Se-2,4,6-triisopropylphenylmethyl selenoformate

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: Se-2,4,6-triisopropylphenylmethyl selenoformate
• 英文别名: Se-[[2,4,6-tri(propan-2-yl)phenyl]methyl] methaneselenoate
• 化学式: C₁₇H₂₆OSe
• 分子量: 325.353
• InChiKey: GHNFXJTYTQJLPZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.45
• 重原子数：
  19
• 可旋转键数：
  6
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.59
• 拓扑面积：
  17.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  bis(2,4,6-triisoprolyphenylmethyl) diselenide 、 甲酸丙酯 在 二异丁基氢化铝 作用下， 以 正己烷 、 苯 为溶剂， 反应 2.33h， 以18%的产率得到Se-2,4,6-triisopropylphenylmethyl selenoformate
  参考文献：
  名称：

  Synthesis of Se-arylmethyl selenoformates by reaction of aluminum arylmethaneselenolates with formates

  摘要：

  Se-Arylmethyl selenoformates were synthesized by the reaction of aluminum arylmethaneselenolates with formates. Se-Benzyl selenoformate is an unstable compound, but steric protection by some bulky substituents enabled the stable isolation of the selenoformates. To the best of our knowledge, this is the first example of the synthesis of Se-alkyl selenoformates. (C) 2005 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2005.01.148

文献信息

• Synthesis of Se-arylmethyl selenoformates by reaction of aluminum arylmethaneselenolates with formates
  作者：Hajime Maeda、Taro Tanabe、Kazuhiro Hotta、Kazuhiko Mizuno

  DOI：10.1016/j.tetlet.2005.01.148

  日期：2005.3

  Se-Arylmethyl selenoformates were synthesized by the reaction of aluminum arylmethaneselenolates with formates. Se-Benzyl selenoformate is an unstable compound, but steric protection by some bulky substituents enabled the stable isolation of the selenoformates. To the best of our knowledge, this is the first example of the synthesis of Se-alkyl selenoformates. (C) 2005 Elsevier Ltd. All rights reserved.