2,2-dimethyl-1-(4-methyl)-phenyl-1,2,5,10-tetrahydrobenzo[g]quinoline-5,10-dione

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 2,2-dimethyl-1-(4-methyl)-phenyl-1,2,5,10-tetrahydrobenzo[g]quinoline-5,10-dione
• 英文别名: 2,2-Dimethyl-1-(4-methylphenyl)benzo[g]quinoline-5,10-dione
• 化学式: C₂₂H₁₉NO₂
• 分子量: 329.398
• InChiKey: YLOSRKSPKKCJMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.7
• 重原子数：
  25
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  37.4
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  黄钟花醌 在 potassium carbonate 作用下， 以 乙醇 、 丙酮 为溶剂， 反应 2.17h， 生成 2,2-dimethyl-1-(4-methyl)-phenyl-1,2,5,10-tetrahydrobenzo[g]quinoline-5,10-dione
  参考文献：
  名称：

  Secondary amines and unexpected 1-aza-anthraquinones from 2-methoxylapachol

  摘要：

  A series of 1-aza-anthraquinones were characterized, besides the expected N-alkylamino derivatives, from the substitution reactions of 2-metboxylapachol with primary amines. An investigation of the reaction conditions allowed reasonable selectivity in the products distribution. (C) 2001 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4020(01)00973-5

文献信息

• Secondary amines and unexpected 1-aza-anthraquinones from 2-methoxylapachol
  作者：Celso A Camara、Angelo C Pinto、Maria A Rosa、Maria D Vargas

  DOI：10.1016/s0040-4020(01)00973-5

  日期：2001.11

  A series of 1-aza-anthraquinones were characterized, besides the expected N-alkylamino derivatives, from the substitution reactions of 2-metboxylapachol with primary amines. An investigation of the reaction conditions allowed reasonable selectivity in the products distribution. (C) 2001 Elsevier Science Ltd. All rights reserved.