tris(2,4,6-trimethylphenyl)phosphite

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: tris(2,4,6-trimethylphenyl)phosphite
• 英文别名: Tris(2,4,6-trimethylphenyl) phosphite
• 化学式: C₂₇H₃₃O₃P
• 分子量: 436.531
• InChiKey: MKIKRHDTUXBFJO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.8
• 重原子数：
  31
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  tris(2,4,6-trimethylphenyl)phosphite 在 双氧水 作用下， 以 二甲基亚砜 、 甲苯 为溶剂， 反应 0.5h， 以39 mg的产率得到trimesityl phosphate
  参考文献：
  名称：

  二苯二硒化物催化白磷合成亚磷酸三芳基酯和磷酸三芳基酯

  摘要：

  工业上重要的亚磷酸三芳基酯，传统上由 PCl 3制备，已通过涉及白磷和苯酚的二苯基二硒化物催化一步法合成，这为这些化合物提供了一种不含卤素和过渡金属的方法。随后亚磷酸三芳基酯氧化产生磷酸三芳基酯和硫代磷酸三芳基酯。三硫代磷酸酯也可以由芳香族硫醇和脂肪族硫醇有效地制备。

  DOI：

  10.1021/acs.orglett.1c01695
• 作为产物：
  描述：

  2,4,6-三甲酚 在 potassium phosphate 、 二苯基二硒醚 、 phosphorus 作用下， 以 二甲基亚砜 、 甲苯 为溶剂， 反应 6.0h， 生成 tris(2,4,6-trimethylphenyl)phosphite
  参考文献：
  名称：

  二苯二硒化物催化白磷合成亚磷酸三芳基酯和磷酸三芳基酯

  摘要：

  工业上重要的亚磷酸三芳基酯，传统上由 PCl 3制备，已通过涉及白磷和苯酚的二苯基二硒化物催化一步法合成，这为这些化合物提供了一种不含卤素和过渡金属的方法。随后亚磷酸三芳基酯氧化产生磷酸三芳基酯和硫代磷酸三芳基酯。三硫代磷酸酯也可以由芳香族硫醇和脂肪族硫醇有效地制备。

  DOI：

  10.1021/acs.orglett.1c01695
• 作为试剂：
  描述：

  non-1-en-8-yn-5-one 在 2,6-二甲基吡啶 、 tris(dibenzylideneacetone)dipalladium(0) chloroform complex 、 溶剂黄146 、 tris(2,4,6-trimethylphenyl)phosphite 作用下， 以 四氢呋喃 、 二氯甲烷 、 苯 为溶剂， 反应 49.5h， 生成 3-(3'-butenyl)-3-(tert-butyldimethylsiloxy)-6-methylenecyclohexene
  参考文献：
  名称：

  Palladium-catalyzed cyclizations of polyenynes. A palladium zipper

  摘要：

  The cycloisomerization of polyenynes with a catalyst derived from Pd(0), acetic acid, and a ligand to polycycles depends upon the juxtaposition of unsaturation. The process involves the stages of initiation (by addition of Pd-H to an acetylene), propagation (by intramolecular carbopalladation), and termination (by beta-hydrogen elimination). With 2-homopropargylated 1,5- and 1,6-dienes, monocyclizations via 5-exo and 6-endo modes dominate with the ratio dependent upon ligand. The 5-exo mode is favored by tri-o-tolylphosphine, whereas triphenylstibine favors the 6-endo mode. On the other hand, a 3-homoallyl-3-homopropargylcyclopentene undergoes smooth bicyclization even when triphenylphosphine is used as ligand. Combining Pd(0)-catalyzed allylic alkylation to make the substrates with Pd(0)-catalyzed cycloisomerization simplifies triquinane and azatriquinane synthesis. A2-allyl-2-homopropargyl-1-methylenecycloalkane array cycloisomerizes to [4.3.3]propellanes and [3.3.3]propellanes. Methallyl alcohol serves as a basic building block to construct acyclic substrates for construction of spirocycles. Both terminal and internal acetylenes serve as suitable initiators provided the proper ligand is employed. With a terminal acetylene as initiator, triphenylphosphine proves satisfactory, but an internal acetylene requires triphenylstibine. High diastereoselectivity may accompany formation of the spirocycle. Increasing the number of double bonds increases the number of rings formed. Substrates bearing 3, 4, 5, 6, and 7 double bonds generate polyspiranes consisting of 3, 4, 5, 6, and 7 rings. The regio- and diastereoselectivity may be understood on the basis of a conformational analysis of the reactive intermediate. This atom economical approach for construction of polycycles can be considered as the equivalent of a palladium zipper in which the pi orbitals are the teeth and the palladium complex is the tab. Closing the zipper stitches the pi bonds into sigma bonds with creation of the polycycles.

  DOI：

  10.1021/ja00074a008

文献信息

• The reaction of tertiary aryl phosphites with diiodine at ambient temperatures; structural characterisation of the tertiary phosphite tetraiodides (PhO)3PI4, (4-MeC6H4O)3PI4 and (2,4-But2C6H3O)3PI4
  作者：Stephen M. Godfrey、Charles A. McAuliffe、Andrew T. Peaker、Robin G. Pritchard

  DOI：10.1039/a909057f

  日期：——

  The reaction of the tertiary phosphites (RO)3P (R = Ph, 4-MeC6H4, 4-ButC6H4, 2,4-But2C6H3, 2,6-Me2C6H3, 2,4,6-Me3C6H2 or 2-PhC6H4) with one and two mole equivalents of diiodine has been investigated. In all cases the tetra-iodide compounds (RO)3PI4 were isolated regardless of the stoichiometry employed. The three compounds (RO)3PI4 (R = Ph, 4-MeC6H4 or 2,4-But2C6H3) have been crystallographically characterised

  第三亚磷酸酯的反应（RO）3 P（R = PH，4-MEC 6 ħ 4，4-卜吨Ç 6 ħ 4，2,4-卜吨2 ç 6 ħ 3，2,6-ME 2 ç 6 ħ 3，2,4,6--ME 3 c ^ 6 ħ 2或2-PHC 6 ħ 4）与二碘的一个和两个摩尔当量进行了研究。在所有情况下，无论采用何种化学计量，都分离出四碘化物（RO）3 PI 4。三种化合物（RO）为了比较的目的，已经对3 PI 4（R = Ph，4-MeC 6 H 4或2,4-Bu t 2 C 6 H 3）进行了结晶表征，并代表了该式化合物的晶体结构的第一个实例。这些化合物的结构表征说明了（RO） 3 PI 4化合物对R的结构依赖性。对于（RO） 3 PI 4（R = Ph或2,4-Bu t 2 C 6 H 3），这些化合物以离散形式存在分子种类，而对于R = 4-MeC 6 H 4离散分子的三碘化物片段通过长距离的I–I相互作
• Hindered phenol phosphites
  申请人：General Electric Company

  公开号：US04276233A1

  公开（公告）日：1981-06-30

  Thermally stable polycarbonate compositions are obtained by admixing with a high molecular weight aromatic polycarbonate resin a stabilizing amount of a hindered phenol phosphite.

  通过与高分子量芳香族聚碳酸酯树脂混合一定量的受阻酚磷酸酯，可以获得热稳定的聚碳酸酯组合物。
• Process for preparing organic pentavalent phosphorus compounds
  申请人：DAIHACHI CHEMICAL INDUSTRY CO., LTD.

  公开号：EP0844249A1

  公开（公告）日：1998-05-27

  A process for preparing an organic pentavalent phosphorus compound comprising oxidizing an organic trivalent phosphorus compound with an aqueous hydrogen peroxide solution in the presence of an inorganic or organic base at a temperature of 0°C to 50°C to obtain the corresponding organic pentavalent phosphorus compound.

  一种制备有机五价磷化合物的工艺，包括在无机或有机碱存在下，在 0°C 至 50°C 的温度下，用过氧化氢水溶液氧化有机三价磷化合物，得到相应的有机五价磷化合物。
• Polymer electrolyte composition and fuel cell
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1289041A2

  公开（公告）日：2003-03-05

  A polymer electrolyte composition comprising a polymer electrolyte and at least one of antioxidant selected from a group which consists of a antioxidant containing tri-valent phosphorous and a sulfur-containing antioxidant is provided as a polymer electrolyte composition superior in radical resistance property.

  提供了一种聚合物电解质组合物，该组合物由聚合物电解质和至少一种抗氧化剂组成，抗氧化剂选自含三价磷的抗氧化剂和含硫抗氧化剂组成的组，是一种抗自由基性能优异的聚合物电解质组合物。
• POLYMER ELECTROLYTE COMPOSITION AND FUEL CELL
  申请人：Hidaka Yasuaki

  公开号：US20060257706A1

  公开（公告）日：2006-11-16

  A fuel cell containing a polymer electrolyte membrane, wherein the polymer electrolyte membrane contains a polymer electrolyte composition that contains a polymer electrolyte and at least one antioxidant selected from the group consisting of an antioxidant containing tri-valent phosphorous and an antioxidant containing sulfur.

  一种含有聚合物电解质膜的燃料电池，其中聚合物电解质膜含有聚合物电解质组合物，该组合物含有聚合物电解质和至少一种抗氧化剂，该抗氧化剂选自由含三价磷的抗氧化剂和含硫的抗氧化剂组成的组。