2,6-dimethoxy-cyclohexanol

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2,6-dimethoxy-cyclohexanol
• 英文别名: 2,6-Dimethoxycyclohexan-1-one
• 化学式: C₈H₁₄O₃
• 分子量: 158.197
• InChiKey: UTDHOGDYMZTKRL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.7
• 重原子数：
  11
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.88
• 拓扑面积：
  35.5
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  2,6-二甲氧基苯酚 在 palladium on activated charcoal 、 氢气 作用下， 以 水 为溶剂， 109.84 ℃ 、2.0 MPa 条件下， 反应 2.0h， 生成 甲醇 、 2-甲氧基环己酮 、 2-甲氧基环己醇 、 2,6-dimethoxy-cyclohexanol
  参考文献：
  名称：

  在Pd / C和HZSM-5催化剂上各种甲氧基取代的木质素单体的水相加氢脱氧研究†

  摘要：

  在2 MPa的H 2（环境温度）下，使用Pd / C和HZSM-5催化剂的组合，已经研究了木质素单体通过加氢脱氧（HDO）进行水相催化提质的方法。选择具有不同甲氧基数目的模型单体，包括苯酚，茴香醚，愈创木酚和2，6-二甲氧基苯酚，作为木质素模型化合物。机理研究表明，通过氢化和脱水（水解）过程，分别由Pd / C和HZSM-5催化。优选在较低温度下氢化，而较高温度有利于除去含氧官能团。还系统地研究了甲氧基对这些单体的HDO的影响。基本上，由于空间约束和给电子羟基的抑制，多取代单体的转化比单取代单体的转化更困难。通过将温度提高到413 K，可以显着提高从苯酚和苯甲醚对环己烷的选择性。但是，即使在高温下使用具有多取代基的模型化合物（愈创木酚和2,6-二甲氧基苯酚），环己酮也比环己烷更易制得513 K以上。

  DOI：

  10.1039/c6ra22492j

文献信息

• HIGH ENERGY DENSITY REDOX FLOW DEVICE
  申请人：Chiang Yet-Ming

  公开号：US20110200848A1

  公开（公告）日：2011-08-18

  Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.
• [EN] HIGH ENERGY DENSITY REDOX FLOW DEVICE<br/>[FR] DISPOSITIF À ÉCOULEMENT REDOX À HAUTE DENSITÉ D'ÉNERGIE
  申请人：MASSACHUSETTS INST TECHNOLOGY

  公开号：WO2011084649A2

  公开（公告）日：2011-07-14

  Redox flow devices are described in which at least one of the positive electrode or negative electrode-active materials is a semi-solid or is a condensed ion-storing electroactive material, and in which at least one of the electrode-active materials is transported to and from an assembly at which the electrochemical reaction occurs, producing electrical energy. The electronic conductivity of the semi-solid is increased by the addition of conductive particles to suspensions and/or via the surface modification of the solid in semi-solids (e.g., by coating the solid with a more electron conductive coating material to increase the power of the device). High energy density and high power redox flow devices are disclosed. The redox flow devices described herein can also include one or more inventive design features. In addition, inventive chemistries for use in redox flow devices are also described.
• An investigation on the aqueous-phase hydrodeoxygenation of various methoxy-substituted lignin monomers on Pd/C and HZSM-5 catalysts
  作者：Cong Zhang、Jingbo Qi、Jing Xing、Si-Fu Tang、Liang Song、Yuanyuan Sun、Chuanhui Zhang、Hongchuan Xin、Xuebing Li

  DOI：10.1039/c6ra22492j

  日期：——

  monomers to hydrocarbons via hydrodeoxygenation (HDO) has been explored using a combination of Pd/C and HZSM-5 catalysts under 2 MPa of H2 (ambient temperature). Model monomers with varying numbers of methoxy groups, including phenol, anisole, guaiacol and 2,6-dimethoxy-phenol, were chosen as lignin model compounds. Mechanistic studies revealed cascade and parallel reaction pathways via hydrogenation and

  在2 MPa的H 2（环境温度）下，使用Pd / C和HZSM-5催化剂的组合，已经研究了木质素单体通过加氢脱氧（HDO）进行水相催化提质的方法。选择具有不同甲氧基数目的模型单体，包括苯酚，茴香醚，愈创木酚和2，6-二甲氧基苯酚，作为木质素模型化合物。机理研究表明，通过氢化和脱水（水解）过程，分别由Pd / C和HZSM-5催化。优选在较低温度下氢化，而较高温度有利于除去含氧官能团。还系统地研究了甲氧基对这些单体的HDO的影响。基本上，由于空间约束和给电子羟基的抑制，多取代单体的转化比单取代单体的转化更困难。通过将温度提高到413 K，可以显着提高从苯酚和苯甲醚对环己烷的选择性。但是，即使在高温下使用具有多取代基的模型化合物（愈创木酚和2,6-二甲氧基苯酚），环己酮也比环己烷更易制得513 K以上。