1,1-双(叔己过氧化) 环己烷 | 22743-71-1

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 1,1-双(叔己过氧化) 环己烷
• 中文别名: 1,1-双(叔己过氧化)环己烷
• 英文名称: 1,1-bis(α,α-dimethylbutylperoxy)cyclohexane
• 英文别名: 1,1-bis(1,1-dimethylbutylperoxy)cyclohexane；1,1-bis(tertiary hexylperoxy)cyclohexane；1,1-bis(tert-hexaneylperoxy)cyclohexane；1,1-di(tert-hexaneyl-peroxy)cyclohexane；(D)-1,1-bis(t-hexylperoxy)cyclohexane；1,1-bis(tert-hexylperoxy)cyclohexane；1,1-bis(tert-hexylperoxy)cyclohexan；1,1-di(tert-hexylperoxy)cyclohexane；1,1-bis(t-hexylperoxy)cyclohexane；1,1-bis(t-hexylperoxy)cyclohexan；1,1-di(t-hexylperoxy)cyclohexane；1,1-Di(t-hexylperoxy)cyclohexan；iodine；1,1-Bis[(2-methylpentan-2-YL)peroxy]cyclohexane；1,1-bis(2-methylpentan-2-ylperoxy)cyclohexane
• CAS: 22743-71-1
• 化学式: C₁₈H₃₆O₄
• 分子量: 316.481
• InChiKey: VBQCFYPTKHCPGI-UHFFFAOYSA-N

物化性质

• 沸点：
  346.2±12.0 °C(Predicted)
• 密度：
  0.95±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.5
• 重原子数：
  22
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2909600000

反应信息

• 作为反应物：
  描述：

  1,1-双(叔己过氧化) 环己烷 在 异丙苯 作用下， 生成 2-甲基-2-戊醇 、 丙酮
  参考文献：
  名称：

  Substituent Effects of Alkyl Groups on the Decomposition of tert-Alkyl Peroxides

  摘要：

  In order to clarify substituent effects of alkyl groups on the decomposition of various tert-alkyl peroxides (RCMe(2)OOR'), the decomposition of 1-methoxy-1-(tert-alkylperoxy)cyclohexanes 3 and 1,1-bis(tert-alkylperoxy)cyclohexanes 4 has been studied by use of methods of kinetics and product analysis in cumene with the range of temperatures from 80-110 degrees C and compared with those of the corresponding peroxyesters (1; R' = CO-t-Bu) and dialkyl peroxides (2; R' = t-Bu). The decomposition rates for each peroxide series decrease in the following order: 1 much greater than 3 much greater than 4 much greater than 2. The decomposition rate for the series of peroxides 1 decreases in the following order: R = t-BuCH(2) much greater than i-Pr much greater than Et > Pr > Me. But, for the series of peroxides 2, 3, and 4, R = t-BuCH(2) much greater than i-Pr much greater than Pr > Et much greater than Me. The decomposition rate is expressed by a modified Taft equation: log k(d) = rho*Sigma sigma(CH2R)* + nh + C, which contains both inductive and C-H hyperoconjugation effects of alkyl groups. On the basis of the isokinetic relationship of the activation parameters, the Taft equation, and the decomposition products, the decomposion mechanism via an polar activation complex having a slightly stretched C-alpha - C-beta bond neighboring to the peroxy oxygen atom is suggested and the abnormal behavior of neopentyl group is discussed.

  DOI：

  10.1021/jo00122a035
• 作为产物：
  描述：

  环己酮二甲缩酮 、 叔己基过氧化氢 在 对甲苯磺酸 作用下， 以 二甲基亚砜 为溶剂， 20.0 ℃ 、2.67 kPa 条件下， 以90.9%的产率得到1,1-双(叔己过氧化) 环己烷
  参考文献：
  名称：

  Substituent Effects of Alkyl Groups on the Decomposition of tert-Alkyl Peroxides

  摘要：

  In order to clarify substituent effects of alkyl groups on the decomposition of various tert-alkyl peroxides (RCMe(2)OOR'), the decomposition of 1-methoxy-1-(tert-alkylperoxy)cyclohexanes 3 and 1,1-bis(tert-alkylperoxy)cyclohexanes 4 has been studied by use of methods of kinetics and product analysis in cumene with the range of temperatures from 80-110 degrees C and compared with those of the corresponding peroxyesters (1; R' = CO-t-Bu) and dialkyl peroxides (2; R' = t-Bu). The decomposition rates for each peroxide series decrease in the following order: 1 much greater than 3 much greater than 4 much greater than 2. The decomposition rate for the series of peroxides 1 decreases in the following order: R = t-BuCH(2) much greater than i-Pr much greater than Et > Pr > Me. But, for the series of peroxides 2, 3, and 4, R = t-BuCH(2) much greater than i-Pr much greater than Pr > Et much greater than Me. The decomposition rate is expressed by a modified Taft equation: log k(d) = rho*Sigma sigma(CH2R)* + nh + C, which contains both inductive and C-H hyperoconjugation effects of alkyl groups. On the basis of the isokinetic relationship of the activation parameters, the Taft equation, and the decomposition products, the decomposion mechanism via an polar activation complex having a slightly stretched C-alpha - C-beta bond neighboring to the peroxy oxygen atom is suggested and the abnormal behavior of neopentyl group is discussed.

  DOI：

  10.1021/jo00122a035

文献信息

• CURED PRODUCT, OPTICAL MEMBER, LENS, COMPOUND, AND CURABLE COMPOSITION
  申请人：FUJIFILM Corporation

  公开号：US20200199095A1

  公开（公告）日：2020-06-25

  According to the present invention, a cured product obtained by curing a curable composition including a compound represented by General Formula 1, in which a birefringence Δn (587 nm) is 0.00≤Δn (587 nm)≤0.01, is provided, and this cured product is suitable for manufacturing an optical member. Pol 1 -Sp 1 -L 1 -Ar-L 2 -Sp 2 -Pol 2 (General Formula 1 ) In formula, Ar is an aromatic ring group represented by General Formula 2-2 and the like. In formula, Z 1 and Z 2 each represent a hydrogen atom, a methyl group, and the like; A 1 and A 2 each represent —S— and the like; X represents C(Rz) 2 and the like (where Rz is a substituent, and two Rz's may form a ring); L 1 and L 2 each represent a single bond, —O—, —OC(═O)—, —OC(═O)O—, —OC(═O)NH—, and the like; Sp 1 and Sp 2 each represent a single bond or a divalent linking group; Pol 1 and Pol 2 each represent a hydrogen atom or a polymerizable group; and a compound represented by General Formula 1 has at least one polymerizable group.

  根据本发明，通过固化包括通式1所代表的化合物的可固化组合物获得的固化产品，其中双折射Δn（587 nm）为0.00≤Δn（587 nm）≤0.01，提供，并且该固化产品适用于制造光学元件。 Pol1-Sp1-L1-Ar-L2-Sp2-Pol2（通式1） 在公式中，Ar是由通式2-2等表示的芳香环基团。 在公式中，Z1和Z2分别表示氢原子，甲基基团等；A1和A2分别表示—S—等；X表示C（Rz）2等（其中Rz是取代基，两个Rz可能形成环）；L1和L2分别表示单键，—O—，—OC（═O）—，—OC（═O）O—，—OC（═O）NH—等；Sp1和Sp2分别表示单键或二价连接基团；Pol1和Pol2分别表示氢原子或可聚合基团；并且由通式1所代表的化合物至少具有一个可聚合基团。
• Macromer composition including light activated initiator
  申请人：Chudzik J. Stephen

  公开号：US20060287410A1

  公开（公告）日：2006-12-21

  The invention provides compositions that include macromers and visible light-activated polymerization initiators, and methods for forming a matrix using these compositions in conjunction with a light source that emits light primarily in the visible light spectrum.

  这项发明提供了包括大分子单体和可见光活化聚合引发剂的组合物，以及利用这些组合物结合发射主要在可见光谱中的光的光源形成基质的方法。
• ASYMMETRIC ORGANIC PEROXIDE, CROSSLINKING AGENT COMPRISING THE SAME, AND METHOD OF CROSSLINKING WITH THE SAME
  申请人：NOF CORPORATION

  公开号：EP1233014A1

  公开（公告）日：2002-08-21

  A crosslinking agent comprising an asymmetry organic peroxide having at least one structure unit of (substituted)benzoylcarbonyloxy group represented by the following formula (1) in the molecule thereof. Environmentally friendly crosslinking agents and crosslinked silicone rubber moldings are provided thereby. Specifically, useful crosslinking agents and crosslinking processes for silicone rubber are provided.

  一种交联剂，包括至少具有分子中表示为以下式（1）的（取代）苯甲酰羰氧基结构单元的不对称有机过氧化物。因此提供了环保的交联剂和交联硅橡胶成型品。具体提供了用于硅橡胶的有用交联剂和交联工艺。
• LENS ADHESIVE, CEMENTED LENS, AND IMAGING MODULE
  申请人：FUJIFILM Corporation

  公开号：US20200325367A1

  公开（公告）日：2020-10-15

  According to the present invention, a lens adhesive including a compound represented by General Formula 1 is provided. Pol 1 -Sp 1 -L 1 -Ar-L 2 -Sp 2 -Pol 2 (General Formula 1) In the formula, Ar is an aromatic ring group represented by General Formula 2-2 and the like. In the formula, Z 1 and Z 2 each represent a hydrogen atom, a methyl group, and the like; A 1 and A 2 each represent —S— and the like; X represents C(Rz) 2 and the like (where Rz is a substituent, and two Rz's may form a ring); L 1 and L 2 each represent a single bond, —O—, —OC(═O)—, —OC(═O)O—, —OC(═O)NH—, and the like; Sp 1 and Sp 2 each represent a single bond or a linking group such as a linear alkylene group; Pol 1 and Pol 2 each represent a hydrogen atom or a polymerizable group; and a compound represented by General Formula 1 has at least one polymerizable group. Using the lens adhesive, it is possible to provide a cemented lens that is unlikely to deteriorate due to light, and an imaging module having high durability.

  根据本发明，提供了一种包括由通式1表示的化合物的镜头粘合剂。 Pol 1 -Sp 1 -L 1 -Ar-L 2 -Sp 2 -Pol 2 （通式1） 在该式中，Ar是由通式2-2等表示的芳香环基团。 在该式中，Z 1 和Z 2 分别表示氢原子，甲基基团等；A 1 和A 2 分别表示—S—等；X表示C(Rz) 2 等（其中Rz是取代基，两个Rz可能形成环）；L 1 和L 2 分别表示单键，—O—，—OC(═O)—，—OC(═O)O—，—OC(═O)NH—等；Sp 1 和Sp 2 分别表示单键或线性烷基基团等连接基团；Pol 1 和Pol 2 分别表示氢原子或可聚合基团；由通式1表示的化合物至少具有一个可聚合基团。使用该镜头粘合剂，可以提供一种不太容易因光线而恶化的胶合镜头，以及具有高耐久性的成像模块。
• DENTAL CEMENT
  申请人：KURARAY NORITAKE DENTAL INC.

  公开号：US20170135909A1

  公开（公告）日：2017-05-18

  The present invention provides a dental cement that exhibits excellent adhesiveness to dentin and has high mechanical strength. The present invention relates to a multi-part dental cement containing: an asymmetric acrylamide-methacrylic acid ester compound (a); an acid group-containing (meth)acrylic polymerizable monomer (b); a hydrophobic crosslinkable polymerizable monomer (c); a chemical polymerization initiator (d); and a filler (e). The asymmetric acrylamide-methacrylic acid ester compound (a) is represented by the following general formula (1): where X is an optionally substituted, linear or branched C 1 to C 6 aliphatic group or an optionally substituted aromatic group, the aliphatic group is optionally interrupted by at least one linking group selected from the group consisting of —O—, —S—, —CO—, —CO—O—, —O—CO—, —NR 1 —, —CO—NR 1 —, —NR 1 —CO—, —CO—O—NR 1 —, —O—CO—NR 1 —, and —NR 1 —CO—NR 1 —, and R 1 is a hydrogen atom or an optionally substituted, linear or branched C 1 to C 6 aliphatic group.

  本发明提供一种对牙本质具有良好粘附性并具有高机械强度的牙科水泥。本发明涉及一种含有多部分的牙科水泥，包括：一种不对称的丙烯酰胺-甲基丙烯酸酯化合物（a）；一种含酸基的（甲基）丙烯酸聚合单体（b）；一种疏水性交联聚合单体（c）；一种化学聚合引发剂（d）；和一种填料（e）。不对称的丙烯酰胺-甲基丙烯酸酯化合物（a）由以下一般式（1）表示：其中X是可选择取代的线性或支链的C1到C6脂肪族基团或可选择取代的芳香族基团，脂肪族基团可选择地被来自由—O—、—S—、—CO—、—CO—O—、—O—CO—、—NR1—、—CO—NR1—、—NR1—CO—、—CO—O—NR1—、—O—CO—NR1—和—NR1—CO—NR1—组成的至少一种连接基团中断，且R1是氢原子或可选择取代的线性或支链的C1到C6脂肪族基团。