1-(propylthio)octan-2-ol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(propylthio)octan-2-ol
• 英文别名: 1-propylsulfanyl-octan-2-ol；1-Propylmercapto-octan-2-ol；1-propylsulfanyloctan-2-ol
• 化学式: C₁₁H₂₄OS
• 分子量: 204.377
• InChiKey: CUIPBPUKGDZTQC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  13
• 可旋转键数：
  9
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  45.5
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  聚合甲醛 、 1-(propylthio)octan-2-ol 、 二正丁胺 以 苯 为溶剂， 以78%的产率得到1-(propylthio)-2-(N,N-diethylaminomethyleneoxy)octane
  参考文献：
  名称：

  Synthesis and properties of methyleneoxyamine derivatives of 1-(propylthio)octane

  摘要：

  Synthesis of new methyleneoxyamine derivatives of 1-(propylthio)octane by condensation of 1-(propylthio)octane with secondary amines and formaldehyde was carried out. Structure of the synthesized compounds was proved by elemental analysis, IR, (1)H NMR, and mass spectra. Compounds were tested as antimicrobial additives to lubricating oils. They were found to suppress effectively the activity of microorganisms.

  DOI：

  10.1134/s107036321005018x
• 作为产物：
  描述：

  丙烷-1-硫醇 、 1-溴辛烷-2-醇 在 sodium hydroxide 作用下， 以 水 为溶剂， 以74%的产率得到1-(propylthio)octan-2-ol
  参考文献：
  名称：

  Synthesis and properties of methyleneoxyamine derivatives of 1-(propylthio)octane

  摘要：

  Synthesis of new methyleneoxyamine derivatives of 1-(propylthio)octane by condensation of 1-(propylthio)octane with secondary amines and formaldehyde was carried out. Structure of the synthesized compounds was proved by elemental analysis, IR, (1)H NMR, and mass spectra. Compounds were tested as antimicrobial additives to lubricating oils. They were found to suppress effectively the activity of microorganisms.

  DOI：

  10.1134/s107036321005018x

文献信息

• REACTIONS OF ATOMS AND FREE RADICALS IN SOLUTION. XXV. THE REACTIONS OF OLEFINS WITH MERCAPTANS IN THE PRESENCE OF OXYGEN¹
  作者：M. S. KHARASCH、W. NUDENBERG、G. J. MANTELL

  DOI：10.1021/jo01144a005

  日期：1951.4
• Synthesis and properties of methyleneoxyamine derivatives of 1-(propylthio)octane
  作者：E. G. Mamedbeyli、I. A. Dzhafarov、K. A. Kochetkov、T. G. Kyazimova、Kh. I. Gasanov

  DOI：10.1134/s107036321005018x

  日期：2010.5

  Synthesis of new methyleneoxyamine derivatives of 1-(propylthio)octane by condensation of 1-(propylthio)octane with secondary amines and formaldehyde was carried out. Structure of the synthesized compounds was proved by elemental analysis, IR, (1)H NMR, and mass spectra. Compounds were tested as antimicrobial additives to lubricating oils. They were found to suppress effectively the activity of microorganisms.