5,12-diphenylquinolino[2,3-b]acridine-7,14(5H,12H)-dione

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 5,12-diphenylquinolino[2,3-b]acridine-7,14(5H,12H)-dione
• 英文别名: 5,12-diphenyl-5,12-dihydro-quino[2,3-b]acridine-7,14-dione；5,12-Diphenyl-5,12-dihydro-chino[2,3-b]acridin-7,14-dion；quino[2,3-b]acridine-7,14-dione, 5,12-dihydro-5,12-diphenyl；N,N'-diphenylquinacridone；N,N-diphenylquinacridone；5,12-diphenylquinolino[2,3-b]acridine-7,14-dione
• 化学式: C₃₂H₂₀N₂O₂
• 分子量: 464.523
• InChiKey: HKHMXTFNINVDFI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.4
• 重原子数：
  36
• 可旋转键数：
  2
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  40.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  dimethyl 2,5-bis(diphenylamino)terephthalate 在 甲烷磺酸 作用下， 反应 4.0h， 以95%的产率得到5,12-diphenylquinolino[2,3-b]acridine-7,14(5H,12H)-dione
  参考文献：
  名称：

  Synthesis for quinacridone compounds

  摘要：

  本文披露了一种形成N,N'-二芳基喹诺啉酮化合物的过程，包括步骤是将1,4-二烷基羧酸酯-2,5-双(N-芳基氨基)苯与碘芳基化合物反应，形成相应的2,5-双(N-二芳基氨基)化合物。该过程具有多功能性，可高产率、高纯度地合成N,N'-二芳基喹诺啉酮化合物。

  公开号：

  US20040002605A1

文献信息

• COMPOUNDS FOR ELECTRONIC DEVICES
  申请人：Parham Amir Hossain

  公开号：US20120292576A1

  公开（公告）日：2012-11-22

  The present invention relates to compounds of the formula (I) and to the use thereof in organic electronic devices, and to organic electronic devices which comprise compounds of the formula (I), preferably as hole-transport materials and/or as matrix materials, in particular in combination with a further matrix material.

  本发明涉及式(I)的化合物及其在有机电子器件中的应用，以及包括式(I)化合物的有机电子器件，优选作为空穴传输材料和/或作为基质材料，特别是与另一种基质材料结合使用。
• Carbazole Derivative and Method for Producing the Same
  申请人：Suzuki Hiroki

  公开号：US20100076201A1

  公开（公告）日：2010-03-25

  To provide a method for producing a wide variety of carbazole derivatives which have a simple and uncomplicated process and in which variations in the yield, purity, etc. of a desired substance which are caused by an aryl group introduced is reduced as much as possible. A method for producing a carbazole derivative represented by General Formula (1) is provided, in which 9-[4-(10-phenyl-9-anthryl)phenyl]-9H-carbazole having an active site at the 3-position of the carbazole skeleton and an aromatic compound having an active site are coupled. In the formula, Ar 1 represents an aryl group with 6 to 13 carbon atoms in a ring, and Ar 1 may have a substituent.

  提供一种生产多种各异的咔唑衍生物的方法，该方法具有简单和不复杂的过程，并尽量减少由引入的芳基团引起的所需物质的产量、纯度等变化。提供了一种生产由通用公式（1）表示的咔唑衍生物的方法，其中9-[4-(10-苯基-9-蒽基)苯基]-9H-咔唑在咔唑骨架的3位具有活性位点，并且与具有活性位点的芳香化合物偶联。在公式中，Ar1代表一个具有6到13个碳原子的环的芳基团，Ar1可能有取代基。
• New quinacridone derivatives: Synthesis, photophysical and third-order nonlinear optical properties
  作者：Jianhong Jia、Dong Feng、Yangcheng Sha、Chunsong Zhou、Guanqiu Liang、Yuanbin She

  DOI：10.1016/j.tet.2020.131057

  日期：2020.4

  quinacridone third-order nonlinear optical chromophores containing phenyl, 4-methoxyphenyl and N,N-bis(4-methoxyphenyl)aniline groups were designed and synthesized. The optical properties, electrical properties, theoretical calculations and Z-Scan of the compounds were measured and analyzed to investigate the relationship between structure and third-order NLO properties. The experimental results showed

  设计并合成了一系列含苯基，4-甲氧基苯基和N，N-双（4-甲氧基苯基）苯胺基的喹ac啶酮三阶非线性发色团。测量并分析了化合物的光学性质，电性质，理论计算和Z-扫描，以研究结构与三阶NLO性质之间的关系。实验结果表明，在喹ac啶酮的N位置引入供电子基团可减少分子的最高占据分子轨道（HOMO）与最低未占据分子轨道（LUMO）之间的能隙（E gap），并且促进分子内电荷转移（ICT）。含N，N的喹Quin啶酮衍生物-双（4-甲氧基苯基）苯胺具有良好的三阶非线性光学特性，其非线性吸收系数（β）值为1.4319×10 -13，二阶超极化率（γ）为2.6849×10 -33  esu。
• [EN] CARBAZOLE DERIVATIVE, LIGHT-EMITTING ELEMENT MATERIAL, LIGHT-EMITTING ELEMENT, AND LIGHT-EMITTING DEVICE<br/>[FR] DÉRIVÉ DE CARBAZOLE, SUBSTANCE D'ÉLÉMENT ÉLECTROLUMINESCENT, ÉLÉMENT ÉLECTROLUMINESCENT, ET DISPOSITIF ÉLECTROLUMINESCENT
  申请人：SEMICONDUCTOR ENERGY LAB

  公开号：WO2010005066A1

  公开（公告）日：2010-01-14

  ABSTRACT An object is to provide a carbazole derivative which has a wide band gap and with which excellent blue color purity is obtained. In addition, another object is to provide highly reliable light-emitting elements, light-emitting devices, lighting devices, and electronic devices in which the carbazole derivative is used. Carbazole derivatives represented by the general formulas (1), (P1), and (M1) are provided. Further, light-emitting elements, light-emitting devices, and electronic devices which are formed using the carbazole derivative represented any of the general formulas (1), (P1), and (M1) are provided.

  摘要：本文旨在提供一种具有宽带隙并具有优异蓝色纯度的咔唑衍生物。此外，另一个目标是提供使用该咔唑衍生物的高可靠性发光元件、发光装置、照明装置和电子装置。提供了由通用公式（1）、（P1）和（M1）表示的咔唑衍生物。此外，提供了使用由通用公式（1）、（P1）和（M1）表示的咔唑衍生物形成的发光元件、发光装置和电子装置。
• [EN] MATERIALS FOR ORGANIC ELECTROLUMINESCENT DEVICES<br/>[FR] MATÉRIAUX POUR DISPOSITIFS ÉLECTROLUMINESCENTS ORGANIQUES
  申请人：MERCK PATENT GMBH

  公开号：WO2017207596A1

  公开（公告）日：2017-12-07

  The present invention relates to compounds of the formula (1) which are suitable for use in electronic devices, in particular organic electroluminescent devices, and to electronic devices, which comprise these compounds.

  本发明涉及式（1）的化合物，其适用于电子器件，尤其是有机电致发光器件，并且涉及包括这些化合物的电子器件。