1-癸烯-4-醇,3,4-二甲基- | 197141-28-9

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1-癸烯-4-醇,3,4-二甲基-
• 英文名称: 3,4-Dimethyl-dec-1-en-4-ol
• 英文别名: 3,4-Dimethyldec-1-EN-4-OL
• CAS: 197141-28-9
• 化学式: C₁₂H₂₄O
• 分子量: 184.322
• InChiKey: AWCUIMMQNFZKDC-UHFFFAOYSA-N

物化性质

• 沸点：
  249.8±9.0 °C(Predicted)
• 密度：
  0.839±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  1-癸烯-4-醇,3,4-二甲基- 在 对苯醌 、 palladium dichloride 作用下， 反应 3.0h， 以61%的产率得到5-Hexyl-4,5-dimethyl-tetrahydro-furan-2-ol
  参考文献：
  名称：

  A new synthetic method for γ-butyrolactols by the paladium-catalyzed regioselective oxidation of 1-alken-4-ols

  摘要：

  DOI：

  10.1016/s0040-4039(00)80713-3
• 作为产物：
  描述：

  仲辛酮 、 crotyltris(diethylamino)titanium 生成 1-癸烯-4-醇,3,4-二甲基-
  参考文献：
  名称：

  REELZ, M. T.;STEINBACH, R.;WESTERMANN, J.;PETER, R.;WENDEROTH, B., CHEM. BER., 1985, 118, N 4, 1441-1454

  摘要：

  DOI：

文献信息

• Barbier/Grignard-Type Allylation or Benzylation Mediated by the Mischmetall/SmI2(cat.) System
  作者：Aurore Di Scala、Stefania Garbacia、Florence Hélion、Marie-Isabelle Lannou、Jean-Louis Namy

  DOI：10.1002/1099-0690(200209)2002:17<2989::aid-ejoc2989>3.0.co;2-0

  日期：2002.9

  achieved by the use of samarium diiodide in catalytic amounts together with mischmetall (an alloy of the light lanthanides) as a coreductant. Plausible catalytic schemes are proposed. In addition, organocerium and -lanthanum reagents have been obtained from samarium diiodide catalysed reactions between organic halides and cerium or lanthanum metal, giving a new route to organolanthanoid compounds. It also

  Barbier 和 Grignard 型烯丙基化和苄基化是通过使用催化量的二碘化钐和作为助还原剂的混合稀土（一种轻镧系元素的合金）实现的。提出了合理的催化方案。此外，通过二碘化钐催化有机卤化物与铈或镧金属的反应获得有机铈和镧试剂，为有机镧系化合物提供了一条新途径。铈和镧的三价苄基和烯丙基有机金属化合物似乎比相应的钐更稳定。(© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)
• Preparation and reactions of samarium diiodide in nitriles
  作者：Béatrice Hamann、Jean-Louis Namy、Henri B. Kagan

  DOI：10.1016/0040-4020(96)00861-7

  日期：1996.11

  Samarium diiodide can be prepared from samarium metal in various nitriles. Because of its chemical inertness pivalonitrile is the most suitable solvent. Organic reactions mediated by SmI2 are slower than in THF, but selectivities are often improved. Reactions are greatly accelerated by addition of catalytic amounts of some transition metal salts.

  可以从各种腈中的金属metal制备二碘化prepared。由于其化学惰性，新戊腈是最合适的溶剂。由SmI 2介导的有机反应比在THF中慢，但选择性通常得到改善。通过加入催化量的某些过渡金属盐，可大大加快反应速度。
• Organosamariums: preparation using diiodosamarium and reactivity in tetrahydropyran
  作者：Béatrice Hamann-Gaudinet、Jean-Louis Namy、Henri B. Kagan

  DOI：10.1016/s0022-328x(98)00666-4

  日期：1998.9

  Diiodosamarium prepared in tetrahydropyran reduces allylic, benzylic and alkyl halides at 0 or -15 degrees C to give organosamariums which are stable under these conditions. The reactivity of these organometallics has been explored, showing that they are very selective reagents. (C) 1998 Elsevier Science S.A. All rights reserved.
• Generation and reactivity of allylic and benzylic samarium compounds using diiodosamarium in tetrahydropyran
  作者：Béatrice Hamann-Gaudinet、Jean-Louis Namy、Henri B. Kagan

  DOI：10.1016/s0040-4039(97)01506-2

  日期：1997.9

  Diiodosamarium prepared in THP reduces allylic iodides and bromides at 0 or -15 degrees C to give organosamarium compounds which are stable under these conditions. These allylic samarium compounds react with many functionalities including the keto group of keto esters. Benzylic samarium compounds were prepared similarly from benzylic bromides. (C) 1997 Elsevier Science Ltd.
• NOKAMI, JUNZO;OGAWA, HIDEKI;MIYAMOTO, SHINYA;MANDAI, TADAKATSU;WAKABAYASH+, TETRAHEDRON LETT., 29,(1988) N 40, C. 5181-5184
  作者：NOKAMI, JUNZO、OGAWA, HIDEKI、MIYAMOTO, SHINYA、MANDAI, TADAKATSU、WAKABAYASH+

  DOI：——

  日期：——