Chlorobis(2,2-dimethylpropyl)indigane | 120666-40-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 金属烷基卤化物
• 英文名称: Chlorobis(2,2-dimethylpropyl)indigane
• 英文别名: chloro-bis(2,2-dimethylpropyl)indigane
• CAS: 120666-40-2
• 化学式: C₁₀H₂₂ClIn
• 分子量: 292.558
• InChiKey: MAFXREACCQXFMO-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.62
• 重原子数：
  12
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Chlorobis(2,2-dimethylpropyl)indigane 以 乙醚 为溶剂， 生成 InNp2Me*THF
  参考文献：
  名称：

  含有新戊基取代基In（CH2CMe3）3，In（CH2CMe3）2Cl，In（CH2CMe3）Cl2和In（CH2CMe3）2CH3的铟（III）化合物。无机聚合物二氯新戊基铟（III）的晶体和分子结构

  摘要：

  DOI：

  10.1021/om00110a014
• 作为产物：
  描述：

  以 氘代苯 、 正戊烷 、 苯 为溶剂， 生成 Chlorobis(2,2-dimethylpropyl)indigane
  参考文献：
  名称：

  Reactions of Neopentylindium(III) Derivatives with Isopropylphosphorus Compounds

  摘要：

  A 1:1 mixture of In(CH2CMe3)(3) and HP(i-Pr)(2) at room temperature undergoes a very slow hydrocarbon elimination reaction to form [(Me3CCH2)(2)InP(i-Pr)(2)](2) and neopentane. The indium phosphide [(Me3CCH2)(2)InP(i-Pr)(2)](2) has also been prepared by reacting KIn(CH2CMe3)(3)H with CIP(i-Pr)(2) in pentane. When pentane solutions of these reagents were combined at -78 degreesC and then maintained at similar to 20 degreesC for 2 days, [(Me3CCH2)(2)InP(i-Pr)(2)](2), (Me3CCH2)(3)In .P(H)(i-Pr)(2), (Me3CCH2)(3)In .P-2(i-Pr)(4), (Me3CCH2)(3)In .P(CH2CMe3)(i-Pr)(2), H-2, indium metal, and KCl were observed. The formation of all products is explained by a set of experimentally verified reactions. An X-ray structural study of [(Me3CCH2)(2)InP(i-Pr)(2)](2) shows each molecule to have an unusual puckered four-membered In2P2 core.

  DOI：

  10.1021/om0101902

文献信息

• Synthesis and molecular structures of R(Me3CCH2)2In · E(SiMe3)3 (R=Me3CCH2, E = P or As; R = Me, E = P).
  作者：Mark F. Self、Andrew T. McPhail、Leonidas J. Jones、Richard L. Wells

  DOI：10.1016/s0277-5387(00)84739-7

  日期：1994.1

  Combining P(SiMe 3 ) 3 or As(SiMe 3 ) 3 with (Me 3 CCH 2 ) 3 In in a 1:1 mole ratio yields simple adducts (Me 3 CCH 2 ) 3 In·P(SiMe 3 ) 3 ( I ) and (Me 3 CCH 2 ) 3 In·As(SiMe 3 ) 3 ( II ), respectively. Addition of (Me 3 CCH 2 ) 2 InCl to a diethyl ether solution of LiP(SiMe 3 ) 2 produces Me(Me 3 CCH 2 ) 2 In·P(SiMe 3 ) 3 ( III ). X-ray crystal structures have been determined for compounds ( I ), (

  摘要以1：1的摩尔比将P（SiMe 3）3或As（SiMe 3）3与（Me 3 CCH 2）3 In结合，可得到简单的加合物（Me 3 CCH 2）3 In·P（SiMe 3）3（ I）和（Me 3 CCH 2）3 In·As（SiMe 3）3（II）。将（Me 3 CCH 2）2 InCl加到LiP（SiMe 3）2的乙醚溶液中可制得Me（Me 3 CCH 2）2 In·P（SiMe 3）3（III）。已经确定了化合物（I），（II）和（III）的X射线晶体结构。
• Bisneopentyl alkyl organometallic compounds and methods of preparing same
  申请人：The Research Foundation of State University of New York

  公开号：US04710575A1

  公开（公告）日：1987-12-01

  In the manufacture of semiconductors it is desirable to make controlled deposits of certain phosphides or arsenides of trivalent metals such as gallium and indium. There are provided novel alkyl bisneopentyl derivatives of these metals whose stability and volatility characteristics makes them ideally suited for the above purpose.

  在半导体制造中，希望能够对三价金属磷化物或砷化物（如镓和铟）进行可控的沉积。提供了这些金属的新型烷基双新戊基衍生物，其稳定性和挥发性特征使它们非常适合上述目的。
• Synthesis and Characterization of Neopentyl Indium Compounds: X-ray Crystal Structures of [(Me3CCH2)2InAs(SiMe3)2]2 and (Me3CCH2)2InAs(SiMe3)2In(CH2CMe3)2Cl
  作者：Leonidas J. Jones、Andrew T. McPhail、Richard L. Wells

  DOI：10.1021/om00021a041

  日期：1994.9

  The 1:1 and 2:1 mole ratio reactions of(Me(3)CCH(2))(2)InCl with As(SiMe(3))(3) yield the dimeric and mixed-bridging compounds [(Me(3)CCH(2))(2)InAs(SiMe(3))(2)](2) (1) and (Me(3)CCH(2))(2)InAs(SiMe(3))(2)In(CH(2)CMe(3))(2)Cl (2), respectively. 1 and 2 were characterized by melting point, H-1 and C-13 NMR spectra, partial elemental analyses (C and H), and single-crystal X-ray analyses. Dimer 1 crystallizes in the monoclinic system, space group C2/m (C(2)h(3)), with a 19.789(2) Angstrom, b = 12.878(1) Angstrom, c 12.282(1) Angstrom, beta = 127.49(1)degrees, V = 2484(1) Angstrom(3), and Z = 2. Crystals of 2 belong to the monoclinic system, space group C2/c (C-2h(6)), With a = 20.191(2) Angstrom, b = 9.967(1) Angstrom, C = 19.758(2) Angstrom, beta = 99.67(1)degrees, V = 3920(1) Angstrom(3), and Z = 4. The facile interconversions of 1 and 2 are reported.
• Beachley Jr.; Banks, Michael A.; Churchill, Melvyn Rowen, Organometallics, 1991, vol. 10, # 9, p. 3036 - 3040
  作者：Beachley Jr.、Banks, Michael A.、Churchill, Melvyn Rowen、Feighery, William G.、Fettinger, James C.

  DOI：——

  日期：——
• Indium compounds that contain two different organic substituents. Crystal structure of [In(CH2CMe3)(CH2SiMe3)Cl]2. An interesting case of partial ligand disorder in the solid state
  作者：O. T. Beachley、John D. Maloney、Melvyn Rowen Churchill、Charles H. Lake

  DOI：10.1021/om00056a029

  日期：1991.10

  Three new indium compounds containing two different organic substituents, In(CH2CMe3)(CH2SiMe3)Cl, In(CH2CMe3)(C6H5)Cl, and (Me3CCH2)(Me3SiCH2)InPEt2, have been prepared, purified, and characterized. All compounds were characterized by partial elemental analysis (C, H, and P as appropriate), cryoscopic molecular weight studies in benzene solution, and NMR and IR spectroscopic studies. All compounds exist as dimeric molecules in solution. NMR spectral data were consistent with the presence of mixtures of cis and trans isomers in solution. [In(CH2CMe3)(CH2SiMe3)Cl]2 crystallizes in the centrosymmetric triclinic space group P1BAR (C(i)1, No. 2) with a = 6.1000 (10) angstrom, b = 10.337 (3) angstrom, c = 12.190 (3) angstrom, alpha = 77.28 (2)-degrees, beta = 84.41 (2)-degrees, gamma = 84.50 (2)-degrees, V = 744.0 (3) angstrom 3, and Z = 1. Diffraction data (Mo K-alpha, 2-theta = 5-50-degrees) were collected on a Siemens R3m/V automated four-circle diffractometer, and the structure was solved and refined to R = 5.39% and R(w) = 7.65% for those 1752 unique data with \F(o)\ > 4-sigma(\F(o)\) (R = 8.30% for all 2629 data). Distances within the centrosymmetric dimeric molecule in the trans conformation include In-CH2CMe3 = 2.140 (13) angstrom, In-CH2SiMe3 = 2.125 (12) angstrom, and In-Cl (bridging) = 2.572 (3) and 2.659 (3) angstrom. There is some slight disorder of CH2CMe3 and CH2SiMe3 ligands (approximately 73%:27%), and there are weak intermolecular In...Cl interactions at 3.528 (3) angstrom along the a-direction. Attempts to prepare the related organogallium compounds, Ga(Me)(CH2CMe3)Cl and Ga(CH2CMe3)(CH2CMe2Ph)Cl, were unsuccessful. Ligand redistribution reactions led to the formation and subsequent isolation of mixtures of the appropriate symmetrized products.