1,5-cyclodecadiyne | 118620-70-5

• 分子结构分类: 有机化合物 - 碳氢化合物 - 不饱和烃
• 英文名称: 1,5-cyclodecadiyne
• 英文别名: Cyclodeca-1,5-diyne
• CAS: 118620-70-5
• 化学式: C₁₀H₁₂
• 分子量: 132.205
• InChiKey: HBRNOPDOZDLBNF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.1
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  4,6-癸二炔-1,10-二醇 在 联苯 、 三溴化磷 、 lithium 作用下， 以 四氢呋喃 为溶剂， 生成 1,5-cyclodecadiyne
  参考文献：
  名称：

  A convenient synthesis of ethano-bridged cyclic diynes — Preparation of 1,1,2,2-tetramethyl-1,2-disilacycloocta-3,7-diyne

  摘要：

  Cyclic diynes bridged by an ethano moiety on one side are formed in the reaction of alpha,omega-dihalogen precursors with lithium in presence of biphenyl. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(97)10329-x

文献信息

• Syntheses and properties of medium sized carbocyclic diacetylenes
  作者：Rolf Gleiter、Detlef Kratz、Volker Schehlmann

  DOI：10.1016/0040-4039(88)85217-1

  日期：1988.1

  The syntheses and properties of cyclonona-1,5-diyne (1), cyclodeca-1,5-diyne (3), cycloundeca-1,5-diyne (4) and cycloundeca-1,6-diyne(5) are reported.

  报道了Cyclonona-1,5-diyne（1），cyclodeca-1,5-diyne（3），cycloundeca-1,5-diyne（4）和cycloundeca-1,6-diyne（5）的合成和性质。
• Bunnage, Mark E.; Nicolaou, K. C., Angewandte Chemie, 1996, vol. 108, # 10, p. 1178 - 1180
  作者：Bunnage, Mark E.、Nicolaou, K. C.

  DOI：——

  日期：——
• Synthesis and properties of medium-sized (C9-C12) carbocyclic diacetylenes
  作者：R. Gleiter、D. Kratz、W. Schaefer、V. Schehlmann

  DOI：10.1021/ja00024a035

  日期：1991.11

  The syntheses of 1,5-cyclononadiyne (3), 1,5-cyclodecadiyne (4), 1,5-cycloundecadiyne (5), 1,6-cycloundecadiyne (6), 1,6-cyclododecadiyne (7), and 1,7-cyclododecadiyne (8) have been carried out. Diacetylenes 3 and 4 are prepared from 5-cyclononynone and 5-cyclodecynone, respectively. Compounds 5-8 are synthesized from cyclic diones by thermolysis of the corresponding bisselenadiazoles. The obtained cyclic diacetylenes are further characterized by their bis(hexacarbonyldicobalt) complexes. The geometrical parameters of 3-8 were calculated with force field and semiempirical methods. From the structural data, a correlation between the C-13 resonance of the sp-hybridized carbon atoms adjacent to the ethano bridge in 3-5 and the corresponding resonance of the symmetric dialkynes 1,5-cyclooctadiyne (1), 1,6-cyclodecadiyne (2), and 1,7-cyclododecadiyne (8) with the bending angle at this center can be verified. The PE spectra of 3-8 have been recorded, and an interpretation of the bands in the low-energy region is presented. It is found that the splitting of the PE bands that are assigned to the in-plane pi-MO's (pi-i) strongly depends on the size of the methylene bridge. In the case of a propano bridge (e.g., in 3, 6, and 7), the splitting between pi-i- and pi=i+ is relatively large. The splitting of the bands that are assigned to the out-of-plane pi-MO's (pi-o) decreases with increasing transannular distance.
• GLEITER, ROLF;KRATZ, DETLEF;SCHEHLMANN, VOLKER, TETRAHEDRON LETT., 29,(1988) N 23, C. 2813-2816
  作者：GLEITER, ROLF、KRATZ, DETLEF、SCHEHLMANN, VOLKER

  DOI：——

  日期：——
• A convenient synthesis of ethano-bridged cyclic diynes — Preparation of 1,1,2,2-tetramethyl-1,2-disilacycloocta-3,7-diyne
  作者：Gebhard Haberhauer、Rolf Roers、Rolf Gleiter

  DOI：10.1016/s0040-4039(97)10329-x

  日期：1997.12

  Cyclic diynes bridged by an ethano moiety on one side are formed in the reaction of alpha,omega-dihalogen precursors with lithium in presence of biphenyl. (C) 1997 Elsevier Science Ltd.