anti-2-norcaranol | 23773-29-7

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: anti-2-norcaranol
• 英文别名: syn-2-norcaranol；exo/endo-7-Hydroxy-bicyclo<4,1,0>heptan；7-Hydroxy-bicyclo-<4,1,0>heptan；7-Hydroxy-bicyclo<4.1.0>heptan；exo/endo-7-Norcaranol；Bicyclo[4.1.0]heptan-7-ol
• CAS: 23773-29-7
• 化学式: C₇H₁₂O
• 分子量: 112.172
• InChiKey: QMIUADBGGPTBNU-UHFFFAOYSA-N

物化性质

• 沸点：
  94 °C(Press: 6 Torr)
• 密度：
  0.9162 g/cm3

计算性质

• 辛醇/水分配系数(LogP)：
  1.5
• 重原子数：
  8
• 可旋转键数：
  0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  20.2
• 氢给体数：
  1
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  双环[4.1.0]庚烷 在 亚碘酰苯 、 ferric porphyrin 作用下， 生成 2-norcaranone 、 anti-2-norcaranol
  参考文献：
  名称：

  铁卟啉配合物催化脂肪族羟基化

  摘要：

  羟基化和氧化脱环己烷、环庚烷和顺式萘烷。选择性和立体特异性

  DOI：

  10.1021/ja00358a009

文献信息

• DANHEISER, R. L.;SAVOCA, A. C., J. ORG. CHEM., 1985, 50, N 13, 2401-2403
  作者：DANHEISER, R. L.、SAVOCA, A. C.

  DOI：——

  日期：——
• MODIFIED MICROORGANISM AND METHODS OF USING SAME FOR PRODUCING 2-PROPANOL AND1-PROPANOL AND/OR 1,2-PROPANEDIOL
  申请人：Braskem S.A.

  公开号：US20150064759A1

  公开（公告）日：2015-03-05

  The present disclosure provides a non-naturally occurring microorganism comprising: one or more polynucleotides encoding one or more enzymes in a pathway that produces acetyl-CoA; one or more polynucleotides encoding one or more enzymes in a pathway that catalyze a conversion of cytosolic acetyl-CoA to 2-propanol; one or more polynucleotides encoding one or more enzymes in a pathway that catalyze a conversion of dihydroxyacetone-phosphate to 1-propanol and/or 1,2-propanediol, wherein the microorganism has reduced levels of pyruvate decarboxylase enzymatic activity (e.g., the microorganism comprises a disruption of one or more enzymes that decarboxylate pyruvate and/or a disruption of one or more transcription factors of one or more enzymes that decarboxylate pyruvate), and wherein the microorganism is capable of growing on a C6 sugar as a sole carbon source under anaerobic conditions. Also provided are methods of using the disclosed non-naturally occurring microorganisms in methods for the coproduction of 2-propanol and 1-propanol and/or 1,2-propanediol.
• US3714186A
  申请人：——

  公开号：US3714186A

  公开（公告）日：1973-01-30
• Aliphatic hydroxylation catalyzed by iron porphyrin complexes
  作者：John T. Groves、Thomas E. Nemo

  DOI：10.1021/ja00358a009

  日期：1983.9

  Hydroxylation et oxydation de cyclohexane, cycloheptane et cis-decaline. Selectivite et stereospecificite

  羟基化和氧化脱环己烷、环庚烷和顺式萘烷。选择性和立体特异性

表征谱图