| 380456-92-8

• CAS: 380456-92-8
• 化学式: C₆H₁₅P*C₁₅H₃₃In
• 分子量: 446.406
• InChiKey: OXAVLQHUTVTQRH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  以 正戊烷 、 苯 为溶剂， 生成
  参考文献：
  名称：

  Reactions of Neopentylindium(III) Derivatives with Isopropylphosphorus Compounds

  摘要：

  A 1:1 mixture of In(CH2CMe3)(3) and HP(i-Pr)(2) at room temperature undergoes a very slow hydrocarbon elimination reaction to form [(Me3CCH2)(2)InP(i-Pr)(2)](2) and neopentane. The indium phosphide [(Me3CCH2)(2)InP(i-Pr)(2)](2) has also been prepared by reacting KIn(CH2CMe3)(3)H with CIP(i-Pr)(2) in pentane. When pentane solutions of these reagents were combined at -78 degreesC and then maintained at similar to 20 degreesC for 2 days, [(Me3CCH2)(2)InP(i-Pr)(2)](2), (Me3CCH2)(3)In .P(H)(i-Pr)(2), (Me3CCH2)(3)In .P-2(i-Pr)(4), (Me3CCH2)(3)In .P(CH2CMe3)(i-Pr)(2), H-2, indium metal, and KCl were observed. The formation of all products is explained by a set of experimentally verified reactions. An X-ray structural study of [(Me3CCH2)(2)InP(i-Pr)(2)](2) shows each molecule to have an unusual puckered four-membered In2P2 core.

  DOI：

  10.1021/om0101902
• 作为产物：
  描述：

  trineopentylindium 、 二异丙基磷化氢 以 苯 为溶剂， 生成
  参考文献：
  名称：

  Reactions of Neopentylindium(III) Derivatives with Isopropylphosphorus Compounds

  摘要：

  A 1:1 mixture of In(CH2CMe3)(3) and HP(i-Pr)(2) at room temperature undergoes a very slow hydrocarbon elimination reaction to form [(Me3CCH2)(2)InP(i-Pr)(2)](2) and neopentane. The indium phosphide [(Me3CCH2)(2)InP(i-Pr)(2)](2) has also been prepared by reacting KIn(CH2CMe3)(3)H with CIP(i-Pr)(2) in pentane. When pentane solutions of these reagents were combined at -78 degreesC and then maintained at similar to 20 degreesC for 2 days, [(Me3CCH2)(2)InP(i-Pr)(2)](2), (Me3CCH2)(3)In .P(H)(i-Pr)(2), (Me3CCH2)(3)In .P-2(i-Pr)(4), (Me3CCH2)(3)In .P(CH2CMe3)(i-Pr)(2), H-2, indium metal, and KCl were observed. The formation of all products is explained by a set of experimentally verified reactions. An X-ray structural study of [(Me3CCH2)(2)InP(i-Pr)(2)](2) shows each molecule to have an unusual puckered four-membered In2P2 core.

  DOI：

  10.1021/om0101902