dimethylol tricyclodecane diacrylate | 116738-40-0

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: dimethylol tricyclodecane diacrylate
• 英文别名: Tricyclodecanedimethanol (2,6)-diacrylate；[8-(prop-2-enoyloxymethyl)-4-tricyclo[5.2.1.02,6]decanyl]methyl prop-2-enoate
• CAS: 116738-40-0
• 化学式: C₁₈H₂₄O₄
• 分子量: 304.386
• InChiKey: LISQVJRGPPEVJK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  22
• 可旋转键数：
  8
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  dimethylol tricyclodecane diacrylate 、 2,5-bis(2-acryloyloxyethylthiomethyl)-1,4-dithian 生成 poly(2,5-bis(acryloxyethylthiomethyl)-1,4-dithiane-co-dimethylol tricyclodecane diacrylate)
  参考文献：
  名称：

  摘要：

  DOI：

文献信息

• 1,3-DIPOLAR CYCLOADDITION OF AZIDES TO ALKYNES
  申请人：Musa Osama M.

  公开号：US20100121022A1

  公开（公告）日：2010-05-13

  A process for the bulk polymerization, in the absence of any solvent, of a reactant containing azide functionality and a reactant containing a terminal alkyne functionality, in the presence of Cu (I) catalyst or in the presence of a Cu(II) catalyst without a reducing agent, is described. Polymerization can be achieved at temperatures less than 100° C., which is suitable for low temperature cures. A controlled synthesis for low molecular weight oligomers is disclosed.

  本发明涉及一种无溶剂的大量聚合过程，其中包含一种含有叠氮官能团的反应物和一种含有末端炔基官能团的反应物，在存在Cu（I）催化剂或Cu（II）催化剂且无还原剂的情况下进行。可以在低于100℃的温度下实现聚合，适用于低温固化。本发明还公开了低分子量寡聚物的可控合成方法。
• SYNERGISTS
  申请人：Davidson Robert Stephen

  公开号：US20130012611A1

  公开（公告）日：2013-01-10

  Compounds of formula (I): wherein Ar represents an, optionally substituted, aryl or heteroaryl group, R represents an, optionally substituted, aryl or heteroaryl group, an optionally substituted straight or branched chain C 1.10 -alkyl, R 1 is H or methyl, X is an extender group, n is 0 or an integer between 1 and 12 inclusive, A is a polyol residue wherein the unsubstituted polyol from which the residue is derived has at least y OH groups, and y is an integer>1, can easily be prepared, and are useful as synergists in radiation curing.

  式(I)的化合物：其中Ar代表一个可选择取代的芳基或杂芳基基团，R代表一个可选择取代的芳基或杂芳基基团，一个可选择取代的直链或支链C1-10烷基，R1为H或甲基，X为延伸基团，n为0或介于1至12之间的整数，A为多元醇残基，其中未取代的多元醇至少具有y个OH基团，y为大于1的整数。这些化合物可以轻松制备，并且在辐射固化中作为协同剂非常有用。
• [EN] UV CURABLE INKJET INKS AND INKJET PRINTING METHODS<br/>[FR] ENCRES POUR JET D'ENCRE DURCISSABLE AUX UV ET PROCÉDÉS D'IMPRESSION À JET D'ENCRE
  申请人：AGFA NV

  公开号：WO2022106100A1

  公开（公告）日：2022-05-27

  A UV curable inkjet ink including a free radical polymerizable compound and an acyl phosphine oxide initiator wherein the acyl phosphine oxide initiator includes an acyl group selected from the group consisting of a benzoyl group substituted by an urea group or an oxalylamide group; a 2,6-dimethyl benzoyl group substituted in position 3 by an urea group or an oxalylamide group; a 2,6-dimethoxy benzoyl group substituted in position 3 by an urea group or an oxalylamide group; a 2,4,6-trimethyl benzoyl group substituted in position 3 by an urea group or an oxalylamide group; and a 2,4,6-trimethoxybenzoyl group substituted in position 3 by an urea group or an oxalylamide group wherein the urea group and the oxalylamide group include a tertiary amine group positioning a phosporus atom of the acylphosphine oxide initiator in a 1 to Z position, where position 1 is defined as that of the phosphorus atom and position Z is defined as the nitrogen atom of the tertiary amine group with Z representing an integer of at least 11; and that the acyl phosphine oxide initiator contains no more than two photoinitiating moieties having a phosphine oxide group.

  一种紫外光固化喷墨墨水，包括自由基聚合化合物和酰基膦氧化物引发剂，其中酰基膦氧化物引发剂包括以下酰基：被尿素基或草酰胺基取代的苯甲酰基；在3位被尿素基或草酰胺基取代的2,6-二甲基苯甲酰基；在3位被尿素基或草酰胺基取代的2,6-二甲氧基苯甲酰基；在3位被尿素基或草酰胺基取代的2,4,6-三甲基苯甲酰基；在3位被尿素基或草酰胺基取代的2,4,6-三甲氧基苯甲酰基，其中尿素基和草酰胺基包括将膦氧化物引发剂的磷原子定位于1到Z位置的三级胺基，其中位置1被定义为磷原子的位置，位置Z被定义为三级胺基的氮原子，其中Z表示至少为11的整数；而且酰基膦氧化物引发剂不含有超过两个具有膦氧化物基团的光引发基团。
• INKJET INK SET FOR A METHOD OF MANUFACTURING A PACKAGING
  申请人：Agfa Graphics NV

  公开号：EP3173246A1

  公开（公告）日：2017-05-31

  A method for manufacturing a packaging (1, 9) including the steps of: jetting one or more free radical UV curable pigmented colour inkjet inks from an inkjet ink set on the packaging (2); UV curing the one or more jetted free radical UV curable pigmented colour inkjet inks; jetting at least one colour forming inkjet ink from the inkjet ink set on the packaging or on the one or more UV cured free radical UV curable pigmented colour inkjet inks; and forming a colour image (10, 11) by a heat treatment (8) of the at least one jetted colour forming inkjet ink. Suitable inkjet ink sets are also described.

  一种制造包装（1，9）的方法，包括以下步骤从喷墨墨水组中喷射一种或多种自由基紫外线固化颜料彩色喷墨墨水到包装上 (2)；紫外线固化一种或多种喷射的自由基紫外线固化颜料彩色喷墨墨水；从喷墨墨水组中喷射至少一种彩色成型喷墨墨水到包装上或一种或多种紫外线固化的自由基紫外线固化颜料彩色喷墨墨水上；以及通过对至少一种喷射的彩色成型喷墨墨水进行热处理 (8) 形成彩色图像 (10、11)。还描述了合适的喷墨墨水组。
• Photocurable composition, denture base, and plate denture
  申请人：Mitsui Chemicals, Inc.

  公开号：US10973742B2

  公开（公告）日：2021-04-13

  A photocurable composition for manufacturing a dental prosthesis by stereolithography, including: a photopolymerization initiator; and a (meth)acrylic monomer component including an acrylic monomer (X) having no aromatic rings and having a ring structure other than an aromatic ring and two or more acryloyloxy groups in one molecule and having an Mw of from 200 to 800, and at least one of a (meth)acrylic monomer (A) having one or more ether bonds and two (meth)acryloyloxy groups in one molecule and having a defined Mw, a (meth)acrylic monomer (B) having a ring structure other than an aromatic ring and one (meth)acryloyloxy group in one molecule and having a defined Mw, a (meth)acrylic monomer (C) having a hydrocarbon skeleton and two (meth)acryloyloxy groups in one molecule and having a defined Mw, and a (meth)acrylic monomer (D) having one or more aromatic rings and one (meth)acryloyloxy group in one molecule and having a Mw.

  一种光固化组合物，用于通过立体光刻技术制造牙科修复体，包括一种光聚合引发剂；和（甲基）丙烯酸单体组分，其中包括：丙烯酸单体 (X)，该单体没有芳香环，具有芳香环以外的环状结构，在一个分子中含有两个或两个以上丙烯酰氧基，其 Mw 为 200 至 800；以及（甲基）丙烯酸单体 (A)，该单体具有一个或多个醚键，在一个分子中含有两个（甲基）丙烯酰氧基，且具有确定的 Mw、(甲基)丙烯酸单体(B)，该单体具有一个非芳香环的环状结构，且一个分子中含有一个(甲基)丙烯酰氧基，并具有确定的 Mw；(甲基)丙烯酸单体(C)，该单体具有一个烃骨架，且一个分子中含有两个(甲基)丙烯酰氧基，并具有确定的 Mw；以及(甲基)丙烯酸单体(D)，该单体具有一个或多个芳香环，且一个分子中含有一个(甲基)丙烯酰氧基，并具有确定的 Mw。