3-(2,4-dihydroxy-phenyl)-cis-crotonic acid

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 肉桂酸及其衍生物
• 英文名称: 3-(2,4-dihydroxy-phenyl)-cis-crotonic acid
• 英文别名: 3-(2,4-dihydroxy-phenyl)-crotonic acid；3-(2,4-Dihydroxy-phenyl)-cis-crotonsaeure；β-(2.4-Dioxy-phenyl)-α-propylen-α-carbonsaeure；2.4-Dioxy-β-methyl-zimtsaeure；β-(2.4-Dioxy-phenyl)-crotonsaeure；3-(2,4-Dihydroxy-phenyl)-crotonsaeure；(E)-3-(2,4-dihydroxyphenyl)but-2-enoic acid
• 化学式: C₁₀H₁₀O₄
• 分子量: 194.187
• InChiKey: RFIVODDCFKVRBD-GQCTYLIASA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.8
• 重原子数：
  14
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  77.8
• 氢给体数：
  3
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  3-(2,4-dihydroxy-phenyl)-cis-crotonic acid 生成 羟甲香豆素
  参考文献：
  名称：

  Murty; Rao; Seshadri, Proceedings - Indian Academy of Sciences, Section A, 1937, vol. 6, p. 316,323

  摘要：

  DOI：
• 作为产物：
  描述：

  羟甲香豆素 在 sodium hydroxide 、 mercury(II) oxide 作用下， 生成 3-(2,4-dihydroxy-phenyl)-cis-crotonic acid
  参考文献：
  名称：

  Murty; Rao; Seshadri, Proceedings - Indian Academy of Sciences, Section A, 1937, vol. 6, p. 316,323

  摘要：

  DOI：

文献信息

• Photo-labile pro-fragrance conjugates
  申请人：The Procter & Gamble Company

  公开号：US20020094938A1

  公开（公告）日：2002-07-18

  The present invention relates to photo-labile pro-fragrance conjugates comprising: a) a photo-labile unit which upon exposure to electromagnetic radiation is capable of releasing a pro-fragrance unit; and b) a pro-fragrance unit, which when so released is either i) a pro-fragrance compound capable of releasing a fragrance raw material; or ii) a fragrance raw material. The present invention relates to systems for delivering fragrances to a situs, and to laundry detergent compositions, fine fragrances, personal care and hair care compositions comprising said systems.

  本发明涉及光敏性前香精偶联物，包括：a）光敏性单元，当暴露于电磁辐射时能够释放前香精单元；以及b）前香精单元，当被释放时，要么是i）能够释放香料原料的前香精化合物；要么是ii）香料原料。本发明涉及用于将香料传递到特定位置的系统，以及包括所述系统的洗涤剂组合物、精致香水、个人护理和头发护理组合物。
• Compositions comprising photo-labile perfume delivery systems
  申请人：The Procter & Gamble Company

  公开号：US20030125220A1

  公开（公告）日：2003-07-03

  The present invention relates to photo-labile pro-fragrances, as well as a fragrance raw material delivery system comprising: i) from about 0.001% to about 100% by weight, of a photo-labile pro-fragrance compound having the formula: 1 wherein OR is a unit derived from a fragrance raw material alcohol, HOR; R 1 is one or more electron donating groups; each R 2 is independently hydrogen, C 1 -C 12 alkyl, and mixtures thereof; X is selected from the group consisting of —OH, —NH 2 , —NHR 3 , and mixtures thereof; R 3 is hydrogen, C 1 -C 12 linear or branched alkyl, C 6 -C 10 aryl, and mixtures thereof; and ii) optionally from about 0.001% to about 50% by weight, of one or more fragrance raw materials.

  本发明涉及光敏感前香料，以及一种香料原料传递系统，包括：i）约0.001%至约100%重量的光敏感前香料化合物，其具有以下公式：1，其中OR是从香料原料醇HOR导出的单位；R1是一个或多个电子给体基团；每个R2独立地是氢、C1-C12烷基或其混合物；X选择自—OH、—NH2、—NHR3和其混合物的群；R3是氢、C1-C12线性或支链烷基、C6-C10芳基或其混合物；以及ii）可选地，约0.001%至约50%重量的一种或多种香料原料。
• Compositions comprising photo-labile perfume delivery
  申请人：Dykstra Richard Robert

  公开号：US20050014663A1

  公开（公告）日：2005-01-20

  The present invention relates to photo-labile pro-fragrances, as well as a fragrance raw material delivery system comprising: i) from about 0.001% to about 100% by weight, of a photo-labile pro-fragrance compound having the formula: wherein OR is a unit derived from a fragrance raw material alcohol, HOR; R 1 is one or more electron donating groups; each R 2 is independently hydrogen, C 1 -C 12 alkyl, and mixtures thereof; X is selected from the group consisting of —OH, —NH 2 , —NHR 3 , and mixtures thereof; R 3 is hydrogen, C 1 -C 12 linear or branched alkyl, C 6 -C 10 aryl, and mixtures thereof; and ii) optionally from about 0.001% to about 50% by weight, of one or more fragrance raw materials.

  本发明涉及光敏感的前香料，以及一种包括以下成分的香料原料传递系统：i）约占重量的0.001％至约100％的光敏感的前香料化合物，该化合物的化学式为：其中OR是来自香料原料醇HOR的单位；R1是一个或多个电子供体基团；每个R2独立地是氢、C1-C12烷基或其混合物；X选自羟基（—OH）、氨基（—NH2）、NHR3（其中R3为氢、C1-C12线性或支链烷基、C6-C10芳基或其混合物）的群；以及ii）可选的约占重量的0.001％至约50％的一个或多个香料原料。
• PHOTO-LABILE PRO-FRAGRANCE CONJUGATES
  申请人：Dykstra Robert Richard

  公开号：US20100040569A1

  公开（公告）日：2010-02-18

  The present invention relates to photo-labile pro-fragrance conjugates comprising: a) a photo-labile unit which upon exposure to electromagnetic radiation is capable of releasing a pro-fragrance unit; and b) a pro-fragrance unit, which when so released is either i) a pro-fragrance compound capable of releasing a fragrance raw material; or ii) a fragrance raw material. The present invention relates to systems for delivering fragrances to a situs, and to laundry detergent compositions, fine fragrances, personal care and hair care compositions comprising said systems.

  本发明涉及光敏性前芳香物质偶联物，包括：a）光敏性单元，当暴露于电磁辐射时，能够释放出前芳香物质单元；和b）前芳香物质单元，当被释放时，可以是：i）能够释放出香料原料的前芳香化合物；或者ii）香料原料。本发明涉及用于向特定位置提供香气的系统，以及包括该系统的洗涤剂组合物、精致香水、个人护理和发护理组合物。
• COMPOSITIONS COMPRISING PHOTO-LABILE
  申请人：THE PROCTER & GAMBLE COMPANY

  公开号：EP1432784A1

  公开（公告）日：2004-06-30