10-methyldispiro[acridine-9(10H),2'-oxirane-3',2''-tricyclo-[3.3.1.1^3,7]decane]

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 10-methyldispiro[acridine-9(10H),2'-oxirane-3',2''-tricyclo-[3.3.1.1^3,7]decane]
• 化学式: C₂₄H₂₅NO
• 分子量: 343.469
• InChiKey: UTJXTWDVPMAADY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.8
• 重原子数：
  26
• 可旋转键数：
  0
• 环数：
  8.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  15.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为产物：
  描述：

  甲基-蒽酮 在 lithium aluminium tetrahydride 、 titanium(III) chloride 、 三乙胺 、 间氯过氧苯甲酸 作用下， 以 四氢呋喃 、 二氯甲烷 为溶剂， 反应 15.0h， 生成 10-methyldispiro[acridine-9(10H),2'-oxirane-3',2''-tricyclo-[3.3.1.1^3,7]decane]
  参考文献：
  名称：

  Oxiranes having an acridane structure as a novel chemiluminescent precursor: synthesis and chemiluminescent studies

  摘要：

  Oxirane derivatives having acridane and adamantane structures were designed as a novel chemiluminescent precursor and were found to have a characteristic chemiluminescent ability which is introduced by a two-step trigger reaction involving treatment with alkaline H2O2 and subsequent acidic treatment. Structural study of the oxirane derivatives showed that the CIEEL mechanism is involved in this chemiluminescent reaction and it was also found that the chemiluminescent profile is affected by the kind of acid employed in the trigger reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(01)00216-2

文献信息

• Oxiranes having an acridane structure as a novel chemiluminescent precursor: synthesis and chemiluminescent studies
  作者：Kazuyuki Miyashita、Masatoshi Minagawa、Yohko Ueda、Yukie Tada、Nobuhiro Hoshino、Takeshi Imanishi

  DOI：10.1016/s0040-4020(01)00216-2

  日期：2001.4

  Oxirane derivatives having acridane and adamantane structures were designed as a novel chemiluminescent precursor and were found to have a characteristic chemiluminescent ability which is introduced by a two-step trigger reaction involving treatment with alkaline H2O2 and subsequent acidic treatment. Structural study of the oxirane derivatives showed that the CIEEL mechanism is involved in this chemiluminescent reaction and it was also found that the chemiluminescent profile is affected by the kind of acid employed in the trigger reaction. (C) 2001 Elsevier Science Ltd. All rights reserved.