trans-4-Hexylcyclohexanecarboxylic acid | 38289-30-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 羧酸及其衍生物
• 英文名称: trans-4-Hexylcyclohexanecarboxylic acid
• 英文别名: trans-4-n-trans-cyclohexanecarboxylic acid；trans 4-n-hexylcyclohexanecarboxylic acid；trans-4-(hexyl)cyclohexanecarboxylic acid；4-hexyl-trans-cyclohexanecarboxylic acid；trans-4-hexylcyklohexane-carboxylic acid；trans-4-n-hexylcyclohexylcarboxylic acid
• CAS: 38289-30-4
• 化学式: C₁₃H₂₄O₂
• 分子量: 212.332
• InChiKey: POEBGIQSFIJHAX-HAQNSBGRSA-N

物化性质

• 沸点：
  321.2±10.0 °C(Predicted)
• 密度：
  0.955±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.85
• 重原子数：
  15.0
• 可旋转键数：
  6.0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  37.3
• 氢给体数：
  1.0
• 氢受体数：
  1.0

安全信息

• 海关编码：
  2916209090

反应信息

• 作为反应物：
  描述：

  trans-4-Hexylcyclohexanecarboxylic acid 在 lithium aluminium tetrahydride 、 氯化亚砜 、 硫酸 、 氢溴酸 作用下， 以 乙醚 、 溶剂黄146 、 二甲基亚砜 为溶剂， 生成 2-(4-Hexyl-cyclohexyl)-1-phenyl-ethanone
  参考文献：
  名称：

  Carr; Gray; McDonnell, Molecular Crystals and Liquid Crystals (1969-1991), 1982, vol. 97, # 1-4, p. 13 - 28

  摘要：

  DOI：
• 作为产物：
  描述：

  4-己基苯甲酸 以 对丁基环已烷甲酸 为溶剂， 以60% (35.7 g)的产率得到trans-4-Hexylcyclohexanecarboxylic acid
  参考文献：
  名称：

  Long-acting androgenic compounds and pharmaceutical compositions thereof

  摘要：

  长效雄激素组合物包括C.sub.4-C.sub.6环烷基羧酸睾酮和一种药用可接受载体介质。酯类化合物可以溶解在一种可接受的油性介质中，或者以微粉化颗粒的形式悬浮在水性介质中，或以研磨颗粒的形式存在。

  公开号：

  US04948790A1

文献信息

• Liquid crystal 2,3-dicyano-hydroquinone derivatives
  申请人：Chisso Corporation

  公开号：US04279770A1

  公开（公告）日：1981-07-21

  Liquid crystal materials for liquid crystal display, having a large negative dielectric anisotropy and maintaining a liquid crystal state at a broad temperature range including room temperature are provided. These materials contain novel compounds expressed by the general formula (I) ##STR1## wherein X represents ##STR2## Y represents ##STR3## R.sup.1 and R.sup.3 each represent an alkyl group or an alkyloxy group of 1-10 carbon atoms; R.sup.2 and R.sup.4 each represent an alkyl group of 1-10 carbon atoms; but compounds wherein ##STR4## are excluded.

  提供了用于液晶显示器的液晶材料，具有大的负介电各向异性，并在包括室温在内的广泛温度范围内保持液晶状态。这些材料包含由通式（I）表示的新化合物 ##STR1## 其中X表示##STR2## Y表示##STR3## R1和R3分别表示1-10个碳原子的烷基或烷氧基；R2和R4分别表示1-10个碳原子的烷基；但是排除了其中##STR4##的化合物。
• New (1R,4R)-2-arylidene-p-menthan-3-ones with a bridging ester group in the arylidene fragment. Synthesis and behavior in liquid-crystalline systems
  作者：V. V. Vashchenko、L. A. Kutulya、M. N. Pivnenko、N. I. Shkolnikova

  DOI：10.1023/b:rucb.0000012363.37580.30

  日期：2003.11

  (1R,4R)-2-(4-Hydroxybenzylidene)- and (1R,4R)-2-(4'-hydroxybiphenyl-4-yl)methylene-p-menthan-3-ones were synthesized by condensation of (-)-menthone with O-tetrahydropyran-2-yl derivatives of 4-hydroxybenzaldehyde and 4'-hydroxy-4-formylbiphenyl, respectively, in a DMSO-base medium followed by the removal of the protective group. The reactions of these hydroxy derivatives with 4-alkylbenzoic, 4-alkyloxybenzoic, traps-4-alkylcyclohexane-4-carboxylic, and 4'-alkylbiphenyl-4-carboxylic acids afforded three series of new chiral esters. Compounds containing the arylidene moiety with three benzene rings were found to exhibit liquid-crystalline properties. The characteristic features of these compounds are discussed based on the results of studies by polarizing microscopy, differential scanning calorimetry, and small-angle X-ray scattering. It was found that the mesomorphic compounds under study can form a smectic A mesophase, twist grain boundary mesophases (TGBA), and blue phases in a wide temperature range. Upon dissolution of certain of chiral compounds in 4'-cyano-4-pentylbiphenyl, a rather high twisting power and the thermal stabilizing effect on mesophases were observed.

  (1R,4R)-2-(4-羟基苯甲基)-和(1R,4R)-2-(4'-羟基二苯基-4-基)甲基-p-薄荷烷-3-酮是通过(-)-薄荷酮与4-羟基苯甲醛和4'-羟基-4-甲酰二苯基的O-四氢吡喃-2-基衍生物在DMSO基介质中缩合，随后去除保护基团而合成的。这些酚衍生物与4-烷基苯甲酸、4-烷氧基苯甲酸、陷阱-4-烷基环己烷-4-羧酸以及4'-烷基二苯基-4-羧酸的反应生成了三类新的手性酯。含有三苯环肉桂基结构的这些衍生物被发现具有液晶性质。基于偏光显微镜、差示扫描量热法和小角X射线散射法的研究结果，讨论了这些化合物的特征。发现研究中的介晶化合物可以在较宽的温度范围内形成一个层状A介晶相、扭曲晶界介晶相(TGBA)以及蓝相。当某些手性化合物溶解于4'-氰基-4-戊基二苯基中时，观察到较高的扭曲力和对介晶相的热稳定效应。
• Liquid crystal device and a method for producing it
  申请人：——

  公开号：US20010005249A1

  公开（公告）日：2001-06-28

  An electrooptic device ( 2 ), and the methods for manufacturing, including a liquid crystal material ( 12 ) disposed between electroded flat glass or polymer substrates ( 4, 20 ) which have been precoated with a e.g. a chiral smectic surface layer ( 10, 14 ) in such way that the surface layer is able to mediate switching of the liquid crystal ( 12 ) between different optical states. The chiral smectic surface layer can be a polymer, oligomer or monomer liquid crystal with paraelectric, ferroelectric, ferrielectric or antiferroelectric response, which is insoluble in the liquid crystal used for the bulk ( 12 ) between the electroded substrates ( 4, 20 ). the switchable surface director enforces a certain orientation of the optic axis in the bulk liquid crystal ( 12 ), which can be a conventional non-chiral or chiral nematic or smectic in a twisted or non-twisted configuration.

  电光设备 ( 2 )及其制造方法，包括一种液晶材料( 12 )放置在电镀平板玻璃或聚合物基板( 4, 20 ) 之间放置液晶材料 ( 12 )，该液晶材料 ( 12 ) 已预先涂覆了手性光滑表面层 ( 10, 14 )，使表面层能够介导液晶( 12 ) 在不同光学状态之间切换。手性 Smectic 表面层可以是聚合物、低聚物或单体液晶，具有副电、铁电、铁锐电或反铁电响应，不溶于用于主体的液晶 ( 12 ) 。 12 ) 之间的电镀基底 ( 4, 20 可切换的表面导向器会强制块状液晶的光轴朝向一定的方向 ( 12 ) 。 12 可以是传统的非手性或手性向列型液晶，也可以是扭曲或非扭曲结构的共晶。
• Composite liquid crystalline mixture
  申请人：Tork Amir

  公开号：US20050104036A1

  公开（公告）日：2005-05-19

  Described is a composite liquid crystalline mixture having a low refractive index and a chemical reactive power that makes it capable of minimizing an anchoring energy when in contact with silica. This mixture comprises: (a) low ordinary refractive index nematic liquid crystal of a single type or a mixture of low ordinary refractive index nematic liquid crystals of different types; (b) at least one reagent compound capable of reducing the anchoring energy via a chemical shielding process and from which originates a decoupling effect with a glass interface leading to the reduction of the anchoring energy and appropriately orienting a liquid crystal director at this interface; and (c) at least one low refractive index additive having a relatively low viscosity. The above mixture is useful in waveguide tuning applications.

  所述的是一种复合液晶混合物，具有低折射率和化学反应能力，使其在与二氧化硅接触时能够将锚定能量降至最低。这种混合物包括：(a) 单一类型的低普通折射率向列液晶或不同类型的低普通折射率向列液晶的混合物；(b) 至少一种能够通过化学屏蔽过程降低锚定能的试剂化合物，该试剂化合物能够与玻璃界面产生解耦效应，从而降低锚定能，并使液晶导向器在该界面上适当定向；(c) 至少一种具有相对低粘度的低折射率添加剂。上述混合物可用于波导调谐应用。
• Carr, N.; Gray, G. W., Molecular Crystals and Liquid Crystals (1969-1991), 1985, vol. 124, p. 27 - 44
  作者：Carr, N.、Gray, G. W.

  DOI：——

  日期：——