bis(2-isopropyl-5-methylphenyl) chlorothiophosphate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: bis(2-isopropyl-5-methylphenyl) chlorothiophosphate
• 英文别名: chloro-bis(5-methyl-2-propan-2-ylphenoxy)-sulfanylidene-λ5-phosphane
• 化学式: C₂₀H₂₆ClO₂PS
• 分子量: 396.918
• InChiKey: UTNFREFSPKBWHP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.6
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.4
• 拓扑面积：
  50.6
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  百里酚 生成 bis(2-isopropyl-5-methylphenyl) chlorothiophosphate
  参考文献：
  名称：

  Bis(dialkylthiophosphoryl)amines as metal extractants

  摘要：

  一种从金属盐水溶液中提取金属价值，特别是锌价值的方法，包括将水溶液与含有以下化合物的有机相接触：其中R.sup.1、R.sup.2、R.sup.3和R.sup.4中的每一个独立地代表一个可选择取代的烃基或烃氧基，或者R.sup.1和R.sup.2连同所连接的磷原子和/或R.sup.3和R.sup.4连同所连接的磷原子形成一个5-至8-成员杂环。

  公开号：

  US05502250A1

文献信息

• Process for extracting metals
  申请人：Zeneca Limited

  公开号：US05393431A1

  公开（公告）日：1995-02-28

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently, represents a substituted hydrocarbyl or hydrocarbyloxy group or R.sup.1 and R.sup.2 together with the attached phosphorus atom and/or R.sup.3 and R.sup.4 together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  一种从金属盐水溶液中提取金属价值，特别是锌价值的过程，其包括将水溶液与含有下式化合物的有机相接触：##STR1## 其中R.sup.1、R.sup.2、R.sup.3和R.sup.4中的每个都独立地表示取代的烃基或烃氧基，或者R.sup.1和R.sup.2与所附磷原子一起，或者R.sup.3和R.sup.4与所附磷原子一起形成一个5-至8-成员杂环环。
• Process for extracting metal values from aqueous solution
  申请人：Zeneca Limited

  公开号：US05433855A1

  公开（公告）日：1995-07-18

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R.sup.1 and R.sup.2 together with the attached phosphorus atom and/or R.sup.3 and R.sup.4 together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  一种从金属盐的水溶液中提取金属价值，尤其是锌价值的过程，包括将水溶液与包含以下化合物的有机相接触：##STR1## 其中每个R1、R2、R3和R4独立地表示可选取代的烃基或烃氧基，或者R1和R2与所连接的磷原子以及/或R3和R4与所连接的磷原子形成5-至8-成员杂环环。
• Alkylphenoxy substituted bis (thio phosphoryl) amines
  申请人：Zeneca Limited

  公开号：US05557003A1

  公开（公告）日：1996-09-17

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R.sup.1 and R.sup.2 together with the attached phosphorus atom and/or R.sup.3 and R.sup.4 together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  从金属盐的水溶液中提取金属价值，特别是锌价值的方法，包括将水溶液与含有以下化合物的有机相接触：##STR1## 其中每个R1、R2、R3和R4独立地表示可选取代的烃基或烃氧基，或者R1和R2与所连接的磷原子以及/或R3和R4与所连接的磷原子形成5-至8-成员杂环环。
• Chemical process
  申请人：Zeneca Limited

  公开号：US05728853A1

  公开（公告）日：1998-03-17

  A process for extracting metal values, especially zinc values, from aqueous solutions of metal salts, which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula, ##STR1## wherein each of R.sup.1, R.sup.2, R.sup.3 and R.sup.4, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R.sup.1 and R.sup.2 together with the attached phosphorus atom and/or R.sup.3 and R.sup.4 together with the attached phosphorus atom from a 5- to 8-membered heterocyclic ring.

  一种从金属盐的水溶液中提取金属价值，特别是锌价值的方法，包括将水溶液与一个有机相接触，所述有机相包括下式化合物：##STR1## 其中，R.sup.1，R.sup.2，R.sup.3和R.sup.4分别独立地表示可选取代的烃基或烃氧基，或R.sup.1和R.sup.2与所附的磷原子以及/或R.sup.3和R.sup.4与所附的磷原子形成5-至8-成员杂环环。
• Process for extracting metal values
  申请人：ZENECA LIMITED

  公开号：EP0573182A1

  公开（公告）日：1993-12-08

  A process for extracting metal values especially zinc values from aqueous solutions of metal salts which comprises contacting the aqueous solution with an organic phase comprising a compound of the formula: wherein each of R¹, R², R³ and R⁴, independently, represents an optionally substituted hydrocarbyl or hydrocarbyloxy group or R¹ and R² together with the attached phosphorus atom and/or R³ and R⁴ together with the attached phosphorus atom form a 5- to 8-membered heterocyclic ring.

  一种从金属盐水溶液中提取金属值，特别是锌值的工艺，包括将水溶液与含有式化合物的有机相接触： 其中 R¹、R²、R³ 和 R⁴ 各自独立地代表任选取代的烃基或烃氧基，或 R¹ 和 R² 与所连接的磷原子和/或 R³ 和 R⁴ 与所连接的磷原子一起形成 5 至 8 元杂环。