6-methyl-3-phenyltetrahydro-2H-pyran-2-one | 90124-77-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 内酯类
• 英文名称: 6-methyl-3-phenyltetrahydro-2H-pyran-2-one
• 英文别名: 6-Methyl-3-phenyloxan-2-one
• CAS: 90124-77-9
• 化学式: C₁₂H₁₄O₂
• 分子量: 190.242
• InChiKey: UKSXWQXPGXBPMV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.7
• 重原子数：
  14
• 可旋转键数：
  1
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.42
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  6-methyl-3-phenyltetrahydro-2H-pyran-2-one 、 碘甲烷 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 生成 3,6-dimethyl-3-phenyltetrahydro-2H-pyran-2-one
  参考文献：
  名称：

  Intermediates for the preparation of octahydroquinolizines

  摘要：

  本发明涉及用作八氢喹啉合成中间体的化合物，其符合以下公式：X = H，F；R = 甲基，乙基，正丙基，正丁基。

  公开号：

  EP2266967A1
• 作为产物：
  描述：

  2-phenylhex-5-enoic acid 在 sodium tetrahydroborate 、 三乙基硼 、 mercury(II) trifluoroacetate 、 mercury(II) oxide 作用下， 生成 6-methyl-3-phenyltetrahydro-2H-pyran-2-one 、 2-Phenyl-hexane-1,5-diol
  参考文献：
  名称：

  An Improved Reductive Demercuration of Organomercurials Using Triethylborane

  摘要：

  Organomercurials, which were generated by intra-and inter-molecular mercury(II)-promoted electrophilic additions, have been reductively demercurated in situ efficiently using sodium borohydride in the presence of triethylborane at low temperature. Under these conditions, the frequently accompanying side reactions such as reductive elimination and oxidative demercuration have not been detected. (C) 1997 Elsevier Science Ltd. All rights reserved.

  DOI：

  10.1016/s0040-4039(97)10488-9

文献信息

• [EN] INTERMEDIATES FOR THE PREPARATION OF OCTAHYDROQUINOLIZINES<br/>[FR] INTERMÉDIAIRES UTILISÉS DANS LA PRÉPARATION D'OCTAHYDROQUINOLIZINES
  申请人：55PHARMA DRUG DISCOVERY & DEV AG

  公开号：WO2010144937A2

  公开（公告）日：2010-12-23

  This invention relates to compounds used as intermediates for the synthesis of octahydroquinolizines in accordance with the formula (A): X = H, F; R= Methyl, Ethyl, nPropyl, nButyl.
• [EN] BINDER FOR ELECTRODE COMPOSITION AND SECONDARY BATTERY COMPRISING SAME<br/>[FR] LIANT POUR COMPOSITION D'ÉLECTRODE ET BATTERIE SECONDAIRE COMPRENANT CELUI-CI
  申请人：G L CHEM CO LTD

  公开号：WO2014038836A2

  公开（公告）日：2014-03-13

  본 발명은 전극 합제용 바인더 및 이를 포함하는 이차전지에 관한 것으로, 보다 상세하게는 전극 합제용 CMC 및 이의 제조방법으로, 상기 본 발명에 따른 CMC를 전극 합제의 바인더로 사용함으로써, 특히 충·방전 시 음극 활물질들의 큰 부피 변화에도 불구하고 활물질 상호간 및 집전체와의 결합력이 안정적으로 유지될 수 있으며 활물질의 부피팽창에 따른 균열을 최소화 시키므로 고용량의 실리콘 또는 주석계 음극 활물질의 상용화를 가능케 하여 대용량 리튬 이차전지의 제조에 크게 기여할 수 있다.
• An Improved Reductive Demercuration of Organomercurials Using Triethylborane
  作者：Sung Ho Kang、Jung Hwa Lee、Sung Bae Lee

  DOI：10.1016/s0040-4039(97)10488-9

  日期：1998.1

  Organomercurials, which were generated by intra-and inter-molecular mercury(II)-promoted electrophilic additions, have been reductively demercurated in situ efficiently using sodium borohydride in the presence of triethylborane at low temperature. Under these conditions, the frequently accompanying side reactions such as reductive elimination and oxidative demercuration have not been detected. (C) 1997 Elsevier Science Ltd. All rights reserved.
• Intermediates for the preparation of octahydroquinolizines
  申请人：55pharma Drug Discovery & Development AG

  公开号：EP2266967A1

  公开（公告）日：2010-12-29

  This invention relates to compounds used as intermediates for the synthesis of octahydroquinolizines in accordance with the following formula: X = H, F; R= Methyl, Ethyl, nPropyl, nButyl

  本发明涉及用作八氢喹啉合成中间体的化合物，其符合以下公式：X = H，F；R = 甲基，乙基，正丙基，正丁基。