1-(2-hexyl-4-methoxy-phenyl)-ethanone

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(2-hexyl-4-methoxy-phenyl)-ethanone
• 英文别名: 1-(2-Hexyl-4-methoxyphenyl)ethanone；1-(2-hexyl-4-methoxyphenyl)ethanone
• 化学式: C₁₅H₂₂O₂
• 分子量: 234.338
• InChiKey: VQQUGEWWODJMDP-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  17
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.53
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  1-己烯 、 苯甲胺,N-[1-(4-甲氧苯基)亚乙基]- 在 [(C₈H₁₄)2RhCl]2 5-hexyl-2,4,6-triaminopyrimidine 、 5-(4-Ph₂P-benzyl)-4-n-decyl-hexahydropyrimidine-2,4,6-trione 、 盐酸 作用下， 以 1,4-二氧六环 、 四氢呋喃 、 正戊烷 为溶剂， 反应 14.0h， 以98%的产率得到1-(2-hexyl-4-methoxy-phenyl)-ethanone
  参考文献：
  名称：

  Recyclable Self-Assembly-Supported Catalytic System for Orthoalkylation

  摘要：

  A new recyclable supported catalyst system for orthoalkylation was devised using a self-assembly consisting of the barbiturate and 2,4,6-triaminopyrimidine H-bonding motifs. At high temperature, the system is completely homogeneous so as to give an efficient catalytic activity, while it is heterogenized at room temperature to form an insoluble solid phase for the easy recovery of the catalyst after the reaction.

  DOI：

  10.1021/ol050865n

文献信息

• Recyclable Self-Assembly-Supported Catalytic System for Orthoalkylation
  作者：Jong Huem Yoon、Young Jun Park、Jun Hee Lee、Jaeho Yoo、Chul-Ho Jun

  DOI：10.1021/ol050865n

  日期：2005.7.1

  A new recyclable supported catalyst system for orthoalkylation was devised using a self-assembly consisting of the barbiturate and 2,4,6-triaminopyrimidine H-bonding motifs. At high temperature, the system is completely homogeneous so as to give an efficient catalytic activity, while it is heterogenized at room temperature to form an insoluble solid phase for the easy recovery of the catalyst after the reaction.