1,2-二异丙氧基-3-甲基苯 | 287117-34-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯酚醚
• 中文名称: 1,2-二异丙氧基-3-甲基苯
• 英文名称: 1,2-Diisopropoxy-3-methyl-benzene
• 英文别名: 1-Methyl-2,3-di(propan-2-yloxy)benzene
• CAS: 287117-34-4
• 化学式: C₁₃H₂₀O₂
• 分子量: 208.301
• InChiKey: XAUPRQJNFHAUKF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  15
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.54
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,2-二异丙氧基-3-甲基苯 在 碘代三甲硅烷 、 四氯化钛 、 sodium hydride 作用下， 以 二氯甲烷 、 氯仿 、 N,N-二甲基甲酰胺 为溶剂， 反应 36.0h， 生成 2-methoxy-3-methylphenol
  参考文献：
  名称：

  A Concise Route to 3-Hydroxy-4-Methoxy-5-Methylbenzaldehyde Derivative

  摘要：

  3-Hydroxy-4-methoxy-5-methylbenzaldehyde derivative(1c) has been synthesized in 7 steps from 2,3-dihydroxytoluene (4). An isopropyl derivative has been used to protect a phenol during this transformation. The overall yield of 1c was 37%.

  DOI：

  10.1080/00397910008086883
• 作为产物：
  描述：

  3-甲基苯邻二酚 在 sodium hydride 、 potassium carbonate 作用下， 以 N,N-二甲基甲酰胺 、 丙酮 为溶剂， 反应 77.0h， 生成 1,2-二异丙氧基-3-甲基苯
  参考文献：
  名称：

  A Concise Route to 3-Hydroxy-4-Methoxy-5-Methylbenzaldehyde Derivative

  摘要：

  3-Hydroxy-4-methoxy-5-methylbenzaldehyde derivative(1c) has been synthesized in 7 steps from 2,3-dihydroxytoluene (4). An isopropyl derivative has been used to protect a phenol during this transformation. The overall yield of 1c was 37%.

  DOI：

  10.1080/00397910008086883

文献信息

• CHEMICAL COMPOUNDS
  申请人：ResMan AS

  公开号：US20150094240A1

  公开（公告）日：2015-04-02

  The present invention relates to novel compounds of polyfunctionalized polyethylene and polypropylene glycols, their synthesis and their use, in particular as tracers in applications related to oil and gas production, and especially as specific markers of various target fluids.
• ULTRAVIOLET CURABLE LIQUID COMPOSITION, ULTRAVIOLET CURING INKJET INK, ULTRAVIOLET CURING WET ELECTROPHOTOGRAPHIC LIQUID DEVELOPER, ULTRAVIOLET CURING ELECTROSTATIC INKJET INK, AND IMAGE FORMING METHOD USING THEREOF
  申请人：CANON KABUSHIKI KAISHA

  公开号：US20170336728A1

  公开（公告）日：2017-11-23

  An object of the present invention is to provide an ultraviolet curing liquid composition having high sensitivity, excellent storage stability, low viscosity, and excellent fixability after ultraviolet curing. The ultraviolet curable liquid composition of the present invention is an ultraviolet curable liquid composition containing a cationically polymerizable liquid monomer, a photopolymerization initiator and a photopolymerization sensitizer, wherein the cationically polymerizable liquid monomer is a vinyl ether compound, the photopolymerization initiator includes a compound represented by general formula (1), and the photopolymerization sensitizer includes (A) at least one compound selected from the group consisting of a compound represented by general formula (2) and a compound represented by general formula (3), and (B) at least one compound selected from the group consisting of a compound represented by general formula (4) and a compound represented by general formula (5).
• A Concise Route to 3-Hydroxy-4-Methoxy-5-Methylbenzaldehyde Derivative
  作者：Naoki Saito、Masashi Tachi、Ryu-Ichi Seki、Yayoi Sugawara、Eri Takeuchi、Akinori Kubo

  DOI：10.1080/00397910008086883

  日期：2000.7

  3-Hydroxy-4-methoxy-5-methylbenzaldehyde derivative(1c) has been synthesized in 7 steps from 2,3-dihydroxytoluene (4). An isopropyl derivative has been used to protect a phenol during this transformation. The overall yield of 1c was 37%.