1-(4-氨基-2,5-二甲基苯基)乙酮 | 80539-09-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-(4-氨基-2,5-二甲基苯基)乙酮
• 英文名称: 4-amino-2,5-dimethylacetophenone
• 英文别名: 1-(4-amino-2,5-dimethyl-phenyl)-ethanone；1-(4-Amino-2,5-dimethyl-phenyl)-aethanon；4-Amino-2.5-dimethylacetophenon；1-(4-Amino-2,5-dimethylphenyl)ethan-1-one；1-(4-amino-2,5-dimethylphenyl)ethanone
• CAS: 80539-09-9
• 化学式: C₁₀H₁₃NO
• 分子量: 163.219
• InChiKey: RXQJGDKYXGBWOJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.7
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.3
• 拓扑面积：
  43.1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1-(4-氨基-2,5-二甲基苯基)乙酮 、 2,6-二甲基苯肼 在 溶剂黄146 作用下， 以33%的产率得到4-amino-2,5-dimethylacetophenone 2,6-dimethylphenylhydrazone
  参考文献：
  名称：

  Sannicolo, Franco, Gazzetta Chimica Italiana, 1981, vol. 111, # 7/8, p. 351 - 356

  摘要：

  DOI：
• 作为产物：
  描述：

  2,5-二甲基乙酰苯胺 在 盐酸 、 三氯化铝 作用下， 以 硝基苯 为溶剂， 反应 20.0h， 生成 1-(4-氨基-2,5-二甲基苯基)乙酮
  参考文献：
  名称：

  Sannicolo, Franco, Gazzetta Chimica Italiana, 1981, vol. 111, # 7/8, p. 351 - 356

  摘要：

  DOI：

文献信息

• Steric Effects of Alkyl Substituents upon the Opening of the Lactone Ring of Coumaran-2,3-diones
  作者：Teruo Matsuura、Masao Kawai、Yasuo Butsugan

  DOI：10.1246/bcsj.43.3891

  日期：1970.12

  The stability of the lactone rings of alkyl substituted coumaran-2,3-diones against hydrolysis and alcoholysis is greatly affected by the positions of alkyl substituents. From UV spectral studies it was suggested that methyl substitutions at positions adjacent to the lactone ring contribute to stability for steric reasons.

  烷基取代的香豆素-2,3-二酮的内酯环对水解和醇解的稳定性在很大程度上受到烷基取代基位置的影响。紫外光谱研究表明，由于立体原因，内酯环邻近位置的甲基取代有助于提高稳定性。
• Eckert et al., Comptes Rendus Hebdomadaires des Seances de l'Academie des Sciences, 1951, vol. 233, p. 1461
  作者：Eckert et al.

  DOI：——

  日期：——
• The Orientation in the Nitration of 3,4- and 2,5-Dimethylacetophenone
  作者：Ng. Ph. Buu-Hoi、Bernard Eckert、Rene Royer

  DOI：10.1021/jo50007a014

  日期：1952.7
• LCP DERIVATIVE/SOFT MAGNETIC FERRITE COMPOSITE MATERIAL AND PREPARATION METHOD THEREFOR
  申请人：YUNNAN INFINE NEO-MATERIAL CO., LTD

  公开号：US20170210878A1

  公开（公告）日：2017-07-27

  The present invention provides an LCP derivative/soft magnetic ferrite composite material, which is prepared by complexing and assembling an LCP derivative as a host and soft magnetic ferrite particles as a guest. The present invention also provides a method for preparing the composite material. The composite material of the present invention has high stability and is not easily dissociated, and has high customized magnestic permeability, dielectricity, thermal stability, environmental resistance, and chemical resistance; and the preparation process of the composite material meets the energy-saving and emission reduction requirements. Therefore, the composite material has a wide industrial application prospect. The composite material of the present invention can be widely applied to the wireless communication field, the aviation, spaceflight and military fields, the microwave and radio frequency component application field, the automotive electronic component field, and the like.
• Sannicolo, Franco, Gazzetta Chimica Italiana, 1981, vol. 111, # 7/8, p. 351 - 356
  作者：Sannicolo, Franco

  DOI：——

  日期：——