1,1-二氯-3-甲基戊-1-烯 | 89580-89-2

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1,1-二氯-3-甲基戊-1-烯
• 英文名称: 1,1-dichloro-3-methyl-pent-1-ene
• 英文别名: (+/-)-1,1-Dichlor-3-methyl-penten-(1)；1,1-Dichloro-3-methylpent-1-ene
• CAS: 89580-89-2
• 化学式: C₆H₁₀Cl₂
• 分子量: 153.051
• InChiKey: ZLVBOZHEOPAERN-UHFFFAOYSA-N

物化性质

• 沸点：
  34 °C(Press: 13.5 Torr)
• 密度：
  1.0473 g/cm3(Temp: 19 °C)

计算性质

• 辛醇/水分配系数(LogP)：
  3.9
• 重原子数：
  8
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  三氯乙烯 、 tri-sec-butylindium 反应 12.0h， 生成 1,1-二氯-3-甲基戊-1-烯
  参考文献：
  名称：

  New triad alkylation reagent. Cross coupling of indium trialkyls with alkenyl halides

  摘要：

  DOI：

  10.1021/ja00033a070

文献信息

• Normant,J., Bulletin de la Societe Chimique de France, 1963, p. 1876 - 1887
  作者：Normant,J.

  DOI：——

  日期：——
• Active compound combinations having insecticidal properties
  申请人：BAYER CROPSCIENCE AKTIENGESELLSCHAFT

  公开号：US20170064958A1

  公开（公告）日：2017-03-09

  The present invention relates to novel active compound combinations comprising at least one known compound of the formula (I) and at least one further known active compound from the class of pyrethroids, which combinations are highly suitable for controlling animal pests such as unwanted insects and/or unwanted acarids.
• US6359164B1
  申请人：——

  公开号：US6359164B1

  公开（公告）日：2002-03-19
• [EN] PROCESS FOR THE PREPARATION OF CYCLOPROPYLACETYLENE<br/>[FR] PROCEDE DE PREPARATION DE CYCLOPROPYLACETYLENE
  申请人：DU PONT PHARM CO

  公开号：WO2000018706A1

  公开（公告）日：2000-04-06

  The present invention relates generally to novel methods for the preparation of cyclopropylacetylene which is an essential reagent in the asymmetric synthesis of (S)-6-chloro-4-cyclopropylethynyl-4-trifluoromethyl-1,4-dihydro-2H-3,1-benzoxazin-2-one; a useful human immunodeficiency virus (HIV) reverse transcriptase inhibitor with superior antiretroviral activity. In the process, for example, cyclopropane carboxaldehyde is alkylated to form 1,1,1-trichloro-2-cyclopropyl-ethanol; which in turn undergoes elimination to form 1,1-dichloro-2-cyclopropyl-ethene; which in turn undergoes elimination to form cyclopropyl acetylene.
• New triad alkylation reagent. Cross coupling of indium trialkyls with alkenyl halides
  作者：Ryoki Nomura、Shinichiro Miyazaki、Haruo Matsuda

  DOI：10.1021/ja00033a070

  日期：1992.3