7-fluoro-4-(4-fluorophenyl)quinoline

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 7-fluoro-4-(4-fluorophenyl)quinoline
• 化学式: C₁₅H₉F₂N
• 分子量: 241.24
• InChiKey: IBOUXXGCFMOHGZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4
• 重原子数：
  18
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  3,3-二(4'-氟苯基)丙-2-烯醛 在 fac-tris(2-phenylpyridinato-N,C2')iridium(III) 、 4-氯苯磺酸 、 4-(aminooxycarbonyl)benzonitrile 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 16.0h， 以56%的产率得到7-fluoro-4-(4-fluorophenyl)quinoline
  参考文献：
  名称：

  Visible-Light-Promoted and One-Pot Synthesis of Phenanthridines and Quinolines from Aldehydes and O-Acyl Hydroxylamine

  摘要：

  A one-pot synthesis of phenanthridines and quinolines from commercially available or easily prepared aldehydes has been reported. O-(4-Cyanobenzoyl)hydroxylamine was utilized as the nitrogen source to generate O-acyl oximes in situ with aldehydes catalyzed by Bronsted acid. O-Acyl oximes were then subjected to visible light photoredox catalyzed cyclization via iminyl radicals to furnish aza-arenes. A variety of phenanthridines and quinolines have been prepared assisted by Bronsted acid and photocatalyst under visible light at room temperature with satisfactory yields.

  DOI：

  10.1021/acs.orglett.5b01096

文献信息

• RESIN COMPOSITION AND ADHESIVE FILM
  申请人：——

  公开号：US20020151659A1

  公开（公告）日：2002-10-17

  The present invention is to provide a resin composition excellent in moisture absorption property, heat resistance, adhesive property and electric characteristics, and excellent in molding property, and suitable for an insulating material such as a multilayer wiring substrate, electronic parts, etc., and an adhesive film. There is disclosed a resin composition comprising (A) a polymer containing a quinoline ring represented by the formula (1) in the structure such as 6,6′-bis(2-(4-fluorophenyl)-4-phenylquinoline) and 4,4′-(1,1,1,3,3,3-hexafluoro-2,2-propylidene)bisphenol, etc., and (B) a bismaleimide compound represented by the formula (2) such as 2,2-bis((4-male-imidophenoxy)phenyl)propane, etc.

  本发明旨在提供一种吸湿性、耐热性、粘合性和电气特性优良，成型性优良，适用于多层配线基板、电子零件等绝缘材料和粘合膜的树脂组合物。 本发明公开了一种树脂组合物，它包含(A)含有结构式(1)代表的喹啉环的聚合物，如 6,6′-双(2-(4-氟苯基)-4-苯基喹啉)和 4,4′-(1,1,1,3,3,3-六氟-2,2-亚丙基)双酚等、(B) 由式 (2) 表示的双马来酰亚胺化合物，如 2,2-双((4-马来酰亚胺基苯氧基)苯基)丙烷等。
• Method of preparation of polyquinolines
  申请人：HITACHI CHEMICAL CO., LTD.

  公开号：EP0861864B1

  公开（公告）日：2004-08-25
• US5648448A
  申请人：——

  公开号：US5648448A

  公开（公告）日：1997-07-15
• US5786071A
  申请人：——

  公开号：US5786071A

  公开（公告）日：1998-07-28
• US6132852A
  申请人：——

  公开号：US6132852A

  公开（公告）日：2000-10-17