1,1-双(叔己过氧化)-3,3,5-三甲基环己烷 | 104066-39-9

• 分子结构分类: 有机化合物 - 有机氧化合物 - 有机氧化物
• 中文名称: 1,1-双(叔己过氧化)-3,3,5-三甲基环己烷
• 英文名称: 1,1-Bis(t-hexylperoxy)-3,3,5-trimethyl cyclohexane
• 英文别名: 1,1,5-trimethyl-3,3-bis(2-methylpentan-2-ylperoxy)cyclohexane
• CAS: 104066-39-9
• 化学式: C₂₁H₄₂O₄
• 分子量: 358.6
• InChiKey: FYRCDEARNUVZRG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  25
• 可旋转键数：
  10
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

文献信息

• [EN] OXIME ESTER PHOTOINITIATORS<br/>[FR] PHOTO-INITIATEURS À BASE D'ESTER D'OXIME
  申请人：BASF SE

  公开号：WO2021175855A1

  公开（公告）日：2021-09-10

  Disclosed are α-oxo oxime ester compounds based on carbazole derivatives which have specific substituent groups useful as a photoinitiator, as well as photopolymerizable compositions comprising said photoinitiator and ethylenically unsaturated compounds. The photopolymerizable compositions are useful, for example, in photoresist formulations for display applications, e.g. liquid crystal display (LCD), organic light emitting diode (OLED) and touch panel.

  揭示了基于咔唑衍生物的α-氧代肟酯化合物，其具有特定取代基，可用作光引发剂，以及包括所述光引发剂和乙烯不饱和化合物的光聚合组合物。这些光聚合组合物可用于例如显示应用的光阻配方，例如液晶显示器（LCD）、有机发光二极管（OLED）和触摸面板。
• ASYMMETRIC ORGANIC PEROXIDE, CROSSLINKING AGENT COMPRISING THE SAME, AND METHOD OF CROSSLINKING WITH THE SAME
  申请人：NOF CORPORATION

  公开号：EP1233014A1

  公开（公告）日：2002-08-21

  A crosslinking agent comprising an asymmetry organic peroxide having at least one structure unit of (substituted)benzoylcarbonyloxy group represented by the following formula (1) in the molecule thereof. Environmentally friendly crosslinking agents and crosslinked silicone rubber moldings are provided thereby. Specifically, useful crosslinking agents and crosslinking processes for silicone rubber are provided.

  一种交联剂，包括至少具有分子中表示为以下式（1）的（取代）苯甲酰羰氧基结构单元的不对称有机过氧化物。因此提供了环保的交联剂和交联硅橡胶成型品。具体提供了用于硅橡胶的有用交联剂和交联工艺。
• DIENE-BASED CARBOXYLATE ANION AND SALT THEREOF, AND POLYMERIZABLE OR CURABLE COMPOSITION THEREOF
  申请人：Kaneko Tomomasa

  公开号：US20130197123A1

  公开（公告）日：2013-08-01

  The claimed invention provides a novel compound not having been studied before, that is, a diene carboxylate anion that contains a specific structure, and a salt thereof. The claimed invention further provides a diene carboxylate anion and a salt thereof, especially a metal salt thereof, which are easily soluble in general organic solvents, reactive diluents, and resins, may be in a liquid state at normal temperature depending on the structure, and have high polymerizability. Polymerization/curing of these produces a resin to which many ionic bonds and a metal are introduced, providing various properties such as hardness, scratch resistance, anti-fingerprint property, gas-barrier property, water vapor barrier property, oxygen absorption property, ultraviolet protection, infrared protection, color development and coloring, high refractive index, adhesion, various catalytic abilities, fluorescence ability and light-emitting ability, optical amplification, dispersibility, and antistatic properties. In addition, the anion and the salt can be used for raw materials for functional fine particles and for metal nanoparticle composites, and also for MOD materials. The claimed invention also provides an advantageous method for producing the diene carboxylate anion and the salt thereof.

  所述发明提供了一种新颖的化合物，此化合物以前未被研究过，即一种含有特定结构的二烯二酸盐阴离子及其盐。所述发明进一步提供了一种二烯二酸盐阴离子及其盐，特别是其金属盐，这些盐在一般有机溶剂、反应性稀释剂和树脂中易溶解，在常温下可能处于液态，具有高聚合性。这些的聚合/固化产生的树脂引入了许多离子键和金属，提供了硬度、抗刮擦性、防指纹性、气体屏障性、阻水汽性、氧气吸收性、紫外线保护、红外线保护、颜色开发和着色、高折射率、粘附性、各种催化能力、荧光能力和发光能力、光学放大、分散性和抗静电性等各种性能。此外，该阴离子和盐可用作功能性细颗粒和金属纳米粒子复合材料的原材料，也可用于MOD材料。所述发明还提供了一种生产二烯二酸盐阴离子及其盐的优势方法。
• Fluoroalkyl iodide and its production process
  申请人：Furuta Shoji

  公开号：US20070249876A1

  公开（公告）日：2007-10-25

  A process for producing a fluoroalkyl iodide as a telomer R f (CF 2 CF 2 ) n I (wherein R f is a C 1-10 fluoroalkyl group, and n is an integer of from 1 to 6) by telomerization from a fluoroalkyl iodide represented by the formula R f I (wherein R f is as defined above) as a telogen and tetrafluoroethylene (CF 2 CF 2 ) as a taxogen, which comprises a liquid phase telomerization step of supplying a homogeneous liquid mixture of the telogen and the taxogen from the lower portion of a tubular reactor, moving the mixture from the lower portion towards the upper portion of the reactor in the presence of a radical initiator over a retention time of at least 5 minutes while the reaction system is kept in a liquid phase state is under conditions where no gas-liquid separation will take place, so that the taxogen supplied to the reactor is substantially consumed by the reaction in the reactor, and drawing the reaction product from the upper portion of the reactor.

  通过从具有以下公式的氟烷基碘化物RfI（其中Rf是C1-10氟烷基团，n为1至6的整数）作为末端剂和四氟乙烯（CF2CF2）作为税原剂的氟烷基碘化物进行末端化，从而生产一种氟烷基碘化物Rf（CF2CF2）nI的过程，其中包括向管式反应器的下部供应末端剂和税原剂的均相液体混合物的液相末端化步骤，将混合物从下部向反应器的上部移动，在自由基引发剂的存在下，在至少5分钟的滞留时间内保持反应系统处于液相状态的条件下进行，这种条件下不会发生气液分离，以使供应到反应器的税原剂在反应器中基本被反应消耗，并从反应器的上部抽出反应产物。
• NOVEL FLUORINATED UNSATURATED CYCLIC CARBONATE AND PROCESS FOR PRODUCING SAME
  申请人：DAIKIN INDUSTRIES, LTD.

  公开号：US20180346437A1

  公开（公告）日：2018-12-06

  An unsaturated cyclic carbonate containing a fluorinated alkyl group represented by the following formula: wherein Rf is a C1-C8 fluorinated alkyl group.

  一种含有氟化烷基基团的不饱和环状碳酸酯，其化学式如下所示：其中Rf为C1-C8的氟化烷基基团。