camphor phenylhydrazone | 2513-91-9

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: camphor phenylhydrazone
• 英文别名: bornan-2-one-phenylhydrazone；Bornan-2-on-phenylhydrazon；Campher-phenylhydrazon；N-[(1,7,7-trimethyl-2-bicyclo[2.2.1]heptanylidene)amino]aniline
• CAS: 2513-91-9；85249-85-0
• 化学式: C₁₆H₂₂N₂
• 分子量: 242.364
• InChiKey: DSIONIRZDGREDD-UHFFFAOYSA-N

物化性质

• 熔点：
  150-151 °C
• 沸点：
  334.6±25.0 °C(Predicted)
• 密度：
  1.09±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  24.4
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  camphor phenylhydrazone 在 benzyltriphenylphosphonium peroxodisulfate 作用下， 以 乙腈 为溶剂， 反应 0.27h， 以92%的产率得到樟脑
  参考文献：
  名称：

  Benzyltriphenylphosphonium Peroxodisulfate (PhCH₂PPh₃)₂S₂O₈: An Efficient and Convenient Reagent for the Oxidative Cleavage of Phenylhydrazones, Paranitrophenylhydrazones, and Semicarbazones to Their Parent Carbonyl Compounds

  摘要：

  Deprotection of phenylhydrazones, paranitrophenylhydrazones, and semicarbazones to their parent aldehydes and ketones in high yields has been carried out using benzyltriphenylphosplionium peroxodisulfate as a selective oxidant under mild conditions.

  DOI：

  10.1080/714040975

文献信息

• Tajbakhsh, Mahmood; Mohammadpoor-Baltork, Iraj; Ramzanian-Lehmali, Farhad, Journal of Chemical Research - Part S, 2003, # 11, p. 710 - 711
  作者：Tajbakhsh, Mahmood、Mohammadpoor-Baltork, Iraj、Ramzanian-Lehmali, Farhad

  DOI：——

  日期：——
• Benzyltriphenylphosphonium Peroxodisulfate (PhCH₂PPh₃)₂S₂O₈: An Efficient and Convenient Reagent for the Oxidative Cleavage of Phenylhydrazones, Paranitrophenylhydrazones, and Semicarbazones to Their Parent Carbonyl Compounds
  作者：Mahmood Tajbakhsh、Iraj Mohammadpoor-Baltork、Farhad Ramzanian-Lehmali

  DOI：10.1080/714040975

  日期：2003.12.1

  Deprotection of phenylhydrazones, paranitrophenylhydrazones, and semicarbazones to their parent aldehydes and ketones in high yields has been carried out using benzyltriphenylphosplionium peroxodisulfate as a selective oxidant under mild conditions.