1,7,7-trimethyl-3-(PhHN-imino)bicyclo[2.2.1]heptan-2-one | 303115-42-6

• 分子结构分类: 有机化合物 - 脂质和类脂质分子 - 异戊烯醇脂质
• 英文名称: 1,7,7-trimethyl-3-(PhHN-imino)bicyclo[2.2.1]heptan-2-one
• 英文别名: bornane-2,3-dione-3-phenylhydrazone；Bornan-2,3-dion-3-phenylhydrazon；3-Phenylhydrazono-bornanon-(2)；(d-Campher)-chinon-phenylhydrazon-(3)；Campherchinon-phenylhydrazon-(3)；1,7,7-Trimethyl-3-(phenylhydrazinylidene)bicyclo[2.2.1]heptan-2-one
• CAS: 303115-42-6
• 化学式: C₁₆H₂₀N₂O
• 分子量: 256.348
• InChiKey: CVTKBMLVYAJWMY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.7
• 重原子数：
  19
• 可旋转键数：
  2
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  41.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  1,7,7-trimethyl-3-(PhHN-imino)bicyclo[2.2.1]heptan-2-one 生成 alkaline earth salt of/the/ methylsulfuric acid
  参考文献：
  名称：

  Forster; Zimmerli, Journal of the Chemical Society, 1911, vol. 99, p. 487,488

  摘要：

  DOI：
• 作为产物：
  描述：

  (1R,E)-(+)-camphorquinone 3-oxime 在 sodium disulfite 、 乙醚 、 硫酸 作用下， 生成 1,7,7-trimethyl-3-(PhHN-imino)bicyclo[2.2.1]heptan-2-one
  参考文献：
  名称：

  Claisen; Manasse, Justus Liebigs Annalen der Chemie, 1893, vol. 274, p. 98

  摘要：

  DOI：

文献信息

• Forster, Journal of the Chemical Society, 1902, vol. 81, p. 868
  作者：Forster

  DOI：——

  日期：——
• Tuning structure and properties of Pd and Pt camphor derived complexes
  作者：Ana S.D. Ferreira、M. Fernanda N.N. Carvalho、Adelino M. Galvão、Luís F. Veiros

  DOI：10.1016/j.ica.2012.10.036

  日期：2013.1

  Seven new camphor palladium or platinum compounds with novel metal coordination environments were obtained by convenient choice of the experimental conditions in particular the solvent. cis-[PtCl2(PhNC10 H14O)(2)]) and [Pd(MeNNC10H14O)(2)] were structurally characterized by X-ray diffraction analysis while [PtCl2(Me2NC10H13NSO2)}(2)], [PdCl2(YNC10H14O)}(2)] (Y = NMe2, NPh2) and [Pd(PhNNC10H14O)(2)] were formulated by elemental analysis and spectroscopic techniques. Relevant aspects of the IR and NMR spectra of complexes [Pd(YNC10H14O)(2)] (Y = MeN, PhN) are discussed with the help of DFT calculations. Evaluation of the properties of the new complexes as catalysts for activation of 4-pentyn-1-ol towards formation of cyclization products showed that [PdCl2(Ph2NNC10H14O)}(2)] is more efficient than [PdCl2 (Me2NNC10H14O)(2)] which is one of the more efficient camphor derived catalysts reported before. In contrast the chelate complexes [Pd(YNC10H14O)(2)] (Y = MeN, PhN) display no catalytic activity. (C)2012 Elsevier B. V. All rights reserved.
• Bishop; Claisen; Sinclair, Justus Liebigs Annalen der Chemie, 1894, vol. 281, p. 345
  作者：Bishop、Claisen、Sinclair

  DOI：——

  日期：——
• Forster; Cardwell, Journal of the Chemical Society, 1913, vol. 103, p. 870
  作者：Forster、Cardwell

  DOI：——

  日期：——
• Betti, Chemische Berichte, 1899, vol. 32, p. 1996
  作者：Betti

  DOI：——

  日期：——