2-(heptadeca-8,11-dienyl)-3,6-dihydroxy-1,4-benzoquinone

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(heptadeca-8,11-dienyl)-3,6-dihydroxy-1,4-benzoquinone
• 英文别名: (Heptadeca-8,11-dienyl)-3,6-dihydroxy-1,4-benzoquinone；3-[(8Z,11Z)-heptadeca-8,11-dienyl]-2,5-dihydroxycyclohexa-2,5-diene-1,4-dione
• 化学式: C₂₃H₃₄O₄
• 分子量: 374.521
• InChiKey: WSPSBGYYAVPUDE-HZJYTTRNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.1
• 重原子数：
  27
• 可旋转键数：
  14
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  74.6
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  2-(heptadeca-8,11-dienyl)-3,6-dihydroxy-1,4-benzoquinone 在 间氯过氧苯甲酸 作用下， 以 氯仿 为溶剂， 以6.8 mg的产率得到
  参考文献：
  名称：

  Benzoquinones from Embelia angustifolia

  摘要：

  Three new 2,5-dihydroxy-3-alkyl-1,4-benzoquinones, (Z)-2,5-dihydroxy-3-(pentadec-8-enyl)-1,4-benzoquinone, (Z,Z)-2,5-dihydroxy-3-(heptadeca-8,11-dienyl)-1,4-benzoquinone and (Z)-2,5-dihydroxy-3-(heptadec-8-enyl)-1,4-benzoquinone and the known 2,5-dihydroxy-3-pentadecyl-1,4-benzoquinone were isolated from the leaves of Embelia angustifolia. Their structures have been established on the basis of spectral analysis and by chemical methods. Copyright (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0031-9422(96)00606-1

文献信息

• Metabolites from the Wood-Rotting BasidiomyceteHapalopilusmutans (Aphyllophorales)
  作者：Bernd Sontag、Johannes Dasenbrock、Norbert Arnold、Wolfgang Steglich

  DOI：10.1002/(sici)1099-0690(199905)1999:5<1051::aid-ejoc1051>3.0.co;2-9

  日期：1999.5

  Fruit bodies of the wood-rotting North American fungus Hapalopilus mutans produce a mixture of dihydroxybenzoic acids 1, dihydroxybenzoquinones 2 and a novel type of spirodiones, e.g. mutadione A (4a). All compounds carry long alkyl chains, which may be partially unsaturated. The structures of the metabolites were established by spectroscopic methods.