1H,1H,2H,3H,3H-全氟壬烷-1,2-二醇 | 107650-06-6

• 分子结构分类: 有机化合物 - 有机氧化合物
• 中文名称: 1H,1H,2H,3H,3H-全氟壬烷-1,2-二醇
• 中文别名: 1H,1H,2H,3H,3H-全氟-1,2-壬二醇
• 英文名称: 4,4,5,5,6,6,7,7,8,8,9,9,9-tridecafluorononane-1,2-diol
• 英文别名: 1H,1H,2H,3H,3H-Perfluoro-1,2-nonanediol
• CAS: 107650-06-6
• 化学式: C₉H₇F₁₃O₂
• mdl: MFCD00042262
• 分子量: 394.133
• InChiKey: DAHZCNRVTNHGGR-UHFFFAOYSA-N

物化性质

• 熔点：
  63-64°C
• 沸点：
  120-130°C
• 密度：
  1.617±0.06 g/cm3(Predicted)
• 闪点：
  >150°C
• 稳定性/保质期：
  常温常压下稳定，避免与强氧化剂接触。

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  24
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  40.5
• 氢给体数：
  2
• 氢受体数：
  15

安全信息

• 危险品标志：
  Xi
• 危险类别码：
  R36/37/38
• 海关编码：
  2905590090
• 安全说明：
  S26,S36/37/39

反应信息

• 作为反应物：
  描述：

  1H,1H,2H,3H,3H-全氟壬烷-1,2-二醇 在 氢氧化钾 、 三苯基膦 、 偶氮二甲酸二乙酯 作用下， 以 四氢呋喃 、 甲苯 为溶剂， 反应 50.0h， 生成 2-(1H,1H-perfluoroheptyl)-2,3-dihydrothieno[3,4-b]-[1,4]-dioxine-5,7-dicarboxylic acid
  参考文献：
  名称：

  Synthesis and characterization of perfluorohexylated poly(3,4-ethylenedioxythiophene)

  摘要：

  The perfluorohexylated 3,4-ethylenedioxythiophene 5 was prepared via Mitsunobu reaction of perfluorohexylatyed diol 2 with diethyl 3,4-dihydroxythiophenedicarboxylate followed by decarboxylation. The polymerization of 5 was conducted with both oxidative chemical and electrochemical polymerizations. The polymers were characterized by cyclic voltammogram, UV, IR, TGA and DSC. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2004.04.011
• 作为产物：
  描述：

  3-(perfluorohexyl)prop-1-ene 在 四氧化锇 、 2-氯-N-(2-氯乙基)-N-甲基乙胺氧化物 作用下， 以 丙酮 、 叔丁醇 为溶剂， 反应 24.0h， 以90%的产率得到1H,1H,2H,3H,3H-全氟壬烷-1,2-二醇
  参考文献：
  名称：

  Synthesis and characterization of perfluorohexylated poly(3,4-ethylenedioxythiophene)

  摘要：

  The perfluorohexylated 3,4-ethylenedioxythiophene 5 was prepared via Mitsunobu reaction of perfluorohexylatyed diol 2 with diethyl 3,4-dihydroxythiophenedicarboxylate followed by decarboxylation. The polymerization of 5 was conducted with both oxidative chemical and electrochemical polymerizations. The polymers were characterized by cyclic voltammogram, UV, IR, TGA and DSC. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jfluchem.2004.04.011

文献信息

• Chemistry of [(perfluoroalkyl)methyl] oxiranes. Regioselectivity of ring opening with O-nucleophiles and the preparation of amphiphilic monomers
  作者：Vladimı́r Cı́rkva、Bruno Améduri、Bernard Boutevin、Oldřich Paleta

  DOI：10.1016/s0022-1139(97)00032-8

  日期：1997.8

  diols was controlled to proceed with one or two molecules of the oxiranes chemoselectively. Non-regioselective, base-catalysed ring opening by methacrylic acid (83% terminal attack) was discussed on the basis of the hard and soft acids and bases (HSAB) concept. A convenient transformation of the oxiranes to the corresponding diols 13a–13c via dioxolane intermediates, and their conversion to bis-methacrylates

  环氧乙烷的反应中[R ˚F CH 2 CH（-O-）CH 2（R ˚F ≡C 4 ˚F 9，C 6 ˚F 13，C 8 ˚F 17 ;图4a - 4c中）与一系列的链烷醇在路易斯酸的存在下在末端碳原子上以完全的区域选择性发生。甲基丙烯酸2-羟基乙酯和丙烯酸酯反应相似。控制与链烷二醇的反应以化学选择性地与一或两个分子的环氧乙烷进行。在硬，软酸和碱（HSAB）概念的基础上，讨论了甲基丙烯酸的非区域选择性的，碱催化的开环反应（83％的末端攻击）。通过二氧戊环中间体方便地将环氧乙烷酮转化为相应的二醇13a - 13c，并将其转化为双甲基丙烯酸酯，总收率为75％-79％。硫脲将环氧乙烷转化为相应的硫杂环丁烷（15a - 15c）。反应提供的产物收率通常为82％–98％。
• Novel polymers, resist compositions and patterning process
  申请人：——

  公开号：US20010033989A1

  公开（公告）日：2001-10-25

  Polymers having fluorinated ester groups are novel. Using the polymers, resist compositions featuring low absorption of F 2 excimer laser light are obtained.

  具有氟酯基团的聚合物是新型的。使用这些聚合物，可以获得具有低吸收F2准分子激光光的抗蚀剂组成物。
• INK COMPOSITION, INKJET RECORDING METHOD AND PROCESS FOR PRODUCING MOLDED PRINTED MATERIAL
  申请人：MOCHIZUKI Kyohei

  公开号：US20110242191A1

  公开（公告）日：2011-10-06

  An ink composition is provided that includes (Component a) an open-chain and/or cyclic ether bond-containing monofunctional (meth)acrylate, (Component b) one or more monofunctional ethylenically unsaturated compounds selected from the group consisting of a polycyclic aliphatic group-containing monofunctional (meth)acrylate and N-vinyl-2-caprolactam, (Component c) a polymerization initiator, (Component e) a polyfunctional (meth)acrylate at no greater than 10 wt % relative to the ink composition, and (Component f) a fluorine-substituted hydrocarbon group- or siloxane structure-containing polymer, the ratio by weight of (Component a)/(Component b) being 0.7 to 1.9. There are also provided an inkjet recording method that includes (a 1 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method and (b 1 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a cured image above the recording medium, and a process for producing a molded printed material that includes (a 2 ) an image formation step of forming an image above a recording medium by discharging the ink composition by an inkjet method, (b 2 ) a curing step of curing the ink composition by irradiating the obtained image with actinic radiation to thus obtain a printed material having a cured image above the recording medium, and (c 2 ) a molding step of molding the printed material.

  提供了一种墨水组合物，包括（组分a）一种开链和/或环状醚键含有单官能基（甲基）丙烯酸酯，（组分b）一种或多种单官能基乙烯基不饱和化合物，所述化合物选自包含多环脂肪族基的单官能基（甲基）丙烯酸酯和N-乙烯基-2-己内酰胺的群组，（组分c）一种聚合引发剂，（组分e）一种多官能基（甲基）丙烯酸酯，相对于墨水组合物不大于10重量％，以及（组分f）一种含有氟代烃基或硅氧烷结构的聚合物，其中（组分a）/（组分b）的重量比为0.7到1.9。还提供了一种喷墨记录方法，包括（a1）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤和（b1）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得固化图像，以及一种生产模塑印刷材料的过程，包括（a2）通过喷墨方法排放墨水组合物形成记录介质上的图像形成步骤，（b2）通过照射获得的图像进行光致固化的固化步骤，从而在记录介质上获得具有固化图像的印刷材料，以及（c2）模塑印刷材料的模塑步骤。
• Water-soluble polyurethane comb polymer production
  申请人：UNION CARBIDE CORPORATION

  公开号：EP0151748A1

  公开（公告）日：1985-08-21

  Water soluble polyurethanes, having hydrophilic polyether backbone and pendant monovalent hydrophobic groups of sufficient size and number while establishing proper hydrophilic/lipophilic balance, provide improved thickening of aqueous systems.

  水溶性聚氨酯具有亲水性聚醚骨架和足够大小和数量的单价疏水悬垂基团，同时还能建立适当的亲水/亲油平衡，从而改善水性体系的增稠效果。
• Contact lens material
  申请人：KUREHA KAGAKU KOGYO KABUSHIKI KAISHA

  公开号：EP0289797A2

  公开（公告）日：1988-11-09

  Disclosed herein is a contact lens material comprising a polymer obtained by reacting and polymerizing 15 - 100 wt.% of the following component (A) and 0 - 85 wt.% of the following component (B) and containing fluorinated side chains and urethane bonds: Component (A): A mixture of (1) a radical-polymerizable monomer containing at least one active hydrogen atom which can undergo an addition reaction with an isocyanate group, (2) a bifunctional or higher polyisocyanate compound and (3) a compound represented by Rf·(OH)n, Rf·COOH, Rf·NH₂ or Rf·CONH₂ wherein n stands for 1 or 2 and Rf means a fluorinated C₁₋₂₅-alkyl group, alkylphenyl group or phenyl group; or an addition reaction product thereof. Component (B): A monomer copolymerizable with the radical-­polymerizable monomer (1) of the component (A). The contact lens material has well-balanced properties among oxygen permeability, hardness, machinability, wearing comfortableness, etc.

  本发明公开了一种隐形眼镜材料，该材料包含一种聚合物，该聚合物是由 15-100 重量份的以下组分（A）和 0-85 重量份的以下组分（B）反应聚合而成，并含有氟化侧链和聚氨酯键： 组分（A）： (1) 含至少一个活性氢原子的可自由基聚合单体的混合物，该单体可与异氰酸酯基团发生加成反应、(2) 双官能度或更高的多异氰酸酯化合物和 (3) 由 Rf-(OH)n、Rf-COOH、Rf-NH₂ 或 Rf-CONH₂ 代表的化合物，其中 n 代表 1 或 2，Rf 指氟化 C₁₋₂₅-烷基、烷基苯基或苯基；或其加成反应产物。 组分 (B)： 可与组分（A）中可自由基聚合的单体（1）共聚的单体。 该隐形眼镜材料在透氧性、硬度、可加工性、佩戴舒适性等方面具有良好的平衡特性。