2-乙基丁基自由基 | 25823-00-1

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 中文名称: 2-乙基丁基自由基
• 英文名称: 2-ethyl butyl radical
• 英文别名: 2-Aethyl-butyl-(1)-Radikal；2-ethyl-butyl
• CAS: 25823-00-1
• 化学式: C₆H₁₃
• 分子量: 85.1692
• InChiKey: MGBLKUKNMFDBPW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  6
• 可旋转键数：
  2
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.83
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  3-(氯甲基)戊烷 在 sodium 作用下， 300.0~450.0 ℃ 、399.99 Pa 条件下， 生成 丁烯 、 乙烷 、 2-乙基丁基自由基
  参考文献：
  名称：

  On the Removal of Metallic Mirrors by Free Radicals

  摘要：

  AbstractLarge Radicals can be formed by passing chlorinated organic compounds at pressures of a few ram., through a furnace containing a pellet of sodium and heated to 350–400°C. It seems to us that the only radicals that will remove metallic mirrors (of tellurium or antimony, etc., previously deposited beyond the furnace) are those that can decompose into methyl or ethyl radicals plus an unsaturated molecule, without undergoing any transmigration of atoms.

  DOI：

  10.1002/bbpc.19870911003

文献信息

• On the Removal of Metallic Mirrors by Free Radicals
  作者：Francis Owen Rice、Joan Tweedell

  DOI：10.1002/bbpc.19870911003

  日期：1987.10

  AbstractLarge Radicals can be formed by passing chlorinated organic compounds at pressures of a few ram., through a furnace containing a pellet of sodium and heated to 350–400°C. It seems to us that the only radicals that will remove metallic mirrors (of tellurium or antimony, etc., previously deposited beyond the furnace) are those that can decompose into methyl or ethyl radicals plus an unsaturated molecule, without undergoing any transmigration of atoms.