(Z)-2-(2-hydrazono-2-phenylethyl)quinoline | 1415752-95-2

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 喹啉及其衍生物
• 英文名称: (Z)-2-(2-hydrazono-2-phenylethyl)quinoline
• 英文别名: (Z)-(1-phenyl-2-quinolin-2-ylethylidene)hydrazine
• CAS: 1415752-95-2
• 化学式: C₁₇H₁₅N₃
• 分子量: 261.326
• InChiKey: FRJQDPQHLZJGII-JZJYNLBNSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  20
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.06
• 拓扑面积：
  51.3
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  (Z)-2-(2-hydrazono-2-phenylethyl)quinoline 、 4-溴苯乙酮 在 溶剂黄146 作用下， 反应 5.0h， 以85%的产率得到
  参考文献：
  名称：

  Tautomerism in 2-ketomethylquinolineazines

  摘要：

  A series of new azines were prepared in three steps. Structures of all compounds have been elucidated using spectroscopic methods and elemental analysis. Our studies show that in chloroform solution generally two tautomeric forms are in equilibrium. In some cases, one tautomer was the dominant species. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2012.05.034
• 作为产物：
  描述：

  (Z)-1,2-dihydro-2-benzoylmethylenequinoline 在 一水合肼 、 溶剂黄146 作用下， 以 乙醇 为溶剂， 反应 6.0h， 生成 (Z)-2-(2-hydrazono-2-phenylethyl)quinoline
  参考文献：
  名称：

  Tautomerism in 2-ketomethylquinolineazines

  摘要：

  A series of new azines were prepared in three steps. Structures of all compounds have been elucidated using spectroscopic methods and elemental analysis. Our studies show that in chloroform solution generally two tautomeric forms are in equilibrium. In some cases, one tautomer was the dominant species. (C) 2012 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2012.05.034

文献信息

• Tautomerism in 2-ketomethylquinolineazines
  作者：Hossein Loghmani-Khouzani、Alireza Minaeifar、Ryszard Gawinecki

  DOI：10.1016/j.molstruc.2012.05.034

  日期：2013.1

  A series of new azines were prepared in three steps. Structures of all compounds have been elucidated using spectroscopic methods and elemental analysis. Our studies show that in chloroform solution generally two tautomeric forms are in equilibrium. In some cases, one tautomer was the dominant species. (C) 2012 Elsevier B.V. All rights reserved.