3,6-di(2-naphthyl)-9-ethylcarbazole | 1026991-04-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吲哚及其衍生物
• 英文名称: 3,6-di(2-naphthyl)-9-ethylcarbazole
• 英文别名: 9-Ethyl-3,6-dinaphthalen-2-ylcarbazole
• CAS: 1026991-04-7
• 化学式: C₃₄H₂₅N
• 分子量: 447.579
• InChiKey: YKQIOLPIMXFJEW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.4
• 重原子数：
  35
• 可旋转键数：
  3
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  4.9
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  2-溴萘 、 3,6-二溴-9-乙基咔唑 在 (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride 叔丁基锂 、 indium(III) chloride 作用下， 以 正戊烷 、 四氢呋喃 、 乙醚 为溶剂， 反应 5.0h， 以83%的产率得到3,6-di(2-naphthyl)-9-ethylcarbazole
  参考文献：
  名称：

  Synthesis and Characterization of Polyaromatic Compounds Using Tri(naphthyl)indium

  摘要：

  A variety of polyaromatic compounds beating 1- and 2-naphthyl groups were prepared from the reactions of corresponding halides with tri(1- and 2-naphthyl)indium in good to excellent yields. Thermal, photophysical and electrochemical behaviors of carbazoles having naphthyl groups were studied. They have shown to be promising host and hole transporting materials in organic electroluminescence due to their high thermal stability, electrochemical reversibility and wide band gap.

  DOI：

  10.1021/jo800438n

文献信息

• Synthesis and Characterization of Polyaromatic Compounds Using Tri(naphthyl)indium
  作者：Wonhyung Lee、Youngjin Kang、Phil Ho Lee

  DOI：10.1021/jo800438n

  日期：2008.6.1

  A variety of polyaromatic compounds beating 1- and 2-naphthyl groups were prepared from the reactions of corresponding halides with tri(1- and 2-naphthyl)indium in good to excellent yields. Thermal, photophysical and electrochemical behaviors of carbazoles having naphthyl groups were studied. They have shown to be promising host and hole transporting materials in organic electroluminescence due to their high thermal stability, electrochemical reversibility and wide band gap.