tert-butyl (+/-)-trans-2,2-dimethyl-3-{2-carboxy-(E)-1-propenyl}cyclopropanecarboxylate | 1195315-35-5

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: tert-butyl (+/-)-trans-2,2-dimethyl-3-{2-carboxy-(E)-1-propenyl}cyclopropanecarboxylate
• 英文别名: tert-butyl 3,3-dimethyl-2-E-(2-carboxy-1-propenyl)cyclopropanecarboxylate；(E)-3-[2,2-dimethyl-3-[(2-methylpropan-2-yl)oxycarbonyl]cyclopropyl]-2-methylprop-2-enoic acid
• CAS: 1195315-35-5
• 化学式: C₁₄H₂₂O₄
• 分子量: 254.326
• InChiKey: BSFHWAFOLCFSGI-BQYQJAHWSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3
• 重原子数：
  18
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.71
• 拓扑面积：
  63.6
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  哌啶 、 tert-butyl 3-formyl-2,2-dimethylcyclopropionate 、 甲基丙二酸 以 吡啶 、 乙醚 、 正己烷 、 乙酸乙酯 为溶剂， 以96%的产率得到tert-butyl (+/-)-trans-2,2-dimethyl-3-{2-carboxy-(E)-1-propenyl}cyclopropanecarboxylate
  参考文献：
  名称：

  Process of producing cyclopropanecarboxylate compounds

  摘要：

  提供了生产化合物Formula (I)的环丙基羧酸酯的过程： 该过程包括将Formula (II)的环丙基甲醛化合物： 与Formula (III)的二羧酸酯化合物： 在至少一种来自哌啶、吗啉、吡咯啉、二乙胺或N-甲基乙醇胺的二级胺的存在下反应。

  公开号：

  US06414181B1

文献信息

• Method for producing oxygen-containing compound
  申请人：Hagiya Koji

  公开号：US20060173221A1

  公开（公告）日：2006-08-03

  It is provided that a method for producing an oxygen-containing compound, characterized in that an olefin compound having a carbon-carbon double bond which is bonded to a methyl or methylene group is reacted with an organic hydroperoxide in the presence of an ionic liquid and a selenium compound.

  本发明提供了一种生产含氧化合物的方法，其特征在于：在离子液体和硒化合物的存在下，使具有碳碳双键并与甲基或亚甲基键合的烯烃化合物与有机过氧化氢反应。
• PROCESS FOR PRODUCING OXYGENIC COMPOUND
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1797953B1

  公开（公告）日：2011-01-05
• METHOD FOR PRODUCING 3,3-DIMETHYL-2-(1-PROPENYL) CYCLOPROPANE CARBOXYLATE
  申请人：Sumitomo Chemical Company, Limited

  公开号：EP1681282B1

  公开（公告）日：2013-01-23
• Method for producing 3, 3-dimethyl-2-(1-propenyl) cyclopropanecarboxylate
  申请人：Hagiya Koji

  公开号：US20070078278A1

  公开（公告）日：2007-04-05

  A method for producing 3,3-dimethyl-2-(1-propenyl)cyclopropanecarboxylate represented by the formula (2): wherein R 1 represent an optionally substituted alkyl group, an optionally substituted aryl group or an optionally substituted aralkyl group, which comprises a 3,3-dimethyl-2-(2-carboxy-1-propenyl)cyclopropanecarboxylate represented by the formula (1): wherein R 1 is as described above, is brought into contact with a copper compound and a nitrogen-containing aromatic compound, is provided.
• Method for Producing Oxygen-Containing Compound
  申请人：Hagiya Koji

  公开号：US20080064898A1

  公开（公告）日：2008-03-13

  An oxidation catalyst composition is obtained by mixing a selenium compound, a nitrogen-containing aromatic compound and an acid, and if necessary, in the presence of a solvent. The oxidation catalyst composition shows an oxidation catalyst activity in the oxidation reaction of an organic compound. For example, at least one oxygen-containing compound selected from an alcohol compound, an aldehyde compound, a ketone compound and a carboxylic acid compound is obtained by reacting the olefin compound having two or more hydrogen atoms on the carbon atom at α-position of a carbon-carbon double bond with an organic hydroperoxide compound in the presence of the oxidation catalyst composition.