tetrahydrofurfuryl 2-(4,6-dimethoxypyrimidin-2-yl)oxybenzoate

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: tetrahydrofurfuryl 2-(4,6-dimethoxypyrimidin-2-yl)oxybenzoate
• 英文别名: oxolan-2-ylmethyl 2-(4,6-dimethoxypyrimidin-2-yl)oxybenzoate
• 化学式: C₁₈H₂₀N₂O₆
• 分子量: 360.367
• InChiKey: LFCATWJTKQLNQZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  26
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.39
• 拓扑面积：
  89
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为产物：
  描述：

  四氢糠醇 、 2,4,6-三异丙基苯磺酰氯 在 N-甲基咪唑 作用下， 以 四氢呋喃 为溶剂， 生成 tetrahydrofurfuryl 2-(4,6-dimethoxypyrimidin-2-yl)oxybenzoate
  参考文献：
  名称：

  Herbicidal pyrimidine compounds, compositions containing the same and

  摘要：

  具有以下式子的除草嘧啶化合物：##STR1## 其中取代基A、R.sup.1、R.sup.2、X、Y.sup.1、Y.sup.2、Y.sup.3和Z的定义如下。

  公开号：

  US05232897A1

文献信息

• Pyrimidine derivatives
  申请人：Sumitomo Chemical Company, Limited

  公开号：US05455355A1

  公开（公告）日：1995-10-03

  A pyrimidine herbicide derivative having the formula, ##STR1## wherein A is C.sub.3 -C.sub.6 oxacycloalkyl, C.sub.3 -C.sub.6 oxacycloalkyl substituted with at least one member selected from the group consisting of C.sub.1 -C.sub.6 alkyl and halogen, C.sub.2 -C.sub.6 oxacycloalkyl C.sub.1 -C.sub.6 alkyl, C.sub.2 -C.sub.6 oxacycloalkyl C.sub.1 -C.sub.6 alkyl substituted with at least one member selected from the group consisting of C.sub.1 -C.sub.6 alkyl and halogen, C.sub.3 -C.sub.5 dioxacycloalykyl, C.sub.3 -C.sub.5 dioxacycloalkyl substituted with at least one member selected from the group consisting of C.sub.1 -C.sub.6 alkyl and halogen, C.sub.3 -C.sub.5 dioxacycloalkyl C.sub.1 -C.sub.6 alkyl or C.sub.3 -C.sub.5 dioxacycloalkyl C.sub.1 -C.sub.6 alkyl substituted with at least one member selected from the group consisting of C.sub.1 -C.sub.6 alkyl and halogen; each of R.sup.1 and R.sup.2, which may be the same or different, is C.sub.1 -C.sub.6 alkyl, C.sub.1 -C.sub.6 alkoxy, halo C.sub.1 -C.sub.6 alkoxy or halogen; X is oxygen or sulfur; Z is nitrogen or CY.sup.4 ; and Y.sup.1-4 are described in the specification.

  一种嘧啶类除草剂衍生物，其化学式为##STR1##其中A是C.sub.3-C.sub.6氧杂环烷基，C.sub.3-C.sub.6氧杂环烷基，其至少被选自C.sub.1-C.sub.6烷基和卤素的一种成员取代，C.sub.2-C.sub.6氧杂环烷基C.sub.1-C.sub.6烷基，C.sub.2-C.sub.6氧杂环烷基C.sub.1-C.sub.6烷基，其至少被选自C.sub.1-C.sub.6烷基和卤素的一种成员取代，C.sub.3-C.sub.5二氧杂环烷基，C.sub.3-C.sub.5二氧杂环烷基，其至少被选自C.sub.1-C.sub.6烷基和卤素的一种成员取代，C.sub.3-C.sub.5二氧杂环烷基C.sub.1-C.sub.6烷基或C.sub.3-C.sub.5二氧杂环烷基C.sub.1-C.sub.6烷基，其至少被选自C.sub.1-C.sub.6烷基和卤素的一种成员取代；每个R.sup.1和R.sup.2，可以相同也可以不同，是C.sub.1-C.sub.6烷基，C.sub.1-C.sub.6烷氧基，卤素C.sub.1-C.sub.6烷氧基或卤素；X是氧或硫；Z是氮或CY.sup.4；Y.sup.1-4在规范中描述。
• Pyrimidine derivatives and their use as herbicides
  申请人：SUMITOMO CHEMICAL COMPANY, LIMITED

  公开号：EP0457505A2

  公开（公告）日：1991-11-21

  A pyrimidine derivative has the formula, wherein A is C3-C8 cycloalkyl C1-C6 alkyl, C3-C8 cycloalkyl C1-C6 alkyl substituted with at least one member selected from the group consisting of C1-C6 alkyl and halogen, C3-C6 oxacycloalkyl, C3-C6 oxacycloalkyl substituted with at least one member selected from the group consisting of C1-C6 alkyl and halogen, C3-C6 oxacydoalkyl C1-C6 alkyl, C3-C6 oxacycloalkyl C1-C6 alkyl substituted with at least one member selected from the group consisting of C1-C6 alkyl and halogen, C3-C5 dioxacycloalkyl, C3-C5 dioxacycloalkyl substituted with at least one member selected from the group consisting of C1-C6 alkyl and halogen, C3-C5 dioxacycloalkyl C1-C6 alkyl or C2-C5 dioxacycloalkyl C1-C6 alkyl substituted with at least one member selected from the group consisting of C1-C6 alkyl and halogen ; each of R1 and R2, which may be the same or different, is C1-C6 alkyl, C1-C6 alkoxy, halo C1-C6 alkoxy or halogen ; X is oxygen or sulfur ; Z is nitrogen or CY4; each of Y1, Y2 and Y3, which may be the same or different, is hydrogen, halogen, C1-C6 alkyl or C1-C6 alkoxy; and Y4 is hydrogen, hydroxyl, mercapto, nitro, halogen, C1-C6 alkyl, C2-C6 alkenyl, C2-C6 alkynyl, C1-C6 alkoxy, C3-C6 alkenyloxy, C3-C6 alkynyloxy, halo C1-C6 alkyl, halo C2-C6 alkenyl, halo C2-C6 alkynyl, halo C1-C6 alkoxy, halo C3-C6 alkenyloxy, halo C3-C6 alkynyloxy, C1-C6 alkoxy C1-C6 alkyl, C3-C6 alkenyloxy C1-C6 alkyl, C3-C6 alkynyloxy C1-C6 alkyl, cyano, formyl, carboxyl, C1-C6 alkoxycarbonyl, C3-C6 alkenyloxycarbonyl, C3-C6 alkynyloxycarbonyl, phenyl, phenyl substituted with at least one member

  一种嘧啶衍生物具有以下式子 其中 A 是 C3-C8 环烷基 C1-C6 烷基、被至少一个选自由 C1-C6 烷基和卤素组成的组的成员取代的 C3-C8 环烷基 C1-C6 烷基、C3-C6 氧代环烷基、被至少一个选自由 C1-C6 烷基和卤素组成的组的成员取代的 C3-C6 氧代环烷基、C3-C6 氧代烷基 C1-C6 烷基、C3-C5 二氧环烷基、C3-C5 二氧环烷基、C3-C5 二氧环烷基、C3-C5 二氧环烷基 C1-C6 烷基或 C2-C5 二氧环烷基 C1-C6 烷基被至少一个选自 C1-C6 烷基和卤素的成员取代； R1 和 R2（可以相同或不同）各自为 C1-C6 烷基、C1-C6 烷氧基、卤代 C1-C6 烷氧基或卤素； X 是氧或硫； Z 是氮或 CY4； Y1、Y2 和 Y3（可以相同或不同）各自是氢、卤素、C1-C6 烷基或 C1-C6 烷氧基；以及 Y4 是氢、羟基、巯基、硝基、卤素、C1-C6 烷基、C2-C6 烯基、C2-C6 炔基、C1-C6 烷氧基、C3-C6 烯氧基、C3-C6 炔氧基、卤代 C1-C6 烷基、卤代 C2-C6 烯基、卤代 C2-C6 炔基、卤代 C1-C6 烷氧基、卤代 C3-C6 烯氧基、卤代 C3-C6 烷氧基、C1-C6 烷氧基 C1-C6烷基、C3-C6 烯氧基 C1-C6烷基、C3-C6 烷炔氧基 C1-C6烷基、氰基、甲酰基、羧基、C1-C6 烷氧基羰基、C3-C6 烯氧基羰基、C3-C6 烷炔氧基羰基、苯基、至少被一个成员取代的苯基
• US5232897A
  申请人：——

  公开号：US5232897A

  公开（公告）日：1993-08-03
• US5298632A
  申请人：——

  公开号：US5298632A

  公开（公告）日：1994-03-29
• US5455355A
  申请人：——

  公开号：US5455355A

  公开（公告）日：1995-10-03