1-(3-bromophenyl)-4-phenylbutan-1-one

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 1-(3-bromophenyl)-4-phenylbutan-1-one
• 化学式: C₁₆H₁₅BrO
• mdl: MFCD17364798
• 分子量: 303.198
• InChiKey: ZEBCTXQSJVKATO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.5
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.187
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-(3-bromophenyl)-4-phenylbutan-1-one 在 一水合肼 、 sodium hydroxide 作用下， 以 二乙二醇 为溶剂， 反应 2.0h， 以10.9 g的产率得到1-Bromo-3-(4-phenylbutyl)benzene
  参考文献：
  名称：

  IRIDIUM COMPLEX COMPOUND, SOLUTION COMPOSITION CONTAINING IRIDIUM COMPLEX COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE, AND LIGHTING DEVICE

  摘要：

  公开号：

  EP2803671B1
• 作为产物：
  描述：

  间溴苯甲腈 、 3-phenylpropyl-magnesium bromide 在 水 、 氯化铵 作用下， 以 四氢呋喃 为溶剂， 反应 1.0h， 以20 g的产率得到1-(3-bromophenyl)-4-phenylbutan-1-one
  参考文献：
  名称：

  IRIDIUM COMPLEX COMPOUND, SOLUTION COMPOSITION CONTAINING IRIDIUM COMPLEX COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE, AND LIGHTING DEVICE

  摘要：

  公开号：

  EP2803671B1

文献信息

• Visible Light Driven and Copper-Catalyzed C(sp³)–H Functionalization of <i>O</i>-Pentafluorobenzoyl Ketone Oximes
  作者：Danhua Wu、Shuang-Shuang Cui、Fengling Bian、Wei Yu

  DOI：10.1021/acs.orglett.1c02133

  日期：2021.8.6

  with copper complexes as catalysts. The reactions involve iminyl-radical-mediated intramolecular hydrogen atom transfer as the key step, with the iminyl radicals being generated via copper-effected N–O cleavage. The reaction afforded 3,4-dihydro-2H-pyrroles under the conditions of [Cu(DPEphos)(bcp)]PF6 and DABCO, while γ-pentafluorobenzoyloxy ketones were produced predominantly when [Cu(dpp)2]PF6 and

  O-五氟苯甲酰基酮肟的C(sp 3 )-H官能化是在可见光照射下以铜配合物为催化剂实现的。该反应涉及亚胺基介导的分子内氢原子转移作为关键步骤，亚胺基自由基是通过铜作用的 N-O 裂解产生的。该反应在[Cu(DPEphos)(bcp)]PF 6和DABCO条件下生成3,4-二氢-2 H-吡咯，而在[Cu(dpp) 2 ]PF 6和DABCO条件下主要生成γ-五氟苯甲酰氧基酮。InCl 3 ·4H 2 O用作催化剂。
• Switchable Decarboxylative Heck-Type Reaction and Oxo-alkylation of Styrenes with <i>N</i>-Hydroxyphthalimide Esters under Photocatalysis
  作者：Zi-Hao Xia、Chun-Lin Zhang、Zhong-Hua Gao、Song Ye

  DOI：10.1021/acs.orglett.8b01268

  日期：2018.6.15

  The switchable visible-light-mediated decarboxylative Heck-type reaction and oxo-alkylation reaction of N-hydroxyphthalimide esters under photocatalysis were developed. Disubstituted or trisubstituted alkenes were obtained in good yield with high E-selectivity in the presence of Bronsted acid as the additive, while ketones resulted in the absence of the acidic additive.
• IRIDIUM COMPLEX COMPOUND, SOLUTION COMPOSITION CONTAINING THE COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY, AND LIGHTING
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：US20140319505A1

  公开（公告）日：2014-10-30

  The present invention is to provide an iridium complex compound, which is soluble in an organic solvent, which can be stored for long periods without reprecipitation thereof and which secures a low driving voltage and a high luminescent efficiency of an organic electroluminescent element produced using the compound, to provide an organic electroluminescent element containing the compound and to provide a display and a lighting using the organic electroluminescent element. The present invention relates to the iridium complex compound having a specific chemical structure. Further, the invention also relates to the organic electroluminescent element produced using the compound, which requires a low operating voltage and has a long operating lifetime.
• US9799837B2
  申请人：——

  公开号：US9799837B2

  公开（公告）日：2017-10-24
• IRIDIUM COMPLEX COMPOUND, SOLUTION COMPOSITION CONTAINING IRIDIUM COMPLEX COMPOUND, ORGANIC ELECTROLUMINESCENT ELEMENT, DISPLAY DEVICE, AND LIGHTING DEVICE
  申请人：Mitsubishi Chemical Corporation

  公开号：EP2803671B1

  公开（公告）日：2019-05-01