2,9-bis(5-tert-butyl-2-hydroxy-3-pyridylphenyl)-1,10-phenanthroline

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,9-bis(5-tert-butyl-2-hydroxy-3-pyridylphenyl)-1,10-phenanthroline
• 英文别名: 4-Tert-butyl-2-[9-(5-tert-butyl-2-hydroxy-3-pyridin-2-ylphenyl)-1,10-phenanthrolin-2-yl]-6-pyridin-2-ylphenol；4-tert-butyl-2-[9-(5-tert-butyl-2-hydroxy-3-pyridin-2-ylphenyl)-1,10-phenanthrolin-2-yl]-6-pyridin-2-ylphenol
• 化学式: C₄₂H₃₈N₄O₂
• 分子量: 630.789
• InChiKey: UCUNCEHETYSVSW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.6
• 重原子数：
  48
• 可旋转键数：
  6
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  92
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  cobalt(II) diacetate tetrahydrate 、 2,9-bis(5-tert-butyl-2-hydroxy-3-pyridylphenyl)-1,10-phenanthroline 以 乙醇 为溶剂， 反应 1.0h， 以81%的产率得到
  参考文献：
  名称：

  EP2133336

  摘要：

  公开号：
• 作为产物：
  描述：

  2,9-bis(3-bromo-5-tert-butyl-2-methoxyphenyl)-1,10-phenanthroline 在 四(三苯基膦)钯 三溴化硼 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 120.0h， 生成 2,9-bis(5-tert-butyl-2-hydroxy-3-pyridylphenyl)-1,10-phenanthroline
  参考文献：
  名称：

  Synthesis of dinucleating phenanthroline-based ligands

  摘要：

  The phenolic bridged dinucleating phenanthroline-pyridine, phenanthroline-phosphine, phenanthroline-alcohol, and phenanthroline-imine ligands have been synthesized from I,10-phenanthroline via key Stille and Suzuki cross couplings. (C) 1999 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(99)00428-7

文献信息

• CATHODE CATALYST FOR AIR SECONDARY BATTERY AND AIR SECONDARY BATTERY
  申请人：Koshino Nobuyoshi

  公开号：US20140066290A1

  公开（公告）日：2014-03-06

  The present invention provides a cathode catalyst for an air secondary cell having both excellent oxygen reduction activity and excellent water oxidation activity, and an air secondary cell that uses the catalyst. The present invention relates to a cathode catalyst for an air secondary cell in which the catalyst contains a polynuclear metal complex.

  本发明提供了一种空气二次电池的阴极催化剂，具有优异的氧还原活性和优异的水氧化活性，并且使用该催化剂的空气二次电池。本发明涉及一种空气二次电池的阴极催化剂，其中该催化剂包含多核金属配合物。
• MODIFIED METAL COMPLEXES AND USE THEREOF
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2133336A1

  公开（公告）日：2009-12-16

  A modified metal complex obtained by subjecting a metal complex containing an organic compound having one nitrogen-containing aromatic heterocycle and four or more structures selected from the group consisting of a phenol ring, a thiophenol ring, an aniline ring and a nitrogen-containing aromatic heterocycle in its molecule as a ligand to any one treatment of a heating treatment, a radiation irradiation treatment and a discharge treatment until a mass reduction rate after the treatment becomes 1 mass% or more and 90 mass% or less, thereby the complex shows a carbon content after the treatment of 5 mass% or more; and a modified metal complex obtained by the step of subjecting a metal complex comprising an organic compound having two or more phenol rings and three or more nitrogen-containing aromatic heterocycles in its molecule as a ligand to any one treatment of a heating treatment, a radiation irradiation treatment and a discharge treatment until a mass reduction rate after the treatment becomes 1 mass% or more and 90 mass% or less, thereby the complex shows a carbon content after the treatment of 5 mass% or more.

  一种改性金属络合物，其制备方法是将含有一种有机化合物的金属络合物作为配体，该有机化合物的分子中含有一个含氮芳香杂环和四个或更多结构，这些结构选自由苯酚环、噻吩酚环、苯胺环和一个含氮芳香杂环组成的组，将该金属络合物作为配体进行加热处理、辐射照射处理和放电处理中的任意一种处理，直至处理后的质量减少率为 1 质量％或以上且 90 质量％或以下，从而使络合物在处理后显示出 5 质量％或以上的碳含量；以及 一种改性金属络合物，该金属络合物包含一种有机化合物，该有机化合物的分子中含有两个或两个以上的苯酚环和三个或三个以上的含氮芳香杂环作为配体，该金属络合物通过加热处理、辐射照射处理和放电处理中的任意一种处理，直至处理后的质量降低率达到 1 质量％或以上和 90 质量％或以下，从而使络合物在处理后显示出 5 质量％或以上的碳含量。
• METAL COMPLEX
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP2123638B1

  公开（公告）日：2018-09-12
• Synthesis of acyclic dinucleating phenanthroline-pyridine and phenanthroline-phosphine ligands
  作者：Fung Lam、Kin Shing Chan、Bang-Ji Liu

  DOI：10.1016/0040-4039(95)01254-f

  日期：1995.8

  The novel phenolic bridged dinucleating phenanthroline-pyridine 10 and phenanthroline-phosphine 15 ligands have been synthesized from 1,10-phenanthroline.
• MODIFIED METAL COMPLEX AND USE THEREOF
  申请人：Matsunaga Tadafumi

  公开号：US20100105909A1

  公开（公告）日：2010-04-29

  A modified metal complex obtained by subjecting a metal complex containing an organic compound having one nitrogen-containing aromatic heterocycle and four or more structures of a phenol, thiophenol, aniline or nitrogen-containing aromatic heterocyclic ring or an organic compound having two or more phenol rings and three or more nitrogen-containing aromatic heterocycles, in its molecule as a ligand, to a heating, radiation irradiation or discharge treatment until a mass reduction rate after the treatment becomes from 1 to 90 mass %, thereby the complex shows a carbon content after the treatment of 5 mass % or more.