庚二酸双[(苯并-15-冠-5)-15-基甲]酯 | 69271-98-3

• 物质功能分类: 分析化学 - 分析试剂 - 常用分析试剂
• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 庚二酸双[(苯并-15-冠-5)-15-基甲]酯
• 中文别名: 钾离子载体II
• 英文名称: bis((benzo-15-crown-5)-15-ylmethyl) pimelate
• 英文别名: potassium ionophore II；bis(2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-trien-17-ylmethyl) heptanedioate
• CAS: 69271-98-3
• 化学式: C₃₇H₅₂O₁₄
• 分子量: 720.811
• InChiKey: LTZRCLYZVSXCTC-UHFFFAOYSA-N

物化性质

• 熔点：
  81-84 °C(lit.)
• 沸点：
  798.3±60.0 °C(Predicted)
• 密度：
  1.146±0.06 g/cm3(Predicted)
• 稳定性/保质期：

  远离氧化物。

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  51
• 可旋转键数：
  12
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.621
• 拓扑面积：
  145
• 氢给体数：
  0
• 氢受体数：
  14

安全信息

• 危险品标志：
  Xn
• 安全说明：
  S26,S36
• 危险类别码：
  R36/37/38,R20/21/22
• WGK Germany：
  3

反应信息

• 作为反应物：
  描述：

  庚二酸双[(苯并-15-冠-5)-15-基甲]酯 在 硝酸 作用下， 反应 0.5h， 以65%的产率得到bis[(18-nitro-2,5,8,11,14-pentaoxabicyclo[13.4.0]nonadeca-1(15),16,18-trien-17-yl)methyl] heptanedioate
  参考文献：
  名称：

  Toeke, Laszlo; Bitter, Istvan; Agai, Bela, Liebigs Annalen der Chemie, 1988, p. 549 - 554

  摘要：

  DOI：

文献信息

• Nanopipette provided with membrane containing saturated ion-sensitive material, method for preparing same, and ion measuring apparatus comprising same
  申请人：Konkuk University Industrial Cooperation Corp.

  公开号：US10335781B2

  公开（公告）日：2019-07-02

  Disclosed are a nanopipette provided with a membrane containing a saturated ion-sensitive material, a method for preparing the same, and an ion measuring apparatus comprising the same.

  本发明公开了一种带有含有饱和离子敏感材料的膜的纳米吸头、制备方法以及包含该纳米吸头的离子测量仪器。
• TOKE, LASZLO;BITTER, ISTVAN;AGAI, BELA;HELL, ZOLTAN;LINDNER, ERNO;TOTH, K+, LIEBIGS ANN. CHEM.,(1988) N 6, 549-554
  作者：TOKE, LASZLO、BITTER, ISTVAN、AGAI, BELA、HELL, ZOLTAN、LINDNER, ERNO、TOTH, K+

  DOI：——

  日期：——
• Voltammetric Ion Sensor
  申请人：Zhang Jie

  公开号：US20080011606A1

  公开（公告）日：2008-01-17

  A method for the quantitative determination of an ion in a fluid which comprises subjecting the fluid to voltammetry using a sensing electrode which comprises an electrically conducting support having a surface which is coated with a support matrix, the support matrix containing an electroactive species capable of being oxidised or reduced to form a charged species, and an ionophore.
• Carbon Nanostructure Electrode Based Sensors: Devices, Processes and Uses Thereof
  申请人：Man Piu Francis

  公开号：US20090278556A1

  公开（公告）日：2009-11-12

  Disclosed herein are methods of preparing and using doped MWNT electrodes, sensors and field-effect transistors. Devices incorporating doped MWNT electrodes, sensors and field-effect transistors are also disclosed. Also disclosed are devices comprising nanostructured electrodes and methods for measuring free chlorine in an aqueous environment. Also disclosed are diamond coated electrodes for use in electrochemical applications.
• CNT-BASED SENSORS: DEVICES, PROCESSES AND USES THEREOF
  申请人：Pace Salvatore J.

  公开号：US20110163296A1

  公开（公告）日：2011-07-07

  Disclosed herein are methods of preparing and using doped MWNT electrodes, sensors and field-effect transistors. Devices incorporating doped MWNT electrodes, sensors and field-effect transistors are also disclosed.