allyloctyl ether

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: allyloctyl ether
• 英文别名: 4-Undec-1-en-4-yloxyundec-1-ene
• 化学式: C₂₂H₄₂O
• 分子量: 322.575
• InChiKey: SABMUAGPYXBHDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.3
• 重原子数：
  23
• 可旋转键数：
  18
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.82
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  乙酸烯丙酯 在 tris-(dibenzylideneacetone)dipalladium(0) 、 1,4-双(二苯基膦)丁烷 辛醇 作用下， 反应 1.0h， 以7%的产率得到allyloctyl ether
  参考文献：
  名称：

  Method for producing allyl compound

  摘要：

  一种制备具有与烯丙基起始材料化合物不同组成式的烯丙基化合物的方法，包括在至少包含选择自周期表8至10族过渡金属的过渡金属化合物和具有以下式（1）结构的单齿磷酸酯化合物催化剂存在下，将烯丙基起始材料化合物与具有不同于烯丙基起始材料化合物的结构的氧亲核试剂反应，其中式（1）中，R1、R2和R3分别独立地是可以具有取代基的烷基，R1、R2和R3的碳链可以具有至少一个碳-碳双键或三键，并且R1、R2和R3的至少两个可选基团可以结合形成至少一个环状结构。

  公开号：

  US20040092777A1

文献信息

• Method for producing allyl compound, and ether or ester compound produced thereby
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20040147757A1

  公开（公告）日：2004-07-29

  A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with an oxygen nucleophilic agent in the presence of a catalyst containing at least one transition metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and a multidentate phosphite compound.

  一种生产具有与烯丙基起始物质化合物不同的组成式的烯丙基化合物的方法，包括在存在至少一种含有从周期表第8组到第10组的过渡金属属于的过渡金属的过渡金属化合物和多齿膦酸酯化合物的催化剂的情况下，将烯丙基起始物质化合物与氧亲核试剂反应。
• Method for producing allyl compound, and allyl compound produced thereby
  申请人：Takai Masaki

  公开号：US20050075518A1

  公开（公告）日：2005-04-07

  A method for producing an allyl compound having a compositional formula different from that of an allyl starting material compound, which comprises reacting the allyl starting material compound with a nucleophilic agent in the presence of a catalyst containing at least one transitional metal compound containing a transition metal selected from the group consisting of transition metals belonging to Group 8 to Group 10 of the Periodic Table and at least one bidentate coordinated phosphite compound selected from the group consisting of compounds having structures of the following formulae (I) to (III): wherein A 1 to A 3 are respectively independently a diarylene group having a branched alkyl group at the ortho-position, R 1 to R 6 are respectively independently an alkyl group which may have a substituent or an aryl group which may have a substituent (including a heterocyclic compound forming an aromatic 6π electron cloud on the upper and lower sides of the ring, hereinafter the same), and Z 1 to Z 3 are respectively independently an alkylene group which may have a substituent, an arylene group which may have a substituent, an alkylene-arylene group which may have a substituent or a diarylene group which may have a substituent.

  一种制备具有不同于烯丙基起始材料化合物的组成式的烯丙基化合物的方法，包括在催化剂的存在下，将烯丙基起始材料化合物与亲核试剂反应，所述催化剂包含至少一种过渡金属化合物，所述过渡金属选自周期表8到10组的过渡金属，并且至少一种双齿配位膦酸酯化合物，所述化合物具有以下式(I)到(III)中的结构，其中A1到A3分别独立地是具有支链烷基的二芳基基团，R1到R6分别独立地是可以具有取代基的烷基基团或可以具有取代基的芳基基团（包括在环上形成芳香6π电子云的杂环化合物，在此以后相同），Z1到Z3分别独立地是可以具有取代基的烷基，可以具有取代基的芳基，可以具有取代基的烷基-芳基基团或可以具有取代基的二芳基基团。
• GRAFTED POLYOLEFIN RESIN AND THERMOPLASTIC RESIN COMPOSITION CONTAINING THE SAME
  申请人：KANEKA CORPORATION

  公开号：EP0866081A1

  公开（公告）日：1998-09-23

  A graft-modified polyolefinic resin, obtained by the polymerization of (a-1) 100 parts by weight of a polyolefinic resin prepared in the presence of a single site catalyst with (a-2) from 0.1 to 30 parts by weight of a compound (a-2a) containing a specific glycidyl group and/or a compound (a-2b) containing a glycidyl group composed of an unsaturated glycidyl ester or the foregoing component (a-2) and a vinyl monomer (a-3) in the presence of a radical polymerization initiator (a-4), and a resin composition comprising the foregoing graft-modified polyolefinic resin and a thermoplastic resin.

  一种接枝改性聚烯烃树脂，它是由(a-1)100 份(重量)在单位点催化剂存在下制备的聚烯烃树脂与(a-2)0.1至30份（重量）含有特定缩水甘油基的化合物(a-2a)和/或含有由不饱和缩水甘油酯或前述组分(a-2)和乙烯基单体(a-3)组成的缩水甘油基的化合物(a-2b)，在自由基聚合引发剂(a-4)存在下进行聚合而得到，以及由前述接枝改性聚烯烃树脂和热塑性树脂组成的树脂组合物。
• Emissive lamps comprising metal clusters confined in molecular sieves
  申请人：Katholieke Universiteit Leuven

  公开号：EP2314657A2

  公开（公告）日：2011-04-27

  The present invention concerns an illumination system comprising radiation source that when operational emits radiation is wave length range 280 nm to an emission element that comprises an assembly of oligo atomic metal clusters confined in molecular sieve for converting invisible radiation emitted by a radiation source at room temperature or an higher temperature to visible light and further a transparent envelope said illumination system.

  本发明涉及一种照明系统，该系统包括辐射源，辐射源工作时向发射元件发射波长范围为 280 纳米的辐射，发射元件包括封闭在分子筛中的寡原子金属团簇组件，用于将辐射源在室温或更高温度下发射的不可见辐射转换为可见光。
• SOLAR CELLS
  申请人：Katholieke Universiteit Leuven, K.U. Leuven R&D

  公开号：EP2162923B1

  公开（公告）日：2012-08-22