1-丁氧基-1-氯丁烷 | 102312-44-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-丁氧基-1-氯丁烷
• 英文名称: butyl-(1-chloro-butyl)-ether
• 英文别名: 1-Butoxy-1-chlor-butan；Butyl-(1-chlor-butyl)-aether；1-Butoxy-1-chlorobutane
• CAS: 102312-44-7
• 化学式: C₈H₁₇ClO
• 分子量: 164.675
• InChiKey: CHFOWCDVIRGTNL-UHFFFAOYSA-N

物化性质

• 沸点：
  185.9±13.0 °C(Predicted)
• 密度：
  0.921±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.3
• 重原子数：
  10
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-丁氧基-1-氯丁烷 在 sodium acetate 作用下， 生成 buten-1-yl butyl ether
  参考文献：
  名称：

  Synthesis of 1-Alkenyl Alkyl Ethers

  摘要：

  DOI：

  10.1021/jo01099a007
• 作为产物：
  描述：

  正丁醛 、 正丁醇 在 氯化亚砜 作用下， 生成 1-丁氧基-1-氯丁烷
  参考文献：
  名称：

  DE880285

  摘要：

  公开号：

文献信息

• Haloalkylation of aromatic compounds
  申请人：ETHYL CORPORATION

  公开号：EP0369728A1

  公开（公告）日：1990-05-23

  The co-formation of diarylalkane by-product in the haloalkylation of an aromatic compound with an ether corre­sponding to the formula R-O-R′, wherein R is an α-halo­alkyl group containing at least two carbons and R′ is R or alkyl, is minimized by conducting the reaction with agita­tion in the presence of both hydrogen sulfate and a hydro­gen halide.

  在芳香族化合物与对应于式 R-O-R′ 的醚进行卤代烷基化反应时，通过在硫酸 氢和卤化氢存在下搅拌进行反应，可最大限度地减少二芳基烷烃副产物的共生成。
• Teramura; Oda, Kogyo Kagaku zasshi / Journal of the Society of Chemical Industry, 1951, vol. 54, p. 604,606
  作者：Teramura、Oda

  DOI：——

  日期：——
• Ozone reactions with aliphatic ethers in CCl4. Kinetics and mechanism
  作者：S. K. Rakovsky、D. R. Cherneva、M. Deneva

  DOI：10.1002/kin.550270206

  日期：1995.2

  AbstractThe kinetics and mechanism of ozone reactions with aliphatic ethers in CCl4 solution have been investigated with a set of six symmetrical ethers: ethyl, chloroethyl, iso‐propyl, n‐butyl, iso‐amyl, and n‐amyl. The corresponding kinetic constants at ambient temperature are 3.1, 0.035, 5.4, 6.3, 6.8, and 7.8 1/(mol s). Upon ozonation of n‐butylether the main products are butylalcohol, butylaldehyde (butyric acid), and butylbutyrate. A common precursor of these products is the α‐hydrotrioxybutylether. Experimental values of the preexponential factors are compared with those calculated according to the activation complex theory with linear or cyclic form of the activated complex. The cyclic form of the activated complexes is unfavorable because of the kinetic factor. Abstraction of hydrogen atom or the far less probable hydride ion abstraction from α‐position in the ether molecules is the rate‐determining step of ozonation. The rate‐determining factors are the electron density and geometry of the reaction center and the energy of the α‐CH bonds. © 1995 John Wiley & Sons, Inc.
• Rozinov,V.G. et al., Journal of general chemistry of the USSR, 1969, vol. 39, p. 1615
  作者：Rozinov,V.G. et al.

  DOI：——

  日期：——
• HALOALKYLATION PROCESS
  申请人：ALBEMARLE CORPORATION

  公开号：EP0767768B1

  公开（公告）日：1999-03-31