辛基环戊烷 | 1795-20-6

• 分子结构分类: 有机化合物 - 碳氢化合物 - 饱和烃
• 中文名称: 辛基环戊烷
• 英文名称: 1-cyclopentyl-octane
• 英文别名: 1-Cyclopentyl-octan；octyl-cyclopentane；n-Octylcyclopentan；Octylcyclopentan；n-Octylcyclopentane；octylcyclopentane
• CAS: 1795-20-6
• 化学式: C₁₃H₂₆
• 分子量: 182.349
• InChiKey: HARXDULSBROLME-UHFFFAOYSA-N

物化性质

• 熔点：
  -43.99°C
• 沸点：
  230.78°C (estimate)
• 密度：
  0.8010
• 保留指数：
  1338;1340;1337

计算性质

• 辛醇/水分配系数(LogP)：
  6.8
• 重原子数：
  13
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  辛基环戊烷 、 硫脲 以94%的产率得到
  参考文献：
  名称：

  OVEZOV, A. A.;AJDOGDYEV, A.;SERGIENKO, S. R., IZV. AN TSSR. CEP. FIZ.-TEXN., XIM. I GEOL. N., 1984, N 3, 95-97

  摘要：

  DOI：
• 作为产物：
  描述：

  alkaline earth salt of/the/ methylsulfuric acid 在 钯 作用下， 生成 辛基环戊烷
  参考文献：
  名称：

  Zelinsky; Michlina; Eventowa, Chemische Berichte, 1933, vol. 66, p. 1422,1424

  摘要：

  DOI：

文献信息

• Metzger, Juergen O., Journal fur praktische Chemie (Leipzig 1954), 1990, vol. 332, # 5, p. 767 - 781
  作者：Metzger, Juergen O.

  DOI：——

  日期：——
• From Dimethylamine to Pyrrolidine: The Development of an Improved Nickel Pincer Complex for Cross-Coupling of Nonactivated Secondary Alkyl Halides
  作者：Pablo M. Perez Garcia、Thomas Di Franco、Alexandre Epenoy、Rosario Scopelliti、Xile Hu

  DOI：10.1021/acscatal.5b02324

  日期：2016.1.4

  Replacement of a dimethyl amino group of the amidobis(amine) nickel(II) pincer complex (1), [((N2N)-N-Me)-Ni-Cl], by a pyrrolidino group resulted in a new nickel(II) pincer complex (2), [((PNNN)-N-yr-N-Me)Ni-Cl]. Complex 2 is an efficient catalyst for Kumada and Suzuki-Miyaura cross-coupling of nonactivated secondary alkyl halides, while complex 1 is largely inactive. The significant activity difference is tentatively attributed to a minimal structural difference, which leads to a more hemilabile ligand.
• Peregudow et al., Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, 1957, p. 37,38; engl. Ausg. S. 39, 40
  作者：Peregudow et al.

  DOI：——

  日期：——
• Orthogonality criteria for compactly supported refinable functions and refinable function vectors
  作者：Jeffrey C. Lagarias、Yang Wang

  DOI：10.1007/bf02510658

  日期：2000.3

  A refinable function phi(x) : R-n --> R or, more generally, a refinable function vector Phi(x) = [phi(1)(x),..., phi(r)(x)](T) is an L-1 solution of a system of (vector-valued) refinement equations involving expansion by a dilation matrix A, which is an expanding integer matrix. A refinable function vector is called orthogonal if phi(j)(x - alpha) : alpha epsilon Z(n), 1 less than or equal to j less than or equal to r} form an orthogonal set of functions in L-2(R-n). Compactly supported orthogonal refinable functions and function vectors can be used to construct orthonormal wavelet and multi-wavelet buses of L-2(R-n). In this paper we give ct comprehensive set of necessary and sufficient conditions for the orthogonality of compactly supported refinable functions and refinable function vectors.
• METZGER, JURGEN O., J. PRAKT. CHEM., 332,(1990) N, C. 767-781
  作者：METZGER, JURGEN O.

  DOI：——

  日期：——