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Ethyl-(tetrahydro-3-methoxy-4,5-dioxafuran)-3-carboxylat

中文名称
——
中文别名
——
英文名称
Ethyl-(tetrahydro-3-methoxy-4,5-dioxafuran)-3-carboxylat
英文别名
Ethyl 3-methoxy-4,5-dioxooxolane-3-carboxylate
Ethyl-(tetrahydro-3-methoxy-4,5-dioxafuran)-3-carboxylat化学式
CAS
——
化学式
C8H10O6
mdl
——
分子量
202.164
InChiKey
UCSZGTDUVJLKBQ-UHFFFAOYSA-N
BEILSTEIN
——
EINECS
——
  • 物化性质
  • 计算性质
  • ADMET
  • 安全信息
  • SDS
  • 制备方法与用途
  • 上下游信息
  • 反应信息
  • 文献信息
  • 表征谱图
  • 同类化合物
  • 相关功能分类
  • 相关结构分类

计算性质

  • 辛醇/水分配系数(LogP):
    0
  • 重原子数:
    14
  • 可旋转键数:
    4
  • 环数:
    1.0
  • sp3杂化的碳原子比例:
    0.62
  • 拓扑面积:
    78.9
  • 氢给体数:
    0
  • 氢受体数:
    6

反应信息

  • 作为反应物:
    描述:
    Ethyl-(tetrahydro-3-methoxy-4,5-dioxafuran)-3-carboxylat硫酸 作用下, 以 为溶剂, 反应 3.0h, 以72.4%的产率得到3-Hydroxy-4-methoxy-2(5H)-furanon
    参考文献:
    名称:
    Chemie freier cyclischer vicinaler Tricarbonyl-Verbindungen (‘1,2,3-Trione') Teil 2. Redox-Reaktionen von 1,2,3-Trionen mit En-1,2-diolen (‘Reduktonen'), 2-Alkoxy-en-1-olen, En-1,2-diaminen und verwandten Spezies Für Teil 1, s. [1].
    摘要:
    Chemistry of Free Cyclic Vicinal Tricarbonyl Compounds ('1,2,3-Triones'). Part 2. Redox Reactions of 1,2,3-Triones with Ene-1,2-diols ('Reductones'), 2-Alkoxy-en-1-ols, Ene-1,2-diamines, and Related SpeciesMidstanding carbonyl groups of cyclic 1,2,3-triones 4 possess outstanding electrophilic (elcctron-pair accepting) as well as oxidizing (one-electron accepting) properties. Their reactions with selected electron-rich C C bonds as efficient nucleophiles (AN reactions) and as efficient reducing agents (SET (single electron transfer) reactions) are studied. In a few cases, short-lived charge-transfer colors could be observed. Particularly, free didehydro-5,6-0-isopropyliden-L-ascorbic acid (4g), its 0,C-adduct 8g to 5,6-O-isopropylidene-(L)-ascorbic acid (1g), and - via an independent pathway - the ostensible C,C-dimer 10a of mono-dehydrodimedone reductone were prepared. Intermediate radical anions 4- can be considered to be ideal representatives of dicapto-dative radicals. Novel large-scale syntheses of 3,4-dihydroxyfuran-2(5H)-one (1e) and of its vicinal trione 4e are presented.
    DOI:
    10.1002/1522-2675(200205)85:5<1295::aid-hlca1295>3.0.co;2-k
  • 作为产物:
    描述:
    三聚甲醛 、 Diethyl-(1-hydroxy-2-methoxyethen-1,2-dicarboxylat) 在 sodium hydride 作用下, 以 乙腈 为溶剂, 反应 7.0h, 以73%的产率得到Ethyl-(tetrahydro-3-methoxy-4,5-dioxafuran)-3-carboxylat
    参考文献:
    名称:
    Chemie freier cyclischer vicinaler Tricarbonyl-Verbindungen (‘1,2,3-Trione') Teil 2. Redox-Reaktionen von 1,2,3-Trionen mit En-1,2-diolen (‘Reduktonen'), 2-Alkoxy-en-1-olen, En-1,2-diaminen und verwandten Spezies Für Teil 1, s. [1].
    摘要:
    Chemistry of Free Cyclic Vicinal Tricarbonyl Compounds ('1,2,3-Triones'). Part 2. Redox Reactions of 1,2,3-Triones with Ene-1,2-diols ('Reductones'), 2-Alkoxy-en-1-ols, Ene-1,2-diamines, and Related SpeciesMidstanding carbonyl groups of cyclic 1,2,3-triones 4 possess outstanding electrophilic (elcctron-pair accepting) as well as oxidizing (one-electron accepting) properties. Their reactions with selected electron-rich C C bonds as efficient nucleophiles (AN reactions) and as efficient reducing agents (SET (single electron transfer) reactions) are studied. In a few cases, short-lived charge-transfer colors could be observed. Particularly, free didehydro-5,6-0-isopropyliden-L-ascorbic acid (4g), its 0,C-adduct 8g to 5,6-O-isopropylidene-(L)-ascorbic acid (1g), and - via an independent pathway - the ostensible C,C-dimer 10a of mono-dehydrodimedone reductone were prepared. Intermediate radical anions 4- can be considered to be ideal representatives of dicapto-dative radicals. Novel large-scale syntheses of 3,4-dihydroxyfuran-2(5H)-one (1e) and of its vicinal trione 4e are presented.
    DOI:
    10.1002/1522-2675(200205)85:5<1295::aid-hlca1295>3.0.co;2-k
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文献信息

  • Chemie freier cyclischer vicinaler Tricarbonyl-Verbindungen (‘1,2,3-Trione') Teil 2. Redox-Reaktionen von 1,2,3-Trionen mit En-1,2-diolen (‘Reduktonen'), 2-Alkoxy-en-1-olen, En-1,2-diaminen und verwandten Spezies Für Teil 1, s. [1].
    作者:Kurt Schank、Günter Bouillon、Michael Fünfrocken、Carlo Lick、Robert Lieder
    DOI:10.1002/1522-2675(200205)85:5<1295::aid-hlca1295>3.0.co;2-k
    日期:2002.5
    Chemistry of Free Cyclic Vicinal Tricarbonyl Compounds (‘1,2,3-Triones'). Part 2. Redox Reactions of 1,2,3-Triones with Ene-1,2-diols (‘Reductones'), 2-Alkoxy-en-1-ols, Ene-1,2-diamines, and Related Species. Midstanding carbonyl groups of cyclic 1,2,3-triones 4 possess outstanding electrophilic (electron-pair accepting) as well as oxidizing (one-electron accepting) properties. Their reactions with
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