Phenyl-dioctylphosphin | 14086-46-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Phenyl-dioctylphosphin
• 英文别名: dioctyl-phenyl-phosphine；Dioctyl-phenyl-phosphin；Dioctyl(phenyl)phosphane
• CAS: 14086-46-5
• 化学式: C₂₂H₃₉P
• 分子量: 334.525
• InChiKey: HXUARCOTWDKZOU-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.3
• 重原子数：
  23
• 可旋转键数：
  15
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.73
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Phenyl-dioctylphosphin 、 碘甲烷 生成 methyl-dioctyl-phenyl-phosphonium; iodide
  参考文献：
  名称：

  CCLXXXVII。—含高级烷基的叔膦

  摘要：

  DOI：

  10.1039/jr9310002109
• 作为产物：
  描述：

  正辛基镁溴盐 、 苯基二氯化磷 在 乙醚 作用下， 生成 Phenyl-dioctylphosphin
  参考文献：
  名称：

  CCLXXXVII。—含高级烷基的叔膦

  摘要：

  DOI：

  10.1039/jr9310002109

文献信息

• Propylene Hydroformylation
  申请人：Caers Frans Raphael

  公开号：US20070282133A1

  公开（公告）日：2007-12-06

  Propylene streams obtained by the conversion of oxygenates to olefins are used as feeds for hydroformylation. The streams may contain measurable amounts of dimethyl ether without adversely impacting the hydroformylation.

  通过将氧化物转化为烯烃获得的丙烯流用作羟甲基化的原料。这些流体可能含有可测量的二甲醚，而不会对羟甲基化产生不利影响。
• METHOD FOR PRODUCING CATALYST FOR CYCLIC CARBONATE SYNTHESIS
  申请人：MARUZEN PETROCHEMICAL CO., LTD.

  公开号：US20160108071A1

  公开（公告）日：2016-04-21

  The present invention provides a method for easily and inexpensively producing a heterogeneous catalyst used to synthesize a cyclic carbonate by reacting an epoxide with carbon dioxide and having excellent catalyst activity; a catalyst obtained using said manufacturing method; and a method for synthesizing a cyclic carbonate using said catalyst. A method for producing a catalyst that is used for the purpose of synthesizing a cyclic carbonate by subjecting to a reaction an epoxide with carbon dioxide, said method comprising the following steps (a) and (b): (a) a step of obtaining a catalyst precursor having a haloalkyl group or a haloaryl group by reacting a silane compound with a silica gel in the presence of xylene, the silane compound having a haloalkyl group or a haloaryl group and (b) a step of obtaining a catalyst for synthesizing a cyclic carbonate by reacting the catalyst precursor obtained in step (a) with a tertiary phosphine.

  本发明提供了一种用于通过将环氧化合物与二氧化碳反应来合成环状碳酸酯的异质催化剂的简便且廉价的生产方法；采用所述制备方法获得的催化剂；以及使用该催化剂合成环状碳酸酯的方法。用于生产一种用于合成环状碳酸酯的催化剂的方法，通过将环氧化合物与二氧化碳反应，该方法包括以下步骤(a)和(b)：(a)通过在二甲苯存在下将硅烷化合物与二氧化硅反应以获得具有卤代烷基或卤代芳基的催化剂前驱体的步骤，其中所述硅烷化合物具有卤代烷基或卤代芳基；以及(b)通过将步骤(a)中获得的催化剂前驱体与三膦反应以获得用于合成环状碳酸酯的催化剂的步骤。
• CURING ACCELERATING COMPOUND-SILICA COMPOSITE MATERIAL, METHOD FOR PRODUCING CURING ACCELERATING COMPOUND-SILICA COMPOSITE MATERIAL, CURING ACCELERATOR, CURABLE RESIN COMPOSITION, AND ELECTRONIC COMPONENT DEVICE
  申请人：Nakamura Shinya

  公开号：US20090062460A1

  公开（公告）日：2009-03-05

  The present invention relates to a curing accelerating compound-silica composite material capable of giving excellent storage stability to a curable resin composition, which is obtained by subjecting one or more compounds selected from compounds represented by the general formula (I-1) below and partial condensates thereof to a sol-gel reaction in the presence of a curing accelerating compound and water; a curable resin composition comprising the same; and an electronic component device comprising a device sealed with the curable resin composition. R 1 n SiR 2 (4-n) (I-1) wherein n is 0 or 1; R 1 is selected from a hydrogen atom and a C1 to C18 substituted or unsubstituted hydrocarbon group and may form a ring structure with R 2 ; R 2 s represent a functional group reactive with a phenolic hydroxyl group, are selected independently from a halogen atom, a hydroxyl group, a C1 to C18 optionally substituted oxy group, a C0 to C18 optionally substituted amino group, and a C2 to C18 optionally substituted carbonyloxy group, all R 2 s may be the same or different from one another, and two or more R 2 s may be bound to each other to form a ring structure.

  本发明涉及一种固化促进剂-二氧化硅复合材料，能够为可固化树脂组分提供优异的储存稳定性。所述复合材料通过在固化促进剂和水的存在下，将下式（I-1）所表示的化合物之一或多个部分缩聚物进行溶胶-凝胶反应而获得；所述化合物如下：R1nSiR2(4-n)(I-1)，其中n为0或1；R1为氢原子和C1到C18取代或未取代的烃基，也可以与R2形成环状结构；R2表示与酚羟基反应的官能团，可独立选择自卤素原子、羟基、C1到C18可选取代的氧基团、C0到C18可选取代的氨基团和C2到C18可选取代的羰基氧基团，所有R2可以相同也可以不同，两个或更多的R2可以结合在一起形成环状结构。本发明还涉及一种包含该复合材料的可固化树脂组分，以及一种包括用该可固化树脂组分封装的电子元器件装置。
• ORGANOMETALLIC COMPOUND, CATALYST FOR POLYMERIZATION OF POLAR GROUP-CONTAINING NORBORNENE AND PROCESS FOR PRODUCING NORBORNENE POLYMER
  申请人：Watanabe Saisuke

  公开号：US20090247729A1

  公开（公告）日：2009-10-01

  An organometallic compound obtained by mixing following (a), (b) and (c): (a) a neutral organopalladium complex that has a palladium atom and two organic ligands each having at least three carbon atoms participating in a bond to the palladium atom; (b) an organophosphorus compound having one phosphorus atom; and (c) a salt comprising: an anion having no unshared electron pair in a central atom; and a counter-cation. And a process for producing a norbornene compound polymer, the process comprising: subjecting at least one norbornene compound represented by formula (A) as defined in the specification to polymerization reaction in a presence of an organometallic complex catalyst produced by mixing compound (a) and compound (d) described in the specification.

  一种有机金属化合物，通过混合以下物质（a）、（b）和（c）获得：（a）一种中性有机钯配合物，其具有钯原子和两个有机配体，每个配体至少有三个碳原子参与与钯原子的键合；（b）一种含有一个磷原子的有机磷化合物；和（c）一种盐，包括：一个中心原子中没有未共享电子对的阴离子；和一个对离子。以及一种生产诺博尔烯化合物聚合物的方法，该方法包括：在混合化合物（a）和规范中描述的化合物（d）的有机金属配合物催化剂的存在下，将至少一种由式（A）表示的诺博尔烯化合物进行聚合反应。
• PROCESS FOR PRODUCING CARBONYL COMPOUNDS BY DEHYDROGENATION OF ALCOHOLS
  申请人：MITSUBISHI CHEMICAL CORPORATION

  公开号：EP1160245A1

  公开（公告）日：2001-12-05

  The present invention provides a method for producing a carbonyl compound by dehydrogenating an alcohol. Namely, it relates to a method for producing a carbonyl compound, which comprises dehydrogenating an alcohol in the presence of a complex compound catalyst comprising ruthenium and an organic phosphine wherein aliphatic carbons are bonded to two or more of the three bonding hands of the phosphorus atom.

  本发明提供了一种通过脱氢醇生产羰基化合物的方法。也就是说，本发明涉及一种生产羰基化合物的方法，该方法包括在由钌和有机膦组成的复合催化剂存在下对醇进行脱氢，其中脂肪族碳与磷原子三个键手中的两个或两个以上键手成键。