An infrared study of the reaction of acetylene halides: HCCCl with O2
作者:Mei-Lee Hwang、Wei-Liang Hsu
DOI:10.1016/s0022-2860(98)00361-5
日期:1998.8
Abstract The reaction of HCCCl with O 2 has been investigated by using the FTIR/matrix isolation technique. The twin-jet codeposition and merged single jet deposition at short sample distances, in either the gas phase or an Ar matrix, gave no apparent new band. Many new peaks were observed as the merged length increased to 19 cm. From the position of the new absorptions, CO, CO 2 , and formyl chloride
摘要 使用 FTIR/基质分离技术研究了 HCCCl 与 O 2 的反应。在气相或 Ar 基质中,在较短的样品距离下,双射流共沉积和合并单射流沉积都没有产生明显的新谱带。随着合并长度增加到 19 cm,观察到许多新峰。从新吸收的位置,观察到 CO、CO 2 和甲酰氯 (HCOCl) 作为主要产物。乙醛酰氯 (HCOCOCl) 暂时被指定为中间体,并在本研究中首次被分离出来。还讨论了可能的反应机理。
FitzGibbon, Journal of the Chemical Society, 1938, p. 1219