2-(cyclohexylsulfinyl)-1,4-benzoquinone | 135615-65-5

• 分子结构分类: 有机化合物 - 有机氧化合物
• 英文名称: 2-(cyclohexylsulfinyl)-1,4-benzoquinone
• 英文别名: 2-Cyclohexylsulfinylcyclohexa-2,5-diene-1,4-dione
• CAS: 135615-65-5
• 化学式: C₁₂H₁₄O₃S
• 分子量: 238.307
• InChiKey: XHZAPTXFKHVVDV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.1
• 重原子数：
  16
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  70.4
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  对苯醌 在 间氯过氧苯甲酸 作用下， 以 甲醇 、 二氯甲烷 为溶剂， 反应 0.28h， 生成 2-(cyclohexylsulfinyl)-1,4-benzoquinone
  参考文献：
  名称：

  Use of sulfoxides as cocatalysts in the palladium-quinone-catalyzed 1,4-diacetoxylation of 1,3-dienes. An example of ligand-accelerated catalysis

  摘要：

  The use of sulfinyl quinones as cocatalysts in the palladium-catalyzed 1,4-diacetoxylation of 1,3-dienes improves the stereochemical outcome of the reaction by increasing the rate of the internal migration of the acetate nucleophile. A mechanism of the interaction between the sulfoxide and the intermediate (pi-allyl)palladium complex, based on H-1 NMR results, is proposed.

  DOI：

  10.1021/jo00020a022

文献信息

• ORGANIC COMPOUND, METHOD FOR MANUFACTURING SAME, ORGANIC SEMICONDUCTOR MATERIAL CONTAINING SAME, AND ORGANIC TRANSISTOR CONTAINING SAME
  申请人：DIC Corporation

  公开号：EP3342769A1

  公开（公告）日：2018-07-04

  Provided are a compound which is excellent in solubility in a solvent and easily provides a film exhibiting high mobility without complicated processes, an organic semiconductor material using the same, and an organic semiconductor ink which enables easy fabrication of an organic transistor composed of a practical configuration. The problems are solved by a method of producing a dinaphthothiophene derivative, the method including the following steps (I) and (II): (I) a first step of subjecting a naphthol derivative represented by General Formula (A) and a naphthalene thiol derivative represented by General Formula (B) to dehydration condensation in the presence of acid to produce a sulfide derivative represented by General formula (C); and (II) a second step of performing dehydrogenation reaction of the sulfide derivative (C) in the presence of a transition metal salt or a transition metal complex to produce a dinaphthothiophene derivative (D).

  本发明提供了一种在溶剂中溶解性极佳且无需复杂工序即可轻松提供具有高迁移率薄膜的化合物、一种使用该化合物的有机半导体材料，以及一种可轻松制造由实用构型组成的有机晶体管的有机半导体墨水。这些问题通过一种生产二萘并噻吩衍生物的方法来解决，该方法包括以下步骤（I）和（II）：(I)第一步，将通式(A)代表的萘酚衍生物和通式(B)代表的萘硫醇衍生物在酸存在下进行脱水缩合，生成通式(C)代表的硫化物衍生物；(II)第二步，将硫化物衍生物(C)在过渡金属盐或过渡金属络合物存在下进行脱氢反应，生成二萘并噻吩衍生物(D)。
• METHOD FOR PRODUCING CYCLIC UNSATURATED COMPOUND
  申请人：Nippon Shokubai Co., Ltd.

  公开号：EP2061778A1

  公开（公告）日：2009-05-27
• ORGANIC COMPOUND, METHOD FOR PREPARING SAME, ORGANIC SEMICONDUCTOR MATERIAL CONTAINING SAME, AND ORGANIC TRANSISTOR CONTAINING SAME
  申请人：DIC Corporation

  公开号：US20180248131A1

  公开（公告）日：2018-08-30

  Provided are a compound which is excellent in solubility in a solvent and easily provides a film exhibiting high mobility without complicated processes, an organic semiconductor material using the same, and an organic semiconductor ink which enables easy fabrication of an organic transistor composed of a practical configuration. The problems are solved by a method of producing a dinaphthothiophene derivative, the method including the following steps (I) and (II): (I) a first step of subjecting a naphthol derivative represented by General Formula (A) and a naphthalene thiol derivative represented by General Formula (B) to dehydration condensation in the presence of acid to produce a sulfide derivative represented by General formula (C); and (II) a second step of performing dehydrogenation reaction of the sulfide derivative (C) in the presence of a transition metal salt or a transition metal complex to produce a dinaphthothiophene derivative (D).
• US8093409B2
  申请人：——

  公开号：US8093409B2

  公开（公告）日：2012-01-10
• [EN] METHOD FOR PRODUCING CYCLIC UNSATURATED COMPOUND<br/>[FR] PROCÉDÉ DE PRODUCTION D'UN COMPOSÉ INSATURÉ CYCLIQUE
  申请人：NIPPON CATALYTIC CHEM IND

  公开号：WO2008023823A1

  公开（公告）日：2008-02-28

  [EN] The present invention provides a method for producing a cyclic unsaturated compound, which sufficiently suppresses generation of acyclic unsaturated compounds and permits excellent yield and reaction rate. Such a method for producing a cyclic unsaturated compound is a method for producing a cyclic unsaturated compound by reacting an a, ß-unsaturated carboxylic acid with an unsaturated organic compound, wherein the method comprises a step of reacting the a, ß-unsaturated carboxylic acid with the unsaturated organic compound in the presence of a catalyst.
  [FR] La présente invention concerne un procédé de production d'un composé insaturé cyclique, permettant de supprimer efficacement la génération de composés insaturés acycliques et d'obtenir un rendement et une vitesse de réaction élevés. Ce procédé vise à produire un composé insaturé cyclique par réaction d'un acide carboxylique a,ß-insaturé avec un composé organique insaturé, ledit procédé consistant à faire réagir l'acide carboxylique a,ß-insaturé avec le composé organique insaturé en présence d'un catalyseur.