1,3-双(5-甲基-2-吡啶基)苯 | 1056464-30-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 中文名称: 1,3-双(5-甲基-2-吡啶基)苯
• 英文名称: 1,3-bis(5-methyl-2-pyridyl)benzene
• 英文别名: 1,3-Di(5-methyl-2-pyridyl)benzene；5-methyl-2-[3-(5-methylpyridin-2-yl)phenyl]pyridine
• CAS: 1056464-30-2
• 化学式: C₁₈H₁₆N₂
• 分子量: 260.338
• InChiKey: AWKWKIXAWQLZQK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.8
• 重原子数：
  20
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  25.8
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  potassium tetrachloroplatinate(II) 、 1,3-双(5-甲基-2-吡啶基)苯 以 溶剂黄146 为溶剂， 以50%的产率得到[2,6-bis(5-methyl-2-pyridyl)phenyl-κ(3)N,C(1),N']chloridoplatinum(II)
  参考文献：
  名称：

  [2,6-Bis(5-methyl-2-pyridyl)phenyl-κ³N,C¹,N′]chloridoplatinum(II)

  摘要：

  In the title compound, [ Pt( C18H15N2) Cl], the Pt-II centre adopts a distorted square- planar coordination geometry due to the pincer- type monoanionic N - C - N tridentate ligand. The planar complexes stack via pi - pi interactions to form twodimensional accumulated sheets. This packing pattern is in contrast to that in related pincer- type N - C - N complexes, which exhibit a one- dimensional columnar stacking.

  DOI：

  10.1107/s0108270107044009
• 作为产物：
  描述：

  2-氯-5-甲基吡啶 、 1,3-二溴苯 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 、 potassium acetate 、 联硼酸频那醇酯 、 水 、 sodium hydroxide 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 反应 3.0h， 以59%的产率得到1,3-双(5-甲基-2-吡啶基)苯
  参考文献：
  名称：

  Single-flask preparation of polyazatriaryl ligands by sequential borylation/Suzuki–Miyaura coupling

  摘要：

  We report a convenient single-flask methodology for the preparation of polyazatriaryl products with relevance to luminescence, catalysis, and pharmacology. The diborylation of 1,3-dibromobenzenes and double Suzuki-Miyaura coupling produces 1,3-diheteroarylbenzenes. Similarly, borylation of heteroaryl halides and double coupling to 2,6-clichloropyridine produces 2,6-diheteroarylpyridines. This methodology appears general in producing challenging polyheteroaryl targets as long as the boronic esters have no ortho heteroatoms and coupling avoids adjacent oxygens. (C) 2011 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2011.01.136

文献信息

• ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES
  申请人：Universal Display Corporation

  公开号：US20190153009A1

  公开（公告）日：2019-05-23

  A compound comprising a tridentate ligand L A selected from Formula I. The ligand L A is complexed to a metal M. wherein Z 1 and Z 2 are independently C or N, wherein if Z 1 is C, then Z 2 is N, or if Z 1 is N then Z 2 is C; X 1 , X 2 , X 3 , and X 4 are independently selected from CR 1 or N, and R 1 can be the same or different for each of X 1 , X 2 , X 3 , and X 4 ; X 5 , X 6 , and X 7 are independently selected from CR 2 or N, and R 2 can be the same or different for each of X 5 , X 6 , and X 7 ; X 8 is independently selected from CR 3 or N; and Y is selected from CR Y or N, and R Y is selected from hydrogen, deuterium, halide, alkyl, cycloalkyl, heteroalkyl, cycloalkenyl, heteroalkenyl, aryl, heteroaryl, nitrile, and combinations thereof, or optionally, R Y can form a ring with R 3 . An OLED that includes an anode, a cathode, and an organic layer disposed between the anode and the cathode. The organic layer will include a compound of Formula I, and a consumer product that includes the OLED.

  一种化合物，包括从式I中选择的三牙配体LA。配体LA与金属M形成络合物。其中Z1和Z2独立地为C或N，如果Z1为C，则Z2为N，或者如果Z1为N，则Z2为C；X1、X2、X3和X4独立地选择自CR1或N，并且R1可以对于X1、X2、X3和X4中的每个都相同或不同；X5、X6和X7独立地选择自CR2或N，并且R2可以对于X5、X6和X7中的每个都相同或不同；X8独立地选择自CR3或N；Y选择自CRY或N，RY选择自氢、氘、卤素、烷基、环烷基、杂原子烷基、环烯基、杂原子烯基、芳基、杂原子芳基、腈基和它们的组合，或者可选地，RY可以与R3形成环。一种OLED，包括阳极、阴极和位于阳极和阴极之间的有机层。有机层将包括式I的化合物，以及包括OLED的消费产品。
• LUMINOPHORES
  申请人：Bruce Duncan W.

  公开号：US20120157681A1

  公开（公告）日：2012-06-21

  There is described novel organo-platinum luminophores comprising a complex of formula I: The luminophores have application as the emissive component in organic light emitting diodes.

  描述了一种新型有机铂发光体，包括公式I的复合物：这些发光体可作为有机发光二极管中的发光组分。
• Luminophores
  申请人：University of York

  公开号：US08106193B2

  公开（公告）日：2012-01-31

  There is described novel organo-platinum luminophores comprising a complex of formula (I). The luminophores have application as the emissive component in organic light emitting diodes.

  描述了一种新型有机铂发光体，包括公式（I）的复合物。这种发光体可以作为有机发光二极管中的发射组分。
• Organic electroluminescent materials and devices
  申请人：Universal Display Corporation

  公开号：US11168103B2

  公开（公告）日：2021-11-09

  The present invention provides compounds comprising a tridentate ligand LA wherein LA is complexed to a metal, M. The metal complexes comprising the tridentate ligand LA may be useful in an organic layer disposed between the anode and the cathode in an organic light emitting device (OLED).

  本发明提供了包含三叉配体LA的化合物，其中LA与金属M络合。包含三叉配体LA的金属络合物可用于有机发光器件（OLED）中阳极和阴极之间的有机层。
• US8106193B2
  申请人：——

  公开号：US8106193B2

  公开（公告）日：2012-01-31