3,6-dimethyl-acridine | 103323-20-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: 3,6-dimethyl-acridine
• 英文别名: 3,6-Dimethyl-acridin；Acridinorange；3,6-Dimethylacridine
• CAS: 103323-20-2
• 化学式: C₁₅H₁₃N
• 分子量: 207.275
• InChiKey: ONDFMMOAYRYYJQ-UHFFFAOYSA-N

物化性质

• 熔点：
  122 °C
• 沸点：
  377.2±11.0 °C(Predicted)
• 密度：
  1.129±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.3
• 重原子数：
  16
• 可旋转键数：
  0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.13
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  2-(2-甲氧基-3-甲基-苯胺基)-4-甲基-苯甲酸 在 PPA 、 氢溴酸 、 溶剂黄146 作用下， 生成 3,6-dimethyl-acridine
  参考文献：
  名称：

  Brockmann; Muxfeldt, Chemische Berichte, 1956, vol. 89, p. 1397,1401

  摘要：

  DOI：

文献信息

• Optically-Detectable Enzyme Substrates and Their Method of Use
  申请人：Life Technologies Corporation

  公开号：US20160139135A1

  公开（公告）日：2016-05-19

  The present invention relates to compounds that are substrates for an enzyme, and upon reaction with the enzyme provide a detectable response, such as an optically detectable response. In particular, the compounds have utility in detecting the presence of a β-lactamase in a sample. In addition to the compounds, methods are disclosed for analyzing a sample for the presence of a β-lactmase, for example, as an indicator of expression of a nucleic acid sequence including a sequence coding for a β-lactmase. Kits are disclosed that include the disclosed compounds and additional components, for example, cells, antibodies, a β-lactmase or instructions for using the components in an assay.

  本发明涉及一种酶底物化合物，与酶反应后产生可检测的响应，例如光学可检测的响应。具体而言，这些化合物在检测样品中β-内酰胺酶的存在方面具有实用性。除了这些化合物外，还公开了用于分析样品中β-内酰胺酶存在的方法，例如，作为表达包括编码β-内酰胺酶序列的核酸序列的指示器。还公开了包括这些化合物和额外组分的试剂盒，例如细胞、抗体、β-内酰胺酶或使用这些组分进行检测的说明书。
• OPTICALLY-DETECTABLE ENZYME SUBSTRATES AND THEIR METHOD OF USE
  申请人：CORRY Schuyler Boon

  公开号：US20090047692A1

  公开（公告）日：2009-02-19

  The present invention relates to compounds that are substrates for an enzyme, and upon reaction with the enzyme provide a detectable response, such as an optically detectable response. In particular, the compounds have utility in detecting the presence of a β-lactamase in a sample. In addition to the compounds, methods are disclosed for analyzing a sample for the presence of a β-lactmase, for example, as an indicator of expression of a nucleic acid sequence including a sequence coding for a β-lactmase. Kits are disclosed that include the disclosed compounds and additional components, for example, cells, antibodies, a β-lactmase or instructions for using the components in an assay.

  本发明涉及一种酶底物化合物，经过与该酶的反应后提供可检测的响应，例如光学可检测响应。特别是，这些化合物在检测样品中β-内酰胺酶的存在方面具有实用性。除了这些化合物，还揭示了一种分析样品中β-内酰胺酶存在的方法，例如，作为包括编码β-内酰胺酶的核酸序列的表达的指示器。还揭示了包括上述化合物和其他组分的试剂盒，例如细胞、抗体、β-内酰胺酶或使用这些组分进行检测的说明。
• PHOTOELECTRIC CONVERSION DEVICE AND SOLAR CELL USING THE SAME
  申请人：AKIYAMA Seiji

  公开号：US20120211082A1

  公开（公告）日：2012-08-23

  There is provides a photoelectric conversion device material which can be used as an electrode buffer material for a solar cell or the like and can improve durability while maintaining the interaction with an electrode and mobility; a photoelectric conversion device using the photoelectric conversion device material; and a solar cell using the photoelectric conversion device. A photoelectric conversion device containing a buffer layer and an active layer, wherein the buffer layer contains a compound represented by the following general formula (I), the active layer contains an n-type semiconductor, and the n-type semiconductor is a compound having a solubility in toluene of 0.5% by weight or more at 25° C. and having an electron mobility of 1.0×10 −6 cm 2 /Vs or more.

  提供了一种光电转换器件材料，可用作太阳能电池或类似器件的电极缓冲材料，可以提高耐久性，同时保持与电极的相互作用和移动性；使用该光电转换器件材料的光电转换器件；以及使用该光电转换器件的太阳能电池。光电转换器件包含缓冲层和活性层，其中缓冲层包含由下列通式（I）表示的化合物，活性层包含n型半导体，且该n型半导体在25℃时在甲苯中的溶解度为0.5%或更高，并具有1.0×10−6cm2/Vs或更高的电子迁移率。
• INK COMPOSITION AND PHOTOELECTRIC CONVERSION ELEMENT PRODUCED USING SAME
  申请人：Sumitomo Chemical Company, Ltd.

  公开号：EP3219765A1

  公开（公告）日：2017-09-20

  An ink composition containing a P-type semiconductor material, an N-type semiconductor material and two or more solvents including a first solvent and a second solvent, wherein the total amount of the first solvent and the second solvent is 70% by weight or more with respect to 100% by weight of all the solvents contained in the ink composition; the boiling point of the first solvent is lower than the boiling point of the second solvent; the boiling point of the first solvent is 120°C or more and 400°C or less; and the hydrogen bond Hansen solubility parameter H1 (MPa0.5) of the first solvent and the hydrogen bond Hansen solubility parameter H2 (MPa0.5) of the second solvent are in the relation of 0.5 ≤ (H2-H1) ≤ 5.0.

  一种含有 P 型半导体材料、N 型半导体材料和两种或两种以上溶剂（包括第一溶剂和第二溶剂）的油墨组合物，其中 第一种溶剂和第二种溶剂的总量占油墨组合物所含全部溶剂重量的 70% 或以上（按重量计）； 第一种溶剂的沸点低于第二种溶剂的沸点； 第一种溶剂的沸点为 120°C 或以上，400°C 或以下；以及 第一种溶剂的氢键汉森溶解度参数 H1 (MPa0.5) 和第二种溶剂的氢键汉森溶解度参数 H2 (MPa0.5) 的关系为 0.5 ≤ (H2-H1) ≤ 5.0。
• INK COMPOSITION AND PHOTOELECTRIC CONVERSION ELEMENT PRODUCED USING SAME
  申请人：Sumitomo Chemical Company, Ltd.

  公开号：EP3496174A1

  公开（公告）日：2019-06-12

  An ink composition comprising a P-type semiconductor material, an N-type semiconductor material and two or more solvents including a first solvent and a second solvent, wherein the total amount of the first solvent and the second solvent is 70% by weight or more with respect to 100% by weight of all the solvents contained in the ink composition; the boiling point of the first solvent is lower than the boiling point of the second solvent; the boiling point of the first solvent is 120°C or more and 400°C or less; and the hydrogen bond Hansen solubility parameter H1 (MPa0.5) of the first solvent and the hydrogen bond Hansen solubility parameter H2 (MPa0.5) of the second solvent are in the relation of 0.5 ≤ (H2-H1) ≤ 5.0; the first solvent is an aromatic hydrocarbon solvent; the P-type semiconductor material is a polymer compound comprising a repeating unit represented by the following (1-1) and/or the following formula (II-1) to (II-4) or (II-6): wherein, Z represents a divalent group represented by (Z-1) to (Z-7), wherein, X1 and X2 each independently represent an oxygen atom or a sulfur atom, R represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, a mono-valent heterocyclic group, a substituted amino group, an acyl group, an imine residue, a substituted amide group, an acid imide group, a substituted carboxyl group, an alkenyl group, an alkynyl group, a cyano group or a nitro group.

  一种油墨组合物，包括一种 P 型半导体材料、一种 N 型半导体材料和两种或两种以上的溶剂，包括第一种溶剂和第二种溶剂，其中 第一种溶剂和第二种溶剂的总量占油墨组合物所含全部溶剂重量的 70% 或以上（按重量计）； 第一种溶剂的沸点低于第二种溶剂的沸点； 第一种溶剂的沸点为 120°C 或以上，400°C 或以下；以及 第一种溶剂的氢键汉森溶解度参数 H1 (MPa0.5) 和第二种溶剂的氢键汉森溶解度参数 H2 (MPa0.5) 的关系为 0.5 ≤ (H2-H1) ≤ 5.0； 第一种溶剂是芳香烃溶剂； 所述 P 型半导体材料为聚合物化合物，其包含由下式（1-1）和/或下式（II-1）至 （II-4）或（II-6）表示的重复单元： 其中，Z 代表由 (Z-1) 至 (Z-7) 所代表的二价基团、 其中 X1和X2各自独立地代表氧原子或硫原子，R代表氢原子、卤素原子、烷基、芳基、烷氧基、芳氧基、烷硫基、芳硫基、单价杂环基、取代的氨基、酰基、亚胺残基、取代的酰胺基、酸亚胺基、取代的羧基、烯基、炔基、氰基或硝基。