(4S,4aS,7R,7aR)-4,4a,7-Trimethyl-4,4a,5,6,7,8-hexahydro-indeno[5,6-b]furan-7a-carbaldehyde

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (4S,4aS,7R,7aR)-4,4a,7-Trimethyl-4,4a,5,6,7,8-hexahydro-indeno[5,6-b]furan-7a-carbaldehyde
• 英文别名: (4S,4aS,7R,7aR)-4,4a,7-trimethyl-5,6,7,8-tetrahydro-4H-cyclopenta[f][1]benzofuran-7a-carbaldehyde
• 化学式: C₁₅H₂₀O₂
• 分子量: 232.323
• InChiKey: MUIMFQOVWHEBND-HKCMKHECSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  17
• 可旋转键数：
  1
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  30.2
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (4S,4aS,7R,7aR)-4,4a,7-Trimethyl-4,4a,5,6,7,8-hexahydro-indeno[5,6-b]furan-7a-carbaldehyde 在 lithium aluminium tetrahydride 作用下， 生成 ((4S,4aS,7R,7aR)-4,4a,7-Trimethyl-4,4a,5,6,7,8-hexahydro-indeno[5,6-b]furan-7a-yl)-methanol
  参考文献：
  名称：

  Sesquiterpenoids from the liverwort dicranolejeunea yoshinaga(HATT.) MIZUT.

  摘要：

  A sesquiterpene alcohol with a new rearranged pinguisane carbon skeleton, which is named a neo-pinguisane type, has been isolated from the ether extract of the liverwort Dicranolejeunea yoshinagana (Hatt.) Mizut., together with two new pinguisane-type sesquiterpenoids and previously known deoxopinguisone and ptychanolide. Their structures were established by spectroscopic means.

  DOI：

  10.1248/cpb.43.714

文献信息

• Sesquiterpenoids from the liverwort dicranolejeunea yoshinaga(HATT.) MIZUT.
  作者：Masao TOYOTA、Hiroki KOYAMA、Toshihiro HASHIMOTO、Yoshinori ASAKAWA

  DOI：10.1248/cpb.43.714

  日期：——

  A sesquiterpene alcohol with a new rearranged pinguisane carbon skeleton, which is named a neo-pinguisane type, has been isolated from the ether extract of the liverwort Dicranolejeunea yoshinagana (Hatt.) Mizut., together with two new pinguisane-type sesquiterpenoids and previously known deoxopinguisone and ptychanolide. Their structures were established by spectroscopic means.