1-(2-甲氧基乙氧基)乙醇 | 108743-21-1

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-(2-甲氧基乙氧基)乙醇
• 英文名称: (2-methoxyethoxy)ethanol
• 英文别名: Methoxyethoxyethanol；1-(2-methoxyethoxy)ethanol
• CAS: 108743-21-1
• 化学式: C₅H₁₂O₃
• 分子量: 120.148
• InChiKey: SXYRTDICSOVQNZ-UHFFFAOYSA-N

物化性质

• 沸点：
  97.1±15.0 °C(Predicted)
• 密度：
  0.987±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  -0.2
• 重原子数：
  8
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  38.7
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1-(2-甲氧基乙氧基)乙醇 生成 乙二醇甲醚 、 乙醛
  参考文献：
  名称：

  Acid- and base-catalyzed decomposition of acetaldehyde hydrate and hemiacetals in aqueous solution

  摘要：

  DOI：

  10.1021/ja00249a034
• 作为产物：
  描述：

  1,1-乙二醇 、 乙二醇甲醚 以 重水 为溶剂， 生成 1-(2-甲氧基乙氧基)乙醇
  参考文献：
  名称：

  Interactive n→ delocalizations that control an aqueous organic equilibrium

  摘要：

  Hydrated acetaldehydes were condensed in D2O with substituted alcohols and thiols to determine Delta G Of hemiacetalization by H-1 NMR. Specific n-->sigma* delocalizations in the alkoxy/alkylthio functionality of the product interact to influence n-->sigma* delocalization in the hemiacetal functionality. Delocalization in the latter functionality controls Delta G. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/s0040-4039(97)82941-3

文献信息

• Polymerizable thiophene monomers
  申请人：Cookson Group plc

  公开号：US04992559A1

  公开（公告）日：1991-02-12

  Thiophene derivatives of the formula ##STR1## wherein R.sup.1 and R.sup.2 are certain specified substituent groups can be homopolymerized or copolymerized to form polymers which are electroconductive. These polymers find many uses, for example, as EMI/RF shielding materials, in electrochromic display systems, as antistatics, as ion and pH sensors, as battery electrode materials etc.

  公式为##STR1##的噻吩衍生物，其中R.sup.1和R.sup.2为特定的取代基团，可以进行同聚或共聚反应，形成电导聚合物。这些聚合物有许多用途，例如作为EMI / RF屏蔽材料，在电致色显示系统中，作为抗静电剂，作为离子和pH传感器，作为电池电极材料等。
• Substituted and unsubstituted 13-(alkoxy)methoxy derivatives of the
  申请人：Merck & Co., Inc.

  公开号：US04587247A1

  公开（公告）日：1986-05-06

  Novel substituted and unsubstituted 13-(alkoxy)methoxy derivatives of the avermectin aglycones are useful as anthelmintic and antiparasitic agents. The compounds are also useful as pesticides and insecticides against agricultural pests. Included herein are novel intermediates useful in the process for preparing said avermectin aglycone derivatives. Compositions of said derivatives and methods of administering said compositions are also disclosed.

  新型替代和非替代的13-(烷氧基)甲氧基阿维菌素缺糖衍生物可用作驱虫和抗寄生虫剂。这些化合物还可用作农业害虫的杀虫剂和杀虫剂。本文介绍了用于制备所述阿维菌素缺糖衍生物的新型中间体。还公开了所述衍生物的组合物和给药方法。
• Interactive n→ delocalizations that control an aqueous organic equilibrium
  作者：Yun-Hua Fan、John Haseltine

  DOI：10.1016/s0040-4039(97)82941-3

  日期：1996.12

  Hydrated acetaldehydes were condensed in D2O with substituted alcohols and thiols to determine Delta G Of hemiacetalization by H-1 NMR. Specific n-->sigma* delocalizations in the alkoxy/alkylthio functionality of the product interact to influence n-->sigma* delocalization in the hemiacetal functionality. Delocalization in the latter functionality controls Delta G. Copyright (C) 1996 Elsevier Science Ltd
• Acid- and base-catalyzed decomposition of acetaldehyde hydrate and hemiacetals in aqueous solution
  作者：Poul E. Sorensen、William P. Jencks

  DOI：10.1021/ja00249a034

  日期：1987.7