n”表示1到10的整数，R1独立地表示以下通用式（2）中的任何一种，其中在通用式（2）中，虚线表示连接点到X，Q1表示含有羰基的一价有机基团，其中至少部分是以下通用式（3）所示的基团，其中在通用式（3）中，虚线表示连接点，X1表示单键或具有1到20个碳原子的二价有机基团，在有机基团具有芳香环时可选地具有取代基，R2表示氢原子、甲基基团、乙基基团或苯基团，**表示连接点。本发明的目的是提供一种用于形成具有干法刻蚀抗性的有机薄膜的材料，同时具有高填充和平整化性能以及对基底的粘附性。
• METHOD FOR PRODUCING CYANOGEN-HALIDE, CYANATE ESTER COMPOUND AND METHOD FOR PRODUCING THE SAME, AND RESIN COMPOSITION
  申请人：MITSUBISHI GAS CHEMICAL COMPANY, INC.

  公开号：US20150299110A1

  公开（公告）日：2015-10-22

  A method for efficiently producing a cyanogen halide with suppressed side effects, and a method for producing a high-purity cyanate ester compound at a high yield includes contacting a halogen molecule with an aqueous solution containing hydrogen cyanide and/or a metal cyanide, so that the hydrogen cyanide and/or the metal cyanide is allowed to react with the halogen molecule in the reaction solution to obtain the cyanogen halide, wherein more than 1 mole of the hydrogen cyanide or the metal cyanide is used based on 1 mole of the halogen molecule, and when an amount of substance of an unreacted hydrogen cyanide or an unreacted metal cyanide is defined as mole (A) and an amount of substance of the generated cyanogen halide is defined as mole (B), the reaction is terminated in a state in which (A):(A)+(B) is between 0.00009:1 and 0.2:1.

  一种用于高效生产抑制副作用的氰卤化物，以及以高收率生产高纯度氰酸酯化合物的方法包括将卤素分子与含有氢氰酸和/或金属氰化物的水溶液接触，使得氢氰酸和/或金属氰化物与卤素分子在反应溶液中发生反应以获得氰卤化物，其中基于1摩尔卤素分子使用超过1摩尔的氢氰酸或金属氰化物，当未反应的氢氰酸或未反应的金属氰化物的物质量定义为摩尔(A)，生成的氰卤化物的物质量定义为摩尔(B)，反应在(A)：(A)+(B)介于0.00009:1和0.2:1之间的状态中终止。
• 新規なシアネートエステルとその製造方法
  申请人：株式会社緑化学研究所

  公开号：JP2005187335A

  公开（公告）日：2005-07-14

  PROBLEM TO BE SOLVED: To provide a new cyanate ester having high storage stability by itself and affording a plastic having excellent light transmittance and heat resistance, low values of permittivity and dielectric dissipation factor and a high refractive index and resultantly useful in, e.g. applications of optical techniques by using the cyanate ester as a raw material and to provide a method for producing the cyanate ester.

  SOLUTION: The cyanate ester is represented by general formula (I) (wherein, R denotes a fluorenylidene group or a p-biphenylmethylidene group). The cyanate ester is obtained by reacting a bisphenol represented by general formula (II) (wherein, R denotes a fluorenylidene group or a p-biphenylmethylidene group) with a cyanogen halide represented by general formula (III) (wherein, X denotes a halogen atom).

  COPYRIGHT: (C)2005,JPO&NCIPI

  要解决的问题：提供一种具有高自身储存稳定性的新氰酸酯，能够制备具有优异透光性和耐热性、低介电常数和介电损耗因子值以及高折射率的塑料，并且能够在光学技术应用中使用氰酸酯作为原材料，同时提供一种生产氰酸酯的方法。氰酸酯由通式（I）表示（其中，R代表芴基亚甲基组或对联苯基亚甲基组）。通过将通式（II）表示的双酚（其中，R代表芴基亚甲基组或对联苯基亚甲基组）与通式（III）表示的氰卤素（其中，X代表卤素原子）反应而得到氰酸酯。版权所有：（C）2005，JPO&NCIPI
• [EN] TRIARYLMETHANE COMPOUNDS<br/>[FR] COMPOSÉS DE TRIARYLMÉTHANE
  申请人：REUTER CHEMISCHE APPBAU KG

  公开号：WO2019154727A1

  公开（公告）日：2019-08-15

  The present invention relates to triarylmethane compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. (I) where R1, R2 are e.g. hydrogen; Y is an alkylene group having 2, 3 or 4 carbon atoms, Ar is selected from mono-or polycyclic aryl and mono-or polycyclic hetaryl; X1, X2, X3, X4 are CH, C-Rx or N, provided that in each ring at most two of X1, X2, X3, X4 are N; Rx is e.g. halogen, CN or CH=CH2. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I).

  本发明涉及具有以下式（I）的三芳基甲烷化合物，该化合物适用作为制备具有有益光学性能的热塑性树脂的单体，并可用于生产光学器件。其中R1，R2例如是氢；Y是具有2、3或4个碳原子的烷基基团，Ar选自单环或多环芳基和单环或多环杂芳基；X1、X2、X3、X4是CH、C-Rx或N，要求在每个环中最多有两个是N；Rx例如是卤素、CN或CH=CH2。该发明还涉及包含具有上述式（I）化合物的聚合单元的热塑性树脂。
• [EN] POLYCYCLIC COMPOUNDS<br/>[FR] COMPOSÉS POLYCYCLIQUES
  申请人：REUTER CHEMISCHE APPBAU E K

  公开号：WO2020079225A1

  公开（公告）日：2020-04-23

  The present invention relates to compounds of the formula (I), which are suitable as monomers for preparing thermoplastic resins having beneficial optical properties and which can be used for producing optical devices. In Formula (I), A1, A2 are selected from mono- or bicyclic aromatic radicals and mono- or bicyclic heteroaromatic radicals; X represents e.g. a single bond, O, NH, CR6R7; Y is e.g. absent or represents a single bond, O, NH, CR8R9; R1, R2 are hydrogen, a radical Ar' or a radical Ra; R3 is Alk, O-Alk'-, O-Alk'-[O-Alk']o, O-CH2-Ar-C(O)-, O-C(O)-Ar-C(O)-or O-Alk-C(O)-,where in the last five moieties the left O is bound to A1 and A2, respectively; m, n are 0, 1 or 2; o is an integer from 1 to 10; R4, R5 are e.g. selected from CN and a radical Ra; R6, R8 are e.g. selected from hydrogen, a radical Ar' and a radical Ra; R7, R9 are e.g. selected from hydrogen, C1-C4-alkyl and a radical Ar'; Ra is selected from the group consisting of C≡C-R11 and Ar-C≡C-R11; R11 is e.g. selected from hydrogen, methyl, mono- or polycyclic aryl having from 6 to 26 carbon atoms and mono- or polycyclic hetaryl having a total of 5 to 26 atoms, which are ring members, where 1, 2, 3 or 4 of the ring atoms of hetaryl are selected from nitrogen, sulphur and oxygen, while the remainder of these atoms are carbon atoms, where mono- or polycyclic aryl are unsubstituted or substituted; and Ar is e.g. phenylene or naphthylene. The invention also relates to thermoplastic resins comprising a polymerized unit of the compound of formula (I) and to optical devices made of such resins.

  本发明涉及公式（I）的化合物，这些化合物适用作为单体制备具有有益光学性能的热塑性树脂，并可用于制造光学器件。在公式（I）中，A1、A2选自单环或双环芳香基团和单环或双环杂芳基团；X代表例如单键，O，NH，CR6R7；Y例如缺失或代表单键，O，NH，CR8R9；R1、R2为氢，基团Ar'或基团Ra；R3为Alk，O-Alk'-，O-Alk'-[O-Alk']o，O-CH2-Ar-C(O)-，O-C(O)-Ar-C(O)-或O-Alk-C(O)-，在最后五个基团中，左侧的O分别与A1和A2结合；m、n为0、1或2；o为1到10的整数；R4、R5例如选自CN和基团Ra；R6、R8例如选自氢，基团Ar'和基团Ra；R7、R9例如选自氢，C1-C4-烷基和基团Ar'；Ra选自C≡C-R11和Ar-C≡C-R11的组，R11例如选自氢，甲基，含有6到26个碳原子的单环或多环芳基和含有总共5到26个原子的单环或多环杂芳基，其中环原子中的1、2、3或4个来自氮、硫和氧，其余原子为碳原子，其中单环或多环芳基是未取代或取代的；Ar例如苯基或萘基。该发明还涉及包含公式（I）化合物聚合单元的热塑性树脂以及由这种树脂制成的光学器件。