(2-methylcyclopentyl)cyclohexane | 5405-90-3

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: (2-methylcyclopentyl)cyclohexane
• 英文别名: MCPCH；(2-methyl-cyclopentyl)-cyclohexane；(2-Methyl-cyclopentyl)-cyclohexan
• CAS: 5405-90-3
• 化学式: C₁₂H₂₂
• 分子量: 166.307
• InChiKey: XCXDPWLAQJIWCQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  12
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  环已基环已烷 在 盐酸 、 三氯化铝 作用下， 生成 (2-methylcyclopentyl)cyclohexane
  参考文献：
  名称：

  The Isomerization of Dicyclohexy¹

  摘要：

  DOI：

  10.1021/ja01216a519

文献信息

• Two- and Three-Dimensional Photonic Crystals Built with VLSI Tools
  作者：Shawn-Yu Lin、J.G. Fleming、E. Chow

  DOI：10.1557/mrs2001.157

  日期：2001.8

  The drive toward miniature photonic devices has been hindered by our inability to tightly control and manipulate light. Moreover, photonics technologies are typically not based on silicon and, until recently, only indirectly benefited from the rapid advances being made in silicon processing technology. In the first part of this article, the successful fabrication of three-dimensional (3D) photonic crystals using silicon processing will be discussed. This advance has been made possible through the use of integrated-circuit (IC) fabrication technologies (e.g., very largescale integration, VLSI) and may enable the penetration of Si processing into photonics. In the second part, we describe the creation of 2D photonic-crystal slabs operating at the λ = 1.55 μm communications wavelength. This class of 2D photonic crystals is particularly promising for planar on-chip guiding, trapping, and switching of light.

  朝向微型光子器件的发展受到了我们无法紧密控制和操作光线的限制。此外，光子技术通常不基于硅，直到最近才间接受益于硅处理技术的迅速进步。本文的第一部分将讨论使用硅处理成功制造三维（3D）光子晶体的进展。这一进展得益于集成电路（IC）制造技术（例如，大规模集成，VLSI）的应用，可能使硅处理渗透到光子学中。在第二部分中，我们描述了在λ = 1.55 μm通信波长下运行的2D光子晶体板的创建。这类2D光子晶体对于平面芯片引导、困禁和光开关非常有前景。
• Carbazole hydrodenitrogenation over nickel phosphide and Ni-rich bimetallic phosphide catalysts
  作者：Richard H. Bowker、Boris Ilic、Bo A. Carrillo、Michael A. Reynolds、Brendan D. Murray、Mark E. Bussell

  DOI：10.1016/j.apcata.2014.05.026

  日期：2014.7

  inhibited carbazole HDN over the metal phosphides, but the Ni2P/SiO2 and Ni-rich bimetallic phosphide catalysts maintained higher activities than the sulfided Ni–Mo/Al2O3 catalyst. The product selectivities of the metal phosphide and sulfide catalysts were similar, except that the sulfided Ni–Mo/Al2O3 catalyst yielded more hydrogenated carbazoles while the metal phosphide catalysts produced more of the

  研究了二氧化硅负载的磷化镍（Ni 2 P）和富镍的双金属磷化物催化剂在有或没有苯并噻吩共同进料的情况下对咔唑的加氢脱氮（HDN）。Ni 2 P / SiO 2，Co 0.1 Ni 1.9 P / SiO 2和Fe 0.03 Ni 1.97 P / SiO 2催化剂表现出高咔唑HDN活性，在该条件下的性能优于市售硫化Ni-Mo / Al 2 O 3催化剂。使用的测试条件。共进料苯并噻吩比金属磷化物抑制咔唑HDN，但Ni 2 P / SiO 2富镍双金属磷化物催化剂比硫化Ni-Mo / Al 2 O 3催化剂具有更高的活性。金属硫化物和硫化物催化剂的产物选择性相似，除了硫化的Ni-Mo / Al 2 O 3催化剂产生更多的氢化咔唑，而金属磷化物催化剂则产生更多的部分氢化的烃环己基苯。金属磷化物催化剂有利于开环（己基环己烷）和缩合（（2-甲基环戊基）环己烷）产物，表明催化剂表面存在金属和布朗斯台德酸位。Ni
• Diastereoselective Hydrogenation of Tetrasubstituted Olefins using a Heterogeneous Pt‐Ni Alloy Catalyst
  作者：William A. Swann、Anish Yadav、Nicholas B. Colvin、Nicole K. Freundl、Christina W. Li

  DOI：10.1002/anie.202317710

  日期：2024.5.6

  A Pt−Ni alloy nanocatalyst is developed for the diastereoselective directed hydrogenation of tetrasubstituted olefins in a cyclopentene scaffold. For this substrate class, established homogeneous catalysts generate hydrogenolysis side products, and commercial heterogeneous catalysts are not stereoselective. Uniform alloying of the noble metal and base metal combined with high catalyst dispersion is

  开发了一种 Pt-Ni 合金纳米催化剂，用于环戊烯支架中四取代烯烃的非对映选择性定向氢化。对于此类底物，已建立的均相催化剂会产生氢解副产物，而商业多相催化剂不具有立体选择性。贵金属和贱金属的均匀合金化与高催化剂分散相结合对于一系列空间位阻烯烃的良好反应性和非对映选择性至关重要。
• Miethchen, Ralf; Steege, Sigrid; Kroeger, Carl-Friedrich, Journal fur praktische Chemie (Leipzig 1954), 1983, vol. 325, # 5, p. 823 - 834
  作者：Miethchen, Ralf、Steege, Sigrid、Kroeger, Carl-Friedrich

  DOI：——

  日期：——
• Zelinsky; Schuikin; Fatejew, Zhurnal Obshchei Khimii, 1932, vol. 2, p. 671,680
  作者：Zelinsky、Schuikin、Fatejew

  DOI：——

  日期：——